This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.
| 1. |
Which properties of hydrogen are responsible for moderation of the climate and body temperature of living beings? |
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Answer» High heat of vapourisation |
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| 2. |
Writenoteson geometrical isomerism or cis iruns isomerism |
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Answer» Solution :(i)it isa TYPEOF stereoisomerismit is alos calledcis -transisomerism . Such typeofboundedcarbonatoms. (II)if thesimilargrouplieon the samesidethen the geometricalisomersare CALLEDAS CIS- isomers (iii)if thesimilargrouplieon theoppositesidethen thegeometricalisomersare calledastrans - isomers
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| 3. |
Which of the following on hydrolysis with dilute alkali following by acidification gives benzaldehyde. |
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Answer» Benzotrichloride |
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| 4. |
When aqueous solution of borax is acidified with hydrochloric acid, a white crystalline solid is formed which is soapy to touch, is this solid acidic or basic in nature? Explain. |
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Answer» Solution :When an aqueous solution of borax is acidified with HCL boric acid is formed `Na_(2)B_(4)O_(7)+2HCl+5H_(2)Orarr2NaCl+underset("Boric acid")(4H_(3)BO_(3))` Boric acid is a white crystalline solid. It is soapy to touch because of its planar layered structure. Boric acid is a weak monobasic acid. It is not a protonic acid but ACTS as a Lewis acid by accepting electrons from a hydroxyl ion `B(OH)_(3)+2HOHrarr[B(OH)_(4)]^(-)+H_(3)O^(+)`. |
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| 5. |
Write the correct increasing order in chemical reactivity in terms of oxidizing property for N, O, F and Cl. |
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Answer» |
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| 6. |
The type of hybridisation present on "S" in SO_2 and SO_3molecules respectively |
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Answer» `SP,sp^(2)` |
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| 7. |
Which of the following statement is true. |
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Answer» 7 – BROMO cycloheptatriene (tropylium bromide) completely dissosciate in water to form `Br^(-)` ion
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| 8. |
Which of the following statements regarding 2-butene is / are right |
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Answer» It EXISTS in two geometrical ISOMERS B) The two geometrical isomers have different boiling points C) Hydrogenation is presence of Ni gives same alkane D) The two geometrical isomers are diastereoisemers |
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| 9. |
Which of the following processes involves absorption of energy? |
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Answer» `Cl_((G))+e^(-)toCl_((g))^(-)` |
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| 10. |
Which of the following principles/rules limits the maximum number of electrons in an orbital to two |
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Answer» Aufbau's principle |
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| 11. |
Which of the following arrangements shows schematic alignment of magnetic moments of antiferromagnetic substances ? |
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Answer»
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| 12. |
Which of the following statements are correct ? |
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Answer» According to Bronsted Lowry CONCEPT, `H_(2)SO_(4)` can also act as a BASE (B) SI has empty d-orbitals to accept electrons. Hence, Si`F_(4)` is a Lewis acid. |
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| 13. |
The shortest wavelength in hydrogen spectrum of Lyman series when R_(H) = 109678 cm^(-1) is |
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Answer» `1002.7 Å` For LYMAN series, `n_(1) = 1` `lamda` is shortest of `1//lamda` is largest when `n_(1) = oo` Hence, `(1)/(lamda) = 109678 ((1)/(1^(2))) = 109678 CM^(-1)` or `lamda = (1)/(109678) cm = 911.7 xx 10^(-8) cm = 911.7 Å` |
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| 14. |
what is the effect of pressure on NaCl type crystals ? |
| Answer» Solution : On increasing pressure , the COORDINATION number of NaCL type ctystals incrases from 6: 6 to 8 : 8/ | |
| 15. |
Which alkane is produced when sodium salt of butanoic acid is heated with soda lime? |
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Answer» `CH_(3)CH_(3)` |
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| 17. |
What is the SI unit of mass ? How is it defined ? |
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Answer» |
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| 18. |
Tritium nucleus contains |
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Answer» 1p+0n |
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| 19. |
Which is the longest group of the long form of the periodic table? How many elements are present in it? |
| Answer» Solution :The LONGEST group in the periodic table is group IIIB (Group 3 in IUPAC notation). There are 32 ELEMENTS in group 3. | |
| 20. |
Which of the following statement is(are) correct? |
