Identify the reagent(s) for the conversion of chlorobenzene to 3-chlorobenzaldehyde.(a) CrO3 and (CH3CO)2O(b) CrO2Cl2; H2O(c) Cl2/hv; H2O(d) CO, HCl and CuClThe question was posed to me by my college director while I was bunking the class.This interesting question is from Preparation of Aldehydes and Ketones topic in section Aldehydes, Ketones and Carboxylic Acids of Chemistry – Class 12

Identify the reagent(s) for the conversion of chlorobenzene to 3-chlor

1.	Identify the reagent(s) for the conversion of chlorobenzene to 3-chlorobenzaldehyde.(a) CrO3 and (CH3CO)2O(b) CrO2Cl2; H2O(c) Cl2/hv; H2O(d) CO, HCl and CuClThe question was posed to me by my college director while I was bunking the class.This interesting question is from Preparation of Aldehydes and Ketones topic in section Aldehydes, Ketones and Carboxylic Acids of Chemistry – Class 12
Answer» Right choice is (d) CO, HCL and CuCl The best I can EXPLAIN: When benzene or its DERIVATIVE is TREATED with CO and HCl in the presence of anhydrous AlCl3 or CuCl, it gives a benzaldehyde or substituted benzaldehyde. This is known as Gatterman-Koch reaction.

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