1.

For a first-order reaction `A rarr B` the reaction rate at reactant concentration of `0.10 M` is found to be `2.0 xx 10^(-5) "mol" L^(-1) s^(-1)`. The half-life period of the reaction isA. 200sB. 30sC. 300sD. 347s

Answer» Correct Answer - D
For first order reaction,
`A to B`
` rate =Kxx[A]`
`rate =Kxx[A]`
`[A]=0.01M`
`SO,2.0xx10^(-5)=Kxx0.01`
`k=(2.0xx10^(-5))/(0.01)s^(-1)`
`=2.0xx10^(-3)S^(-1)`
for first order reaction .
`t_(1//2)=(0.693)/(k)=(0.693)/(2.0xx10^(-3))`
`=346.5=347s`


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