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Equimolal solutions `KCl` and compound `X` in water show depression in freezing point in the ratio of `4:1`, Assuming `KCl` to be completely ionized, the compound `X` in solution mustA. Dissociate to the extent of `50%`B. Hydrolyze to the extent of `80%`C. Dimerize to the extent of `50%`D. Trimerize to the extent of `75%` |
Answer» Correct Answer - D `underset(("p moles"))(KCl) and underset(("p moles"))(X)` `DeltaT_(f) (KCl)=iK_(f)m=2K_f m` `DeltaT_f (X) = iK_f .m=1/2(2K_f m)rArr i=1/2 (lt1)` `2X hArr X_2` `{:(1,0),(1-alpha , a//2):}` `i=1+alpha+alpha/3=1-(2alpha)/3=1/2rArr alpha=3/4=75%` |
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