1.

A certain mass of gas expanded from ( 1L, 10 atm) to (4 L, 5 atm) against a constant external pressure of 1 atm. If initial temperature of gas is 300 K and the heat capacity of process is `50 J//^(@)C`. Then the enthalpy change during the process is : (`1"L" "atm" underline ~ 100 J`)A. `Delta H = 15 KJ`B. `Delta H= 15.7 KJ`C. `Delta H=14.4 KJ`D. `DeltaH=14.7 KJ`

Answer» Correct Answer - B
`Delta H=Delta E+Delta(PV)& Delta E=q+W=(50xx300-3xx100)J ["as" T_(f)=2xx300 K=600K]=14.7 KJ`
`Delta H=14700+10xx100=15700 J=15.7 KJ`.


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