1.

The degree of association `(alpha)` is given by the expressionA. `alpha=(i-1)/(1/n-1)`B. `alpha=(i-1)/(n-1)`C. `alpha=(1-i)/(1/n-1)`D. `alpha=(1-i)/(n-1)`

Answer» Correct Answer - 3
Degree of association `(alpha)` is the fraction of one mole of solute which associates to form bigger particle:-
`nA hArr (A)_(n)`
moles 1 mol 0 mol
before assocation
Moles `(1 - alpha)` mol `((alpha)/(n))` mole
after associates
`i=("Molar after association")/("Moles before association")`
`=((1-alpha)+(alpha/n))/1=(1+(1/n-1)alpha)/1`
or `(1/n-1)alpha=i-1`
`alpha=(i-1)/((1/n-1))`
For dissociation
`alpha=(i-1)/(n-1)`


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