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84401.

alpha-(D)-(-)fructose and beta-(D)-(-) differs in orientation at

Answer»

C-1
C-2
C-3
C-4

Answer :B
84402.

alpha - D -(+)- glucose and beta-D-(+)-glucose are

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Epimers
Anomers
Enantiomers
Conformers

Answer :B
84403.

alpha - D - (+) glucose and beta - D - (+) glucose are:-Metameres, Anomers, Geometrical isomers, Fuctional group isomers

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METAMERES
Anomers
Geometrical ISOMERS
FUNCTIONAL GROUP isomers

Answer :B
84404.

alpha - D (+) Glucose and beta - D (+) glucoseare ……… .

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Epimers
ANOMERS
Enantiomers
CONFORMATIONAL isomers

Answer :B
84405.

alpha-chloropropionic acid on treatment with alcoholic KOH followed by acidification gives :

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`CH_3-CH(OH)-COOH`
`CH_2=CH-COOH`
`HO-CH_2-CH_2-COOH`
NONE of above

ANSWER :B
84406.

alpha, beta and gamma forms of sulphur differ in

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OVERAL packing of rings
MOLECULAR weight
Atomicties
Their ring structure

ANSWER :A
84407.

alpha-amino acids on heating with Ba(OH)_2 gives :

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BA SALT of acid
Amine
alpha-hydroxy acids
None

ANSWER :B
84408.

alpha- Amino acids are the building blocks of proteins. About 20 alpha-amino acids have been isolated by the hydrolysis of proteins. All these amino acids except glycine are chiral and have L-configuration. Ten amino acids (valine , leucine, isoleucine , phenylalanine, methionine , trytophan , threonine , lysine , arginine and histidine) which the body cannot synthesize are called essential amino acids. The remaining ten are called non -essential amino acids. All alpha-amino acids exist are zwitterions each of which has a specific isoelectric point. Above isoelectric point , a alpha-amino acid exists as an anion. Two, three or many alpha-amino acids join together to form di-,tri -or polypeptides or proteins respectively. Each polypeptides or protein has a free amino group at one end called the N-terminal end and a free carboxyl group at the other end called the C-terimal end. Sanger's reagent (i.e., 2,4-dinitrofluorobenzene) is used to determine the N-terminal end while C-terimal end is determined by hydrazinolysis. Which of the following reagents is used to determine the C-terminal end in a polypeptide ?

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HYDRAZINE
2,4-Dintrophenylhydrazine
2,4-Dinitrofluorobenzene
3,5-Difluorenitrobenzene

Answer :A
84409.

alpha- Amino acids are the building blocks of proteins. About 20 alpha-amino acids have been isolated by the hydrolysis of proteins. All these amino acids except glycine are chiral and have L-configuration. Ten amino acids (valine , leucine, isoleucine , phenylalanine, methionine , trytophan , threonine , lysine , arginine and histidine) which the body cannot synthesize are called essential amino acids. The remaining ten are called non -essential amino acids. All alpha-amino acids exist are zwitterions each of which has a specific isoelectric point. Above isoelectric point , a alpha-amino acid exists as an anion. Two, three or many alpha-amino acids join together to form di-,tri -or polypeptides or proteins respectively. Each polypeptides or protein has a free amino group at one end called the N-terminal end and a free carboxyl group at the other end called the C-terimal end. Sanger's reagent (i.e., 2,4-dinitrofluorobenzene) is used to determine the N-terminal end while C-terimal end is determined by hydrazinolysis. The acid showing salt-like character in aqueous solution is

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acetic ACID
benzoic acid
FORMIC acid
`alpha`-aminoacetic acid.

