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84451.

Allotrope of sulphur which shows paramagnetic behaviour

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`S_(8)` - Rhombic
`S_(8)`- MONOCLINIC
`S_(2)`- In vapour phase
Not possible

Answer :A::B::C
84452.

Allergy in the body is caused by the production of-

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vitamins
harmone
histamine
ezymes

Answer :C
84453.

Alldehydes and Ketones react with NH_(2)OH to form aldoximes and Ketoximes respectively. Configuration of these can be determined by Beckmann rearragement as that group migrates which is anti w.r.t -OH Which step is Rate determening step ?

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I
II
III
IV

ANSWER :B
84454.

Alldehydes and Ketones react with NH_(2)OH to form aldoximes and Ketoximes respectively. Configuration of these can be determined by Beckmann rearragement as that group migrates which is anti w.r.t -OH [X] overset(H_(2)SO_(4))to overset(H_(2)O)to Ph-NH_(2)+CH_(3)-underset(O)underset(||)(C)-OH Identify the configuration of [X] compound

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ANSWER :A
84455.

All three amines 1^@,2^@,3^@ react with 1. H_2O , 2.R-X , 3.HCl , 4.(CH_3CO)_2O

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1,2
4 only
1,2,4
1,2,3

Answer :D
84456.

All though electron gain enthalpy of fluorine is less negatibe as compared to chlorine, Fluorine is stronger oxidizing agent then Chlorine becose of (i) Low Enthelpy of dissociation of F-F bond

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I,II, correct
I,III correct
I, ii, iii correct
ii, iii correct

Solution :CONCEPTUAL
84457.

All three amine 1^(0),2^(0),3^(0)arereactwith

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1,2
only 4
1,2,4
1,2,3

Answer :D
84458.

All the three amines (pri-, sec- and tert-) react with

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KOH
RX
HCl
`CH_(3)COCl`

ANSWER :A::B::C
84459.

All the substances become diamagnetic at :

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4 K
10 k
20 K
25 K

Answer :A
84460.

All the s-block elements of the periodic table are placed in the group…..

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IA and IIA
IIIA and IVA
B SUB groups
VA to VIIA

Answer :A
84461.

All the oxygen in 0.5434g sample of pure oxide of iron is removed by reduction in a stream of H_(2). The loss in weight is 0.1210g. What is the formula of the oxide of iron ? (At. Mass of Fe = 56)

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SOLUTION :Iron oxide = 0.5434 g
Oxygen lost as `H_(2)O=0.1212g`
`therefore"Iron "=0.5434-0.1210=0.4224g`
`therefore""%" of FE"=(0.4224)/(0.5434)xx100=77.73%`
`%" of O=100-77.73=22.27%`

Hence, formula of iron oxide = FEO.
84462.

All the nuclei from the initial element to the final element constitute a series which is called

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g-SERIES
b-series
b-g series
DISINTEGRATION series

Solution :DEFINITION of disintegration series.
84463.

All the naturally occuring processes proceed spontaneously in a direction which leads to

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DECREASE of entropy
Increase of enthalpy
Increase of FREE energy
Decrease of free energy

Answer :D
84464.

All the naturally occuring process i.e., spontaneous proceed spontaneously in a direction which leads to:

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DECREASE of FREE energy
Increase of free energy
Decrease of entropy
Increase of entropy

Answer :A
84465.

All the metals form oxides of the type MO except

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Copper
Barium
Silver
Lead

Answer :C
84466.

All the metals or iron family have a strong magnetic property commonly referred as

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Diamagnetism
Paramagnetism
Ferromagnetism
none of these

Answer :C
84467.

All the lanthanoids are_______________soft metals and______________rapidly in air.

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SOLUTION :SILVERY WHITE, TARNISH
84468.

All the interhalogen compoundsexcept one which has AX_(n) type, can be prepared by direct combination of halogens under appropriate conditions. What is the maximum value of n"___________".

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SOLUTION :`AX_(N)` TYPE `: IF_(7)AX_(y)` maximum value of n 7
84469.

