1.

For reaction a `A tox` P , when [A] = 2.2 mM , the rate was found to be 2.4 m M `s^(-1)` . On reducing concentration of A to half , the rate changes to 0.6 m M `s^(-1)` . The order of reaction with respect to A isA. 1.5B. `2.0`C. `2.5`D. `3.0`

Answer» Correct Answer - b
`a A to x`P
Rate of constant = `[A]^(a)`
Order of reaction = a
`[A]_(1) = 2.2` mM , `r_(1) = 2.4 m M s^(-1) " " … (i)`
`[A]_(2) = 2.2//2 m M , r_(1) = 0.6 m M s^(-1)` or `(2.4)/(4) " " … (ii)`
On reducing the concentration of A to half , the rate of reaction is decreased by four times .
Rate of reaction = `[A]^(2)`
Order of reaction = 2 .


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