ANSWER :D
84410.

alpha- Amino acids are the building blocks of proteins. About 20 alpha-amino acids have been isolated by the hydrolysis of proteins. All these amino acids except glycine are chiral and have L-configuration. Ten amino acids (valine , leucine, isoleucine , phenylalanine, methionine , trytophan , threonine , lysine , arginine and histidine) which the body cannot synthesize are called essential amino acids. The remaining ten are called non -essential amino acids. All alpha-amino acids exist are zwitterions each of which has a specific isoelectric point. Above isoelectric point , a alpha-amino acid exists as an anion. Two, three or many alpha-amino acids join together to form di-,tri -or polypeptides or proteins respectively. Each polypeptides or protein has a free amino group at one end called the N-terminal end and a free carboxyl group at the other end called the C-terimal end. Sanger's reagent (i.e., 2,4-dinitrofluorobenzene) is used to determine the N-terminal end while C-terimal end is determined by hydrazinolysis. An alpha-amino below its isoelectric point exists as

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`H_(3)overset(+)N-CHR-COO^(-)`
`H_(2)N-CHR-COOH`
`H_(2)N-CHR-COO^(-)`
`H_(2)overset(+)N-CHR -COOH`

Solution :Below the ISOELECTRIC point of an aminoacid, the medium is acidic in NATURE. Therefore amino ACID exists as a CATION , i.e., option (d) is correct.
84411.

alpha-amino acid may be prepared by

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WILLIAMSON synthesis
Skraup synthesis
Strecker synthesis
Knorr synthesis

Answer :C
84412.

Al(OH)_(3) is precipitate if itsproduces (a)____is (b) ____ that K_(sp)

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Answer :`[A]^(2+)[OH^(THETA)]^(3)`,b. Greater
84413.

Al(OH)_(3) darr "(white)" + OH^(-) to [Al(OH)_(4)]^(-) soluble complex White precipitate of Al(OH)_(3) reappears when

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a solution of ammonium chloride is added
a solution of ammonia is added
concentrated `HNO_(3)` is added in excess
all of these

Solution :`underset("WHITE ppt")(Al(OH)_(3))+OH^(-) to underset("soluble")([Al(OH)_(4)]^(-))`
`[Al(OH)_(4)]^(-)+NH_(4)^(+) to Al(OH)_(3) darr +H_(2)O+NH_(3) uarr`
84414.

Al(OH)_(3) darr "(white)" + OH^(-) to [Al(OH)_(4)]^(-) soluble complex Identify the correct statement with respect to the gelatinous white precipitate of aluminum hydroxide.

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FRESH precipitate dissolves by the ADDITION of strong acid and base
Precipitate develops red lake with ALIZARIN reagent.
White precipitate is SLIGHTLY soluble in excess of ammonia solution.
all of these

Solution :`Al(OH)_(3)` + Alizarin + Red lake on `Al(OH)_(3)`
84415.

Al(OH)_(3) darr "(white)" + OH^(-) to [Al(OH)_(4)]^(-) soluble complex Fe(OH)_(3) precipitate and Al(OH)_(3) precipitate can be separated by

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increasing the `OH^(-)` CONCENTRATION by SODIUM hydroxide.
increasing the `H^(+)` concentration by hydrochloric acid,
(a) and (b) both
none

Solution :`Al(OH)_(3)` dissolved in `OH^(-)` but NET `Fe(OH)_(3)`
84416.

Alocohols are compounds with general formula R-OH Alcohols are soluble in water. What is the reason?

Answer»

Solution :ALCOHOLS form HYDROGEN bonds with WATER.
84417.

Alocohols are compounds with general formula R-OH How will you convert phenol to benzene?

Answer»

SOLUTION :
84418.

Alocholic solution of KOH is used for:

Answer»

Dehalogenation
Dehydrohalogenation
Dehydration
dehydrogenation

Answer :B
84419.

Almost the following elements the configuration having the highest ionization energy is :

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[NE] `3s^2 3p^1`
[Ne] `3s^2 3p^3`
[Ne] `3s^2 3p^2`
[AR] `3d^10 4s^2 4p^3`

ANSWER :B
84420.

Almostall …………..areopticallyactiveas theyone or morechiralcarbon.

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SOLUTION :CARBOHYDRATES
84421.

Almost all amides exist in

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SOLID STATE
LIQUID state
GASEOUS state
Liquid and gaseous state.

Answer :A
84422.

