1.

In the reaction, `3BrO^(-)rarrBrO_(3)^(-)+2Br^(-)` (aqueous alkaline medium at `80^(@)C`) the vlaue of the rate constant in the rate law in terms of `--(d)/(dt)[BrO^(-)]` is `0.056 L "mol"^(-1)s^(-1)`. What will be the rate constant when the law is stated in terms of `(d)/(dt)[BrO^(-)]`?A. `18.7xx10^(-3) L"mol"^(-1)s^(-1)`B. `37.4xx10^(-3) L"mol"^(-1)s^(-1)`C. `0.0187 L"mol"^(-1)s^(-1)`D. `0.0187xx10^(-2) L"mol"^(-1)s^(-1)`

Answer» Correct Answer - C
`-(1)/(3)(d[BrO^(-)])/(dt)=(d[BrO_(3)^(-)])/(dt)=+(1)/(3)(d[Br^(-)])/(dt)`
Required rate constant `=(1)/(3)xx0.056 L "mol"^(-1)s^(-1)`
`=0.0187 L "mol"^(-1)s^(-1)`


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