Explore topic-wise InterviewSolutions in Current Affairs.

This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.

1.

The concentration of commercial H_2O_2is 3.125 M than its grade is ______volume.

Answer»

SOLUTION :35 VOLUME
2.

The concentration of Ag_2 Cr_2O_7 is 6.5xx10^(-5)M in concentrated solution of Cr_2O_7^(2-)at a temp. then calculate K_2Cr_2O_7

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SOLUTION :`K_(sp)=[Ag^+]^2 [Cr_2O_7^(2-)]`
`therefore K_(sp)=4S^3=4(6.5xx10^(-5))^3`
`=1.098xx10^(-12)`
Where S=Solubility of `Ag_2Cr_2O_7=6.5xx10^(-5)` M
3.

The concentration of Al^(3+)ion in aqueous solution of Al_(2)(SO_(4))_(3) is 0.28 M Then the concentration of SO_(4)^(2-) ion in this solution will be:

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0.28 M
0.042 M
0.42 M
0.84 M

Solution :Ionisation of `Al_(2)(SO_(4))_(3)` in its aqua solution
`Al_(2)(SO_(4))_(3) overset(H_(2)O)rarr 2Al_((aq))^(3+) + 3SO_(4(aq))^(2-)`
ACCORDING to STOCHIOMETRY of the REACTION `2AL^(3+)`IONS and `3SO_(4)^(2-)` ions are formed.
`SO_(4)^(2-)` ions `=(0.28xx3)/(2) = 0.42 M`
4.

The concentration of acetic acid required to get 3.5 xx 10^(-4) mole/lit of H^(+) ion is [K_(a) = 1.8 xx 10^(-5)]

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`6.8 XX 10^(-3) mol lit^-1`
`6.8 N`
`1.9 4 N`
`1.94 xx 10^(-2) N`

Answer :A
5.

The concentration of 500 ML NaOH solution is 0.02 M. How many grams of FeSO_4 added in this solution for precipitation of Fe(OH)_2 ? The K_(sp)of Fe(OH)_2 is 1.5 xx 10^(-15), Molecular mass of Fe(OH)_2 is 152 g "mol"^(-1))

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SOLUTION :More than `2.85xx10^(-10)` GM
6.

The concentration term is used in the calculation of vapour pressure of solution is ……………..

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SOLUTION :MOLE FRACTION
7.

The compund Yb Ba_(2)Cu_(3)O_(7) which shows superconductivity has copper in oxidation stte…………..Assume that the reare earth element ytterbium isin the usual + 3oxidation state

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Answer :`7//3 overset(+3)ya overset(+2)Ba_(2)overset(X)Cu_(3)overset(-23)O_(7) therefore 3+4+3x-14 or x=7//3`
8.

The compressibilty factor for a real gas at high pressure is:

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`1 + (RT)/(Pb)`
`1`
`1 + (Pb)/(RT)`
`1 - (Pb)/(RT)`

SOLUTION :For 1 mol gas
`(P+ (a)/(V^(2))) (V - b) = RT`
Pressure correction can be NEGLECTED at high pressure.
THUS, `P (V - b) = RT`
`PV = Pb + RT`
`(PV)/(RT) = 1 + (Pb)/(RT)`
`Z = 1 + (Pb)/(RT)`
9.

The compression factor (compressibility factor) for one mole of a van der Waals gas at 0^(@)C and 100 atm pressure is found to be 0.5. Assuming that the volume of a gas molecule is negligible, calculate the van der Waals constant a.

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Solution :`Z=(PV)/(NRT),i.e., 0.5=(100xxV)/(1xx0.082xx273)"or"V=0.1119" L"`
`(P+(a)/(V^(2)))(V-B)=RT` for 1 MOL
Neglecting b, `(P+(PV)/(V^(2)))V=RT "or"PV+(a)/(V)=RT"or" (PV)/(RT)+(a)/(VRT)=1`
or `"" a=(1-(PV)/(RT))VRT=(1-0.5)0.1119xx0.082xx273=1.252" atm "L^(2)mol^(-2)`
10.