Almonds are recommended for good health. They not only tend to lower the blood pressure but also contain oils which prevent conorary heart disease responsible for heart attacks. But hemant, a class XII student, told his mother that some of the almonds are bitter in taste. these bitter almonds contain a poison and eating a few of these in one sitting may kill a child. After reading the above passage, answer the following questions: (i) Name the chemical present in bitter almonds an write its hydrolysis products. (ii) How does this chemical act as a poison? (iii) Write the uses of the other hydrolysis products. (iv) What values are displayed by hemant?

Answer»

SOLUTION :(i) Bitter ALMONDS contain the chemical amygdalin. It, on acid or enzymatic hydrolysis, gives benzaldehyde, glucose and hydrocyanic (HCN) acid.
`underset("Amygdalin")(C_(20)H_(27)O_(11)N)+2H_(2)O underset("or Enzyme EMULSION")OVERSET(H^(+))tounderset("Benzaldehyde")(C_(6)H_(5)CHO)+underset("Glucose")(2C_(6)H_(12)O_(6))+HCN`
(ii) HCN acts as a poison and kills the person in higher doses.
(iii) The other hydrolysis products are glucose and benzaldehyde. Whereas glucose is used as a food but benzaldehyde is used as a flavouring agent in biscuit making and in perfume industry.
(iv) Hemant has displayed health conscious values by emphasizing that all bitter things should be taken only after careful examination.
84423.

Allylic allohols may be

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`1^@`TYPES
`2^@` types
`3^@` types
`1^@`, `2^@`, `3^@` types

ANSWER :D
84424.

Allyl isocyanide contains sigmaand pi bonds respectively as:

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`9sigma, 3pi`
`9sigma, 9pi`
`3sigma, 4PI`
`5sigma, 7pi.`

SOLUTION :ALLYL isocyanide is
`overset(H)overset(|)underset(H)underset(|)C=overset(H)overset(|)C-overset(H)overset(|)C-overset(H)overset(|)underset(H)underset(|)C-N-=C""9sigma and 3pi"bonds"`
84425.

Allyl isocyanide contains sigma and pi bonds, as

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`9 SIGMA` and `3pi`
`9 sigma` and `9 PI`
`3 sigma` and `4 pi`
`5 sigma` and `7 pi`.

Solution :`underset("ALLYL isocyanide")(C=N-CH_(2)-CH=CH_(2))`
It CONTAINS `9 sigma` and `3pi` bonds.
84426.

Allyl isocyanide has

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9 SIGMA BONDS and 4 PI bonds
8 sigma bonds and 5 pi bonds
8 sigma bonds, 3 pi bonds and 4 non-bonding electrons
9 sigma bonds, 3 pi bonds and 2 non-bonding electrons.

Solution :Allyl ISOCYANIDE `CH_(2)=CH-CH_(2)-N-=C`
84427.

Allyl isocyanide contains ……..and …….bonds :

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`9 SIGMA ` and `3pi`
`9 sigma ` and `9pi`
`3 sigma ` and `4PI`
`5sigma ` and `7pi`

ANSWER :A
84428.

Allyl iodide can be obtained from allyl chloride. Explain.

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Solution :Allyl chloride when heated with SODIUM iodide in PRESENCE of acetone, allyl iodide is formed.
`CH_(2)= CH-CH_(2)Cl + NaI UNDERSET("HEAT,"-NaCl)overset("acetone")rarr CH_(2)=CH-CH_(2)I`
This is a halogen exchange reaction and is called Finkelstein reaction
84429.

Allyl cholride can be distinguished from vinyl chloride by NaOH and silver nitrate test.

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Solution :Vinyl chloride does not respond to NAOH and silver nitrate test because of DOUBLE bond character DUE to resonance. This STOPS the release of chloride IONS.
84430.

Allyl chloride on dehydrochlorination gives:

Answer»

Propadiene
Propylene
Allyl alcohol
Propene

Answer :B
84431.

Allyl chloride on dehydrochlorination gives

Answer»

PROPADIENE
propylene
acetyl chloride
acetone

Solution :`UNDERSET("Allyl chloride")(CH_(2)=CH-CH_(2)Cl)overset("Dehydrohalogenation")underset(Alc. KOH)rarr underset("Propadiene")(CH_(2)=C)=CH_(2)+KCl+H_(2)O`
84432.

