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    				| 1. | One mole of an ideal gas at NTP occupies 22.4 liters (molar volume). What is the ratio of molar volume to atomic volume to atomic volume of a mole of hydrogen ? Take size of hydrogen molecule to be 1 Å. Why is this ratio so large? | 
| Answer» Solution :`1A^(0)=10^(-10)m` Atomic volume of 1 mole of hydrogen = Avagadros number `×` volume of hydrogen molecule `=6.023xx10^(23)xx(4)/(3)xxpixx(10^(-10)m)^(3)` `=25.2xx10^(-7)m^(3)` Molar volume =`22.4 L = 22.4 × 10^(–3) m^(3)` `("Molar volume")/("Atomic volume")=(22.4xx10^(-3))/(25.2xx10^(7))=0.89xx10^(4)~~10^(4)` This ratio is large because ACTUAL SIZE of gas molecule is negligible in comparison to the inter molecular separation. | |