1.

Which of the following carboxylic acids is most reactive towards esterification with given alcohol?(a) HCOOH(b) CH3COOH(c) (CH3)2CHCOOH(d) (CH3)3CCOOHI got this question during an online interview.The query is from Carboxylic Acids Chemical Reactions topic in portion Aldehydes, Ketones and Carboxylic Acids of Chemistry – Class 12

Answer»

Right option is (a) HCOOH

Easiest explanation: The rate at which carboxylic ACIDS are esterified DEPENDS upon the stearic HINDERANCE and to some EXTENT the acidic strength of the acid, as it is a nucleophilic substitution reaction. Since formic acid has the lowest molecular mass and SMALLEST group, it is the most reactive.



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