Allyl chloride on dehydrochlorination gives …….

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Propadiene
Propylene
Alkyl ALCOHOL
Acetone

Solution :`Cl-CH_(2)-CH=CH_(2)overset(KOH (alc.)Delta)UNDERSET(-HCl)RARR underset("Propadiene")(CH_(2)=C=CH_(2))`
84433.

Allyl chloride is hydrolysed more readily than n-propyl chloride. Why ?

Answer»

Solution :Allyl chloride shows HIGH reactivity as the carbocation formed by HYDROLYSIS is stabilized by resonance while no such stabilization of carbocation EXISTS in case of n-propyl chloride.
84434.

Allyl chloride is hydrlysed more readily than n-propyl chloride. Why?

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Solution :In `S_(N)1` reactions, carbocations are the intermediates. OBVIOUSLY more stable the carbocation, more reactive is the alkyl halide. Since ALLYL chloride upon ionization gives allyl cation which is stabilized by RESONANCE but the carbocation obtained from n-propyl chloride is not, therefore, allyl chloride UNDERGOES hydrolysis MUCH faster than n-propyl chloride.
84435.

Allyl bromide and n- propyl bromide can be distinguished by:

Answer»

`AgNO_3` SOLUTION
`NAOH` solution
Tollen's reagent
baeyer's reagent

Answer :D
84436.

Allyl bromide is 3-bromopropene.

Answer»
84437.

Alloys of which metal are light and strong and used in the manufacture of aeroplanes :

Answer»

Cr
Sn
Fe
Mg

Answer :D
84438.

Alloys of which metal are light and strong and are used in the manufacture of aeroplane parts:

Answer»

Cr
Sn
Fe
Mg

Answer :D
84439.

Alloys are generally prepare to modify the property A) malleability B) toughness C) resistance to corrosion

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A and B are CORRECT
A and C are correct
B and C are correct
All are correct

ANSWER :D
84440.

Alloyused in making anchors, bolts, chains and wires

Answer»

PIG iron
Cast iron
Wrought iron
german silver

Answer :C
84441.

Alloy used for making ball mills

Answer»

NICKEL STEEL
MANGANESE steel
TUNGSTEN steel
CHROME steel

Solution :Manganese steel
84442.

Alloy Select the correct statement based on the above scheme :

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Layer X CONTAINS Zinc & Silver
Layer Y contains LEAD & silver but the AMOUNT of silver in the layer Y is SMALLER than in the layer X
X and Y immiscible layers
All are correct statements

Solution :All statements are correct.
84443.

Alloy of .... Metal are light and strong and so are used in the manufacture of aeroplane parts

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Cr
Sn
Fe
Mg

Solution :Duralumin (Al=95% , Cu=4%, Mn =0.5% , Mg=0.5 % ) Being LIGHT, TOUGH and durable is used for the MANUFACTURE of aeropolanes and automobiles parts.
84444.

Alloy of Misch metal consists of

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95% of actionoid metal, +5% IRON
95% of alkali metal, 5% iron
95% of LANTHANOID metal, +5% iron
95% of alkaline EARTH metal, + 5% iron

Answer :C
84445.

Alloy is an example of :

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Gel
Aerosal
Solid sol
Emulsion

Answer :C
84446.

Alloy formation ability of transition elements is due to

Answer»

same crystalline structures
same ATOMIC radii
SIMILAR CHEMICAL PROPERTIES
anyone of these properties

Solution :anyone of these properties
84447.

Alloy formation gives rise to:

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DECREASE in corrosion
Increase in hardness
Decrease in conductivity
All are correct

Answer :D
84448.

Allotropic form of phosphorous which show chemiluminescence

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WHITE phosphorous
Black phosphorous
Red phosphorous
All of the above

Answer :A
84449.

Allotropy is due to ___________

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DIFFERENCE in CHEMICAL PROPERTIES
difference in the NUMBER of atoms in the MOLECULES
difference in the arrangement of atoms in the molecules in the crystal
None of these

Answer :C
84450.

Allotrophic form of oxygen is ……………..and ………………. .

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SOLUTION :DIOXYGEN and OZONE