1.

`DeltaU^(@)` of combustion of `CH_(4(g))` at certain temperature is `-"393 kJ mol"^(-1)`. The value of `DeltaH^(@)` isA. zeroB. `lt DeltaH^(@)`C. `gt DeltaU^(@)`D. equal to `DeltaU^(@)`

Answer» Correct Answer - B
The balanced equation for combustion of methane is
`CH_(4(G))+2O_(2(g))rarrCO_(2(g))+2H_(2)O_((l))`
Here, `Deltan_(g)=1-3=-2`
`DeltaH^(@)=DeltaU^(@_+Deltan_(g)RT`
`DeltaH^(@)=-393-2RT`
`therefore" "DeltaH^(@) lt DeltaU^(@)`


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