The compression factor for one mole of real gas at 0^@C and 100 atm is 0.5. Calculate the van der Waals' constant 'a', if 'b' is zero.

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ANSWER :`1.253 L^2 ATM MOL^(-2)`
11.

The compressibility of a gas is less than unity at STP. Therefore,

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`V_(m) GT 22.4L`
`V_(m) LT 22.4L`
`V_(m)=22.4L`
`V_(m)=44.8L`

ANSWER :B
12.

The compressibility of a gas is less than unity at N.T.P.Therefore.

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`V_(m) GT 22.4 L`
`V_(m) lt 22.4 L`
`V_(m) = 22.4 L`
`V_(m) = 44.8 L`

Solution :`Z = (PV)/(nRT)`
For ideal gas, `V_(m) = 22.4 L` at N.T.P. At a given TEMPERATURE and pressure if `Z` is LESS than unity, then `V_(m) lt 22.4 L`
13.

The compressibility of a gas is less than unity at S.T.P

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`V_(m)gt22.7` LITRES
`V_(m)gt22.7` litres
`V_(m)=22.7` litres
`V_(m)=45.4` litres

Answer :C
14.

The compressibility factor (Z) for one mole ofa gas is more than one under S.T.P. conditions. Therefore

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`V GT 11.2 L`
`V lt 22.38 L`
`V gt 22.38 L`
`V = 22.38 L`

Solution :`Z = (PV)/(NRT)`, if `Z gt 1`
`(PV)/(nRT) gt 1` or `V gt (nRT)/(P)`
`V gt ((1MOL) XX (0.0821 L atmK^(-1) mol^(-1)) xx 273K)/((1atm)) gt 22.4 L`
15.

The compressibilityfactor ( z) for a real gas at its Boyle temperature is "_____________".

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1
0
`GT 1 `
`LT 1 `

ANSWER :A
16.

The compressibility factor Z for an ideal gas will be .........

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`1.5`
`1.0`
`2.0`
zero

Answer :B
17.

The compressibility factor of an ideal gas is

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1.0 
1.5 

Infinity 

Solution :Z for IDEAL GAS = 1
18.

The compression factor (compressibility factor) for one mole of a van der Waals gas at 0°C and 100 atmospheric pressure is found to be 0.5. Assuming that the volume of a gas molecule is negligible, calculate the van der Waals constant a.

Answer»

1.253 ATM LIT`""^2MOL^(-2)`
12.53 atm lit`""^2mol^(-2)`
0.125 atm lit`""^2mol^(-2)`
22.53 atm lit`""^2mol^(-2)`

ANSWER :A
19.

The compressibility factor for a real gas at high pressure is :

Answer»

`1+ (RT)/(PB)`
1
`1+(Pb)/(RT)`
`1-(Pb)/(RT)`.

SOLUTION :`1+(Pb)/(RT)`
20.

The compressibility factor for a real gas at high pressure is

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1
`1+Pb//RT`
`1-Pb//RT`
`1+RT//Pb`

SOLUTION :For real gases, `(P+(a)/(V^(2)))(V-b)=RT`
At high pressure, `P GT gt a//V^(2)`
21.

The compounds which on heating produce at least one polymeric product, are:

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`Na(NH_(4))HPO. 4H_(2)O`
`NaH_(2)PO_(4)`
`MgHPO_(4)`
`NaHSO_(4)`

Solution :`NaH_(2)PO_(4) overset(DELTA)RARR (HPO_(3))_(n)//(NaPO_(3))_(n)`
22.

The compound(s) which have -O-O- bond (s)is / are

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`BaO_(2)`
`Na_(2)O_(2)`
`CrO_(5)`
`Fe_(2)O_(3)`

Solution :Only peroxide such as `BaO_(2), Na_(2)O_(2) & CrO_(5)` can form peroxy BONDS (-O-O)
23.