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Answer» `H_(2)O` is a PALE blue viscous LIQUID |
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| 21. |
Which molecule among the following has both polar nad non-polar covalent bond ? |
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Answer» `NH_(4)^(+)` |
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| 22. |
What is saturated vapour pressure ? |
| Answer» Solution :At CONSTANT temperature, and evacuated container is partially filled with liquid, after some time it becomes constant, an EQUILIBRIUM is established between liquid phase and VAPOUR pressure, vapoure pressure at this stage is known as equilibrium vapour pressure or SATURATED vapour pressure. | |
| 23. |
The region of the atmosphere lying upto 11 km from earth's surface is called whereas that lying above it upto 50 km is called _____________ |
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Answer» |
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| 24. |
The reductive ozonolysis of an alkene gave butanone and ethanal. Give the structure of alkene and its IUPAC name. |
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Answer» Solution :Write the structures of the PRODUCTS with carbonyl groups facing each other. `UNDERSET("Ethanal")(CH_(3)-CH)=O+Ounderset("Butanone")(=overset(CH_(3))overset(|)C-)CH_(2)CH_(3)to` Ethana! Butanone Remove OXYGENS and put the double bond between the carbonyl carbons to get alkene `{:(""CH_(3)),("|"),(CH_(3)-CH=C-CH_(2)CH_(3)),("3-Methylpent-2-ene"):}` |
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| 25. |
The values of coefficients to balance the following reaction are Cr(OH)_(3)+ClO^(-)+OH^(-) rarr CrO_(4)^(2-)+Cl^(-)+H_(2)O |
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Answer» `{:(CR(OH)_(3),CLO^(-),CrO_(4)^(2-),CL^(-)),("2","3","3","3"):}` |
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| 26. |
Vanderwaal's constants for hydrogen chloride gas are a = 3.67 atm lit^(-2) and b = 40.8 ml mol^(-1). Find the critical temperature and critical pressure of the gas. |
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Answer» Solution :`T_(c) = (8a)/(27 RB)` `= (8 xx 3.67 )/(27 xx 0.0821 xx 0.0408) = 324.7` K `= 51.7^(@) C` `P_(c) = (a)/(27 B^(2)) = (3.67)/(27 xx (0.0408)^(2)))` `= 81.6` atm |
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| 27. |
Which one of the following pair is called an ideal solution ? |
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Answer» 1) nicotine-water |
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| 28. |
Write the relationship between K_(sp) and S of PbI_(2). |
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Answer» Solution :`PbI_(2)` belongs to `AB_(2)` type of salt. `PbI_(2)hArrPb^(2+)+2I^(-)` `[Pb^(2+)]=S" mol "dm^(-3)and[I^(-)]=2S" mol "dm^(-3)` `K_(sp)=[Pb^(2+)][I^(-)]=(S)*(2S)^(2)` `thereforeK_(sp)=4S^(3)`. |
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| 29. |
What is the value of electron gain enthalpy of Na^+ if IE_1 of Na=5.1 eV |
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Answer» `+2.55` eV |
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| 30. |
Which one is not aromatic compound ? |
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Answer»
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| 31. |
The thickness of window panes of old buildings is more at the bottom than at the top, which is due to |
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Answer» Surface tension of GLASS |
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| 32. |
What happens when Boric acid is added to water |
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Answer» |
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| 33. |
Which among of the following has same kinetic energy as O_(2) gas at NTP ? |
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Answer» `H_(2)` |
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| 34. |
What is the catalyst used in the following reaction? 2CH_(3)Cl+Sioverset("Catalyst")underset(570K)rarr (CH_(3))_(2)SiCl_(2) |
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Answer» NICKEL POWDER |
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| 35. |
Use Lewis symbols to show electron transfer between the following atoms to form cations and anions : (a) K and S (b) Ca and O (c)Al and N . |
Answer» SOLUTION :
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| 36. |
The weight of oxygen required to completely react with 27gof Al is |
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Answer» 8g |
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| 37. |
Which bond is more polar in the following pairs of molecules (a) H_(3)C- H, H_(3)C- Br (b) H_(3)C- NH_(2), H_(3)C-OH (c ) H_(3)C- OH, H_(3)C- SH |
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Answer» Solution :(a) C-Br bond is more polar than C-H. Because the electronegativity of Br is more than H. (B) C-O bond is more polar than C-N. Because the electronegativity of O is more than N. (c ) Bond POLARITY of C-O bond is more than C-S bond, Because the electronegativity of S is less. Electronegativity in period is increase. `((H),(2.1))((C),(2.5))((N),(3.0))((O),(3.5)) ((F),(4.0))` Electronegativity in GROUP is decrease. `(N gt P gt "As"), (O gt S gt Se), (F gt Cl gt Br)` The extend of bond polarity `prop` deference of electronegativity. `C - H lt C-N lt C-O lt C-F` `C- H lt C- O lt C-F lt C-Cl` `C- H lt C- S lt C - O lt C - F` `rarr` Increase polarity of bond `rarr` |
