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If one mole of ammonia and one mole of hydrogen chloride are mixed in a closed container to form ammonium chloride vapor, thenA. `Delta H = Delta U`B. `Delta H gt Delta U`C. `Delta H lt Delta U`D. there is no relationship

Answer» Correct Answer - C
Themochemical equation is
`NH_(3) (g) + HCl (g) rarr NH_(4) Cl_(g)`
Accroding to thermodynamics,
`Delta H = Delta U + Delta n_(g) RT`
where `Delta n_(g) = sum n_(P) (g) - sum n_(R ) (g)`
`= (1) - (1 + 1)`
`= -1`
Since `Delta n_(g)` is negative `(lt 0)` we conclude that `Delta H lt Delta U`


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