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The converison of vinyl allyl ether to pent-`4`-enol follows first order kinetics. The following plot is obtained for such a reaction: The rate constant for the reaction isA. `4.6 xx 10^(-2) s^(-1)`B. `1.2 xx 10^(-2) s^(-1)`C. `2.3 xx 10^(-2) s^(-1)`D. `8.4 xx 10^(-2) s^(-1)` |
Answer» Correct Answer - C `k = (2.303)/(t)log.(a)/(a-x)` `(kt)/(2.303) = log.a-log (a-x)` `:. log (a-x) = log a-(kt)/(2.303)` `log(a-x) = log a -(k)/(2.303)t` (Equation of straight line) `y = mx + c` Slope `= (-k)/(2.303) = (-6)/(10 xx 60)` `:. k = 2.303 xx 10^(-2)s^(-1)` |
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