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| 38. |
Write the chemical formulae of the following: Quick lime, slaked lime, milk of lime, lime water. |
| Answer» SOLUTION :`CAO, CA(OH)_2, Ca(OH)_2, Ca(OH)_2` | |
| 39. |
Which compound is predominantly formed when phenol is allowed to react with bromine in aqueous medium? |
| Answer» Solution :2,4,6-Tribromophenol. | |
| 40. |
Which one of the following statement is not true ? |
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Answer» pH of drinking water should be between5.5-9.5. |
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| 41. |
Which of the following anionic radicals give white precipitate with magnesium nitrate reagent or magnesia mixture? |
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Answer» `HPO_(4)^(2-)` |
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| 42. |
Total number of alkyl groups having the molecular formula C_(4)H_(9) is |
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Answer» |
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| 43. |
Whenever a reaction between an oxidising agent and a reducing agent is carried out, a compound of lower oxidation state is formed if the reducing agent is in excess and a compound of higher oxidation state is formed if the oxidising agent is in excess. Justify this statement giving three illustrations. |
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Answer» Solution :The given statement can be verified by the FOLLOWING illustrations : (a) `UNDERSET(("reducing AGENT Excess"))(2C(s))+underset(("oxidising agent"))(O_(2)(g))tounderset(("Compound of lower O.S."))overset(+2)(2CO(g))""......(i)` `underset(("reducing agent"))(C(s))+underset(("oxidising angent Excess"))(O_(2)(g))tounderset(("Compound of higher O.S."))overset(+4)(CO_(2)(g))""......(ii)` In REACTION (i), the reducing agent, i.e., carbon is in excess, whereas in reaction (ii) the oxidising agent, i.e., `O_(2)` is in excess. Reaction (i) leads to the formation of CO (O.S. of C = + 2), while reaction (ii) leads to the formation of `CO_(2)` (O.S. of C=+4) (b) `underset(("reducing agent Excess"))(4Na(s))+underset(("oxidising agent"))(O_(2)(g))tounderset(("Compound of lower O.S."))(Na_(2)overset(-2)(O)(s))""......(i)` `underset(("reducing agent"))(2Na(s))+underset(("oxidising agent Excess"))(2O_(2)(g))tounderset(("Compound of higher O.S."))(Na_(2)overset(-1)(O_(2))(g))"".......(ii)` (c ) `underset(("reducing agent Excess"))(P_(4)(s))+underset(("oxidising agent"))(6Cl_(2)(g))tounderset("Compound of lower O.S.")(4overset(+3)(P)Cl_(3)(l))"".......(ii)` `underset(("reducing agent"))(P_(4)(s))+underset(("oxidising agent Excess"))(10Cl_(2)(g))tounderset("Compound or higher O.S.")(4overset(+5)(P)Cl_(5)(s))""........(ii)` |
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| 44. |
What is the shape of anionic part of (C)? |
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Answer» TRIGONAL planar |
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| 45. |
Which one of the following reagents is used for detection of unsaturation in alkenes? |
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Answer» `NaOH+CaO` |
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| 46. |
Which of the following statements about H_(2)O_(2) a true? |
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Answer» `H_2O_2` is USED oil paintings |
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| 47. |
Which of the following is not a periodic property? |
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Answer» ATOMIC radius |
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| 48. |
Which of the following reagents can be used to differentiate between Ph-underset(O)underset(||)(C)-H and CH_(3)CH_(2)OH? |
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Answer» NaOI |
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| 49. |
The value ofK_(p)" for the reaction ", CO_(2) (g) + C (s) hArr2 CO (g),is 3.0at 1000 K. Initially , p_(co_(2)) = 0.48" bar "and P_(CO)= 0 bar and opure graphite is present , calculate the equilibrium partial pressures of CO and CO_(2) |
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Answer» Solution :`{:(,CO_(2)(g) + C(s),hArr,2 CO (g)),("INTIAL",0.48 " bar ",,0 "bar"),("AT.eqm.",(0.48-p)"bar",,2" p bar"):}` ` K_(p) = (2 p)^(2)/(0.48-p )=3.0 " (Given) ".` ` :. 4 p^(2) = 1.44 - 3 p or 4 p^(2) + 3 p - 1.44=0` ` :.p = ( -b pm sqrt(b^(2) - 4 ac))/(2a)=(-3 pm sqrt ( 9-4 xx 4 ( - 1. 44)))/8` ` = ( -3 pm sqrt(32*04))/8= (-3 pm 5.66)/8 = 2.66/8 ""` (neglecting - ve value) = 0.33 ATM `:. p_(CO_(2))= 0.48 - 0.33 = 0.15 " bar" , p_(CO_(2)) = 2 xx 0.33 = 0. 66 " bar " ` |
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| 50. |
What volume of water should be added to 50 mL M/5 HCI solution to make it decimolar? |
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Answer» `=(1/5 XX 50)/1000 =0.01` (No. of gram moles `=(M xx V)/1000`) Suppose, v mL of water should be added to make it decimolar. The total volume will now be = 50 + v mL. Number of gram moles of HCI in this DILUTED solution `=(1/10 xx (50 + v))/1000` The two gram moles should be equal. THEREFORE, `=(1/10 xx (50 + v))/1000 = 0.01` which gives v=50 mL HENCE, 50 mL of water should be added to 50 mL `M/5` HCI to make it decimolar. |
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