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When 2.0g of a non-volatile solute was dissolved in 90 gm of benzene, the boiling point of benzene is raised by 0.88K. Which of the following may be the solute? `K_(b)` for benzene `=2.53 K kg mol^(-1))`A. `CO(NH_(2))_(2)`B. `C_(6)H_(12)O_(6)`C. `NaCI`D. None of these |
Answer» Correct Answer - A `Na^(+)Cl^(-)` an ionic solid is not soluble in benzene `therefore Delta T_(b)=K_(b)xxm` `m=(Delta T_(b))/(K_(b))=(0.88)/(2.53)=0.348` `m = (wxx1000)/(MxxW)` `0.348=(2xx1000)/(Mxx90)` `(["W = mass of solvent, w = mass of solute"])/(M = (2xx1000)/(90xx0.348)=63.86)` Molar mass of urea, `CO(NH_(2))_(2)` `=12+16+(14+2)xx2` `=28+32=60 gmol^(-1)` `therefore` Solute is urea (A) |
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