The compounds which gives the most stable carboniurn ions on dehydrohalogenation is

Answer»

`CH_3I`
`C_2H_5I`
`(CH_3)_3Cl`
`(CH_3)_2CHI`

Solution :Order of STABILITY: tertiary`gt` secondary`gt` PRIMARY
24.

The compound(s) which generate(s) N_(2) gas upon thermal decomposition below 300^(@)C is (are)

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`NH_(4)NO_(3)`
`(NH_(4))_(2)Cr_(2)O_(7)`
`Ba(N_(3))_(2)`
`Mg_(3)N_(2)`

Solution :`NH_(4)NO_(3)` on HEATING gives `N_(2)O` while `Mg_(3)N_(2)` does not decompose below `300^(@)C`. Thus, `(NH_(4))_(2)Cr_(2)O_(7)andBa[N_(3)]_(2)` on thermal DECOMPOSITION give `N_(2)` i.e., options (b,c) are correct.
25.

The compound(s) which contain ionic, covalent and coordinate bonds is (are)

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`H_(2)SO_(4)`
`NH_(4)CI`
`K_(4)[FE(CN)_(6)]`
`CaC_(2)`

Answer :A::B::C
26.

The compounds which are used for denaturation of ethyl alcohol are

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Paphtha
`CH_(3)OH`
Pyridine
Anhy. `CaCl_(2)`

ANSWER :B::C
27.

The compound(s) that undergo slower electrophilic substitution than benzene is/are

Answer»





Solution :`-CH = CH_2`, has overall electron WITHDRAWING effect, deactivate the ring. In both (c) and (d) STRONG electron withdrawing REASONANCE effect deactivat ring for ELECTROPHILIC substitution reaction.
28.

The compound(s) that direct incoming electrophile predominantly at meta position is/are

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Solution :Both `-CF_3 and -CN` are META DIRECTION GROUPS. `-CH_2Cl` is deactivating but ortho/para DIRECTING due to hyperconjugation bye benzylic hydrogens. In (d) electrophilic attack occur at ortho/para positions of the ring directly BONDED to oxygen atom.
29.

The compounds P,Q and S were separately to nitration using HNO_3//H_2SO_4 mixture.The major product formed in each case respectively is :

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ANSWER :C
30.

The compounds(s) of alkaline earth metals, which are amphoteric in nature is / are

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BeO
MgO
`Be(OH)^(2)`
`MG(OH)_(2)`

Solution :The compounds of Be such as BeO and `Be(OH)_(2)` are amphoteric due to HIGH POLARISING power
31.

The compounds of alkaline earth metals have the following magnetic nature.

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Diamagnetic
Paramagnetic
Ferromagnetic
Anti ferromagnetic

Answer :A
32.

Fill in the blanks The compounds of Al are predominantly ............ due to the ............ size and ............ charge of A1^(3+) ions.

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SOLUTION :COVALENT , SMALL , HIGH
33.

The compounds formed at anode in the electrolysisof an aqueous solution of potassium acetate are…………….

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`CH_(4)` NAD `H_(2)`
`CH_(4)` and `CO_(2)`
`C_(2)H_(6)` and `CO_(2)`
`C_(2)H_(4)` and `CI_(2)`

Answer :c
34.

The compounds CH_3 CH = CH CH_3 and CH_3 CH_2 CH = CH_2 (a) are tautomers (b) are position isomers (c) contain same number of sp^3 sp^3, sp^3 - sp^2 and sp^2 - sp^2 carbon-carbon bonds (d) exist together in dynamic equilibrium (e) are optical isomers

Answer»


ANSWER :B
35.

The compounds C_(2)H_(5)OC_(2)H_(5) and CH_(3)OCH_(2)CH_(2)CH_(3) are

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CHAIN isomers
geometrical isomers
metamers
CONFORMATIONAL isomers

Solution :They are called metamers because there is different in the NATURE of ALKL group.
36.

