1.

In view of the signs of `DeltaG^(ө)` for the following reactions, `PbO_(2)+Pb to 2PbO,Delta_(r)G^(ө) lt 0`, `SnO_(2)+Snto 2SnO,Delta_(r)G^(ө) gt 0` Which oxidation states are more characteristic for lead and tin?A. For lead +4, for tin +2B. For lead +2, ffor tin +2C. For lead +4, for tin +4D. For lead +2, for tin +4

Answer» Correct Answer - D
`overset(+4)(Pb)O_(2)+overset(0)(Pb) to 2 overset(+2)(Pb)O`
Since, `Delta_(r)G^(@) lt 0`, hence +2 state of lead is favourable.
`overset(+4)+(Sn)O_(2)+overset(0)(Sn) to 2 overset(0)(Sn)O`
Since, `Delta_(r)G^(@)gt0` it means forward reaction is not spontaneous.
`2overset(+2)(Sn)O+overset(+4)(Sn)O_(2) to 2overset(0)(S)n`
`Delta_(r)G^(@) lt0`, thus +4 state of tin is favourable.


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