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Water and oxygen atoms react in upper atmospheric level bimolecularly to form two `OH` radicals having heat of reaction `72 kJ` at `400 K` and energy of activation being `77 kJ mol^(-1)`. Calculate the `E_(a)` for bimolecular combination of two `OH` radicals to form `H_(2)O` and `O`-atom. |
Answer» Correct Answer - 5 `H_(2)O+O overset(E_(a)=77 kJ)(hArr) 2OH, DeltaH=72 kJ` `2 OH rarr H_(2)O+O, DeltaH=-72 kJ` `DeltaH=E_(a(f))-E_(a(b))` `-72=E_(a(f))-77` or `E_(a(f))=5 KJ` |
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