1.

X' is an alicylic hydrocarbon . with the moleclar formulaC_4H_8. Y is the corrcsponding aliphatic compound. Give all the possible isomers of y · and their IUPAC names. Identify the products of bro-mination. When Y is treated with hydrogen what are the products formed? How are these products separated from the nuxture?

Answer»

SOLUTION :X is cyclobutane
Y is butane
Isomers of Y are
(a)`underset (2-"Butane")(CH_3-CH=CH-CH_3)`
`underset (1-"Butane")(CH_3-CH_2=CH=CH_3)`
(a), (b) are position isomers. (a) and (c)and (c) are CHAIN isomers.
Therefore, the hydrogenated products aren-butane C in case (a), (b) and isobutene in case if (c):Among these two N-butane is having high boiling point than isobutane. The boiling point is PROPORTIONAL to surface area of the molecule, more is the surface area more are the intermolecular forces of attraction between the MOLECULES. So, its boiling point increases. Between n butane and isobutene n butane is having high surface areaso, boiling point is more when compared to isobutene. Hence, these two can be separated by fractional distillation.


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