The compounds A and B are mixed in equimolar proportion to from the products, A+B harr C+D. At equilibrium, one third of A and B are consumed. The equilibrium constant for the reaction is

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0.5
4
2.5
0.25

Solution :
`K_(C)=((a)/(3) XX (a)/(3))/((2a)/(3) xx (2a)/(3))=(1)/(4)`
37.

The compounds A, B, C have R or S configurations respectively

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R,R,S
R,S,R
R,R,R
S,R,S

Answer :3
38.

The compound Y is

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`BCl_(3)`
`BF_(3)`
`B_(2)H_(6)`
`B_(2)O_(3)`

Answer :C
39.

The compound Y in the above sequence is

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2-Methyl-2-phenyl-1-propanol
2-Phenyl-2-propanol
Acetophenone
2-Methyl-1-Phenyl-2-propanol

Solution :
40.

The compound (X) on heating gives a colourless gas and a residue that is dissolved in water to obtain (B). Excess of CO_(2) is bubbled through aqueous solution of B, C is formed. Solid (C) or heating gives back X. (B) is …......

Answer»

`CaCO_(3)`
`Ca(OH)_(2)`
`Na_(2)CO_(3)`
`NaHCO_(3)`

SOLUTION :`CaCO_(3)OVERSET(Delta)toCaO+CO_2`
`CaO+H_2OtoCa(OH)_2 , Ca(OH)_2+CO_2to CaCO_3+H_2O`
41.

The compound (X) on heating gives a colourless gas a nd a residue that is dissolved in water to obtain (B). Excess of CO_2 is bubbled through aqueous solution of B, C is formed. Solid (C) on heating gives back X. (B) is

Answer»

`CaCO_(3)`
`CA(OH)_(2)`
 `Na_(2) CO_(3)`
 `NaHCO_(3)`

Solution :`caCO_(3)overset(triangle)toCaO+CO_(2)`
`CaO+H_(2)OtoCa(OH)_(2)`
`Ca(OH)_(2)+CO_(2)toCaCO_(3)+H_(2)O`
42.

The compound "X" is used as

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INSECTICIDE 
SOLVENT 
REFRIGERANT 
MOTOR fuel

Answer :A
43.

The compound 'X' is

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SOLUTION :
44.

The compound X is

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`C Cl_(4)`
`CO_(2)`
`CH_(3)OH`
`CO`

ANSWER :B
45.

The compound X is

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`B_(2)H_(6)`
`[B(OH)_(4)]^(-)`
`B_(2)O_(3)`
`H_(2)B_(4)O_(7)`

Answer :C
46.

The compound X in the reaction is :

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ANSWER :B
47.

The compound with the lowest oxidation state of iron is:

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`Fe_(2)O`
`Cr^(2+)`
`Ti^(4+)`
`MN^(2+)`

Answer :A
48.

The compound with the highest boiling point is

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n-hexane
n-pentane
2,2-dimethylpropane
2-methylbutane.

Answer :A
49.

The compound with molecular formula C_8H_10which will give only two isomers on electrophilic substitution with Cl_2//FeCl_3or with HNO_3//H_2SO_4is

Answer»

p-dimethylbenzene
m-dimethylbenzene
o-dimethylbenzene
ethylbenzene

Solution :Since `CH_3` groups are o,p-directing , therefore , o-dimethylbenzene (i.e., o-xylene) gives only two ISOMERIC products on chlorination or NITRATION.

50.

The compound with molecular formula, C_(6)H_(14) has two tertiary carbons. Its IUPAC name is

Answer»

n-hexane
2-methylpentane
2, 3-dimethylbutane
2, 3-dimethylpentane

Solution :2, 3-Dimethylbutane as SHOWN in ANS 15 has TWO `3^(@)` carbon atoms.