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The enthalpies of neutralisation of a strong acid HA and weaker acid HB by NaOH are -13.7 and -12.7 kcal/eq. When one equivalent of NaOH is added to a mixture containing 1 equivalent of HA and HB; the enthalpy change was -13.5kcal. In what ratio is the base distributed between HA and HB? |
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Answer» Let x equivalent of HA and y equivalent of HB are taken in the mixture x + y = 1 ... (i) x × 13.7 + y × 12.7 = 13.5 … (ii) Solving eqs. (i) and (ii), we get x = 0.8, y = 0.2 x: y = 4: 1 |
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