One mole of an non linear triatomic ideal gas is expanded abiabatically at 300 K form 16 atm to 1 atm ltbr gt Find the value `DeltaS_(sys), DeltaS_(surr) & DeltaS_("total")` under the following conditions. (i) Expansion is carried out reversibly (ii) Expansion is carried out irreversibly (iii) Expansion is free.

One mole of an non linear triatomic ideal gas is expanded abiabaticall

1.	One mole of an non linear triatomic ideal gas is expanded abiabatically at 300 K form 16 atm to 1 atm ltbr gt Find the value `DeltaS_(sys), DeltaS_(surr) & DeltaS_("total")` under the following conditions. (i) Expansion is carried out reversibly (ii) Expansion is carried out irreversibly (iii) Expansion is free.
Answer» Correct Answer - (i)` " "DeltaS_("sys")= nC_(v)ln .(T_(1))/(T_(2))+nRln .(V_(1))/(V_(2))= 0, q= 0,DeltaS_("surr")= - DeltaS_("sys")=DeltaS_("total")=0` (ii)` " "DeltaS_("sys")= 1.702R," "DeltaS_("surr")=0 , DeltaS_("total")=DeltaS_("sys")=1.702 R` (iii)` " "DeltaS_("sys")= nRln .(p_(1))/(p_(2))= 2.77 R, DeltaS_("surr")=(-q_("irr"))/(T) = 0, DeltaS_("total")= DeltaS_("sys") = 2.177 R`

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