An electric current is passed through electrolytic cells in series one containing `Ag(NO_(3))`(eq) and other `H_(2)SO_(4)` (aq). What volume of `O_(2)` measured at `25^(@)C` and `750`mm Hg pressure would be liberated form `H_(2)SO_(4)` if (a) one mole of `Ag^(+)` is deposited from `AgNO_(3)` solution (b) `8 xx 10^(22)` ions of `Ag^(+)` are deposited from `AgNO_(3)` solution.

An electric current is passed through electrolytic cells in series one

1.	An electric current is passed through electrolytic cells in series one containing `Ag(NO_(3))`(eq) and other `H_(2)SO_(4)` (aq). What volume of `O_(2)` measured at `25^(@)C` and `750`mm Hg pressure would be liberated form `H_(2)SO_(4)` if (a) one mole of `Ag^(+)` is deposited from `AgNO_(3)` solution (b) `8 xx 10^(22)` ions of `Ag^(+)` are deposited from `AgNO_(3)` solution.
Answer» Correct Answer - (a) `V(O_(2))=6.2L` , (b). `V(O_(2))=0.823L` (i). Equivalents of `Ag^(+)=` Equivalent of `O_(2)` `1=` equivalent of `O_(2)` `therefore` mass of `O_(2)=(1)/(4)=(PV)/(RT)` `V=(1)/(4)xx(0.081xx298xx760)/(750)=6.5lit`. (ii). Moles of `O_(2)=("equivalent of "O_(2))/(4)=(8x10^(22)//6.023xx10^(23))/(4)=0.0332`. `V=(0.0332xx0.0821xx298xx760)/(750)=0.823lit`

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