All the following substances react with water. The pair which gives the same gaseous product is:

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K and `KO_2`
NA and `Na_2 O_2`
Ca and `CaH_2`
BA and `BaO_2`

Answer :C
84470.

All the following statements are correct except……………..

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All the DISACCHARIDES are reducing sugars.
All the monosaccharides are reducing sugars
All the carbohydrates are optically active
All the carbohydrates have ALDEHYDE or ketone as a principal functional GROUP.

SOLUTION :All the disaccharides are reducing sugars.
Sucrose is a non-reducing sugar
84471.

All the following complexes show decrease in their weights when placed in a magnetic balance then the group of complexes having tetrahedral geometry is : (P) Ni(CO)_(4)""(Q) K[AgF_(4)] (R) Na_(2)[Zn(CN)_(4)]""(S) K_(2)[PtCl_(4)] (T) [RhCl(PPh_(3))_(3)]

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<P>Q, R, T
P, Q, R
P, R, S
None of these

Solution :(P) and (R ) are TETRAHEDRAL.
84472.

All the following reactions are SN^2 reactions except

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ANSWER :C
84473.

All the following complexes show a decrease in their weights when placed in a magnetic balance. Then Which of these has square planar geometry?

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`Ni(CO)_(4)`
`K[AgF_(4)]`
`Na_(2)[ZN(CN)_(4)]`
None of these

Solution :`overset(+1)K[overset(+3)AgF_(4)]implies d^(8)`
Although, `F^(-)` is a WFL, but DUE to high charge on `Ag(+3),C.F.S.E.uparrow`
84474.

All the following complex ions are found to be paramagnetic P=[FeF_(6)]^(3-)Q=[CoF_(6)]^(3-)R=[V(H_(2)O)_(6)]^(3+)S=[T:(H_(2)O)_(6)]^(3+) The correct order of their paramagnetic moment (spin only) is

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`PgtQgtRgtS`
`PltQltRltS`
P=Q=R=S
`PgtRgtQgtS`

Solution :Both F and `H_(2)O` are WEAK field ligands. So no regrouping of ELECTRONS occurs. HENCE the unpaired electrons will be LEFT as such (5, 4, 2, 1)
84475.

All the following are the effects of depletion of ozone layer, except

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It can cause SKIN cancer
It INCREASES transpiration in PLANTS and hence decreases soil moisture
It increases the acidity of soil
It damages the paints over the BUILDINGS causing them to FADE faster

Answer :C
84476.

All the energy released from the reaction XtoY,Delta_(r)G^(@)=-193" kJ "mol^(-1) is used for oxidizing M^(+) as M^(+)toM^(3+)+2e^(-),E^(@)=-0.25V. Under standard conditions, the number of moles of M^(+) oxidized when one mole of X is converted to Y is (F=96500" C "mol^(-1)).

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Solution :`XtoY,Delta_(r)G^(@)=-193" kJ "mol^(-1)`. . . (i)
`M^(+)toM^(3+)+2E^(-),E^(@)=-0.25V`
For this reaction, `DeltaG^(@)=-nFE^(@)`
`=-2xx96500xx(-0.25)=48250" J "mol^(-1)`
`=48.25" kJ "mol^(-1)`
i.e., 48.25 kJ of energy is used for oxidizing 1 mole of `M^(+) ` to `M^(3+)`
`therefore` No. of moles of `M^(+)` oxidized by 193 kJ of energy `=(193)/(48.25)=4`
84477.

All the energy realesed from the reation X rarr Y, Delta_(r) G^(@) = -193 kJ mol^(-1), is used for oxidizing M^(+) as M^(+) rarr M^(3+) + 2e^(-), E^(@) = -0.25 V. Under standard consistions, the number of moles of M^(+) oxidized when on e mol of X is converted to Y is [F = 96,500 C "mol"^(-1)]

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ANSWER :4
84478.

All the energy released from the reaction XrarrY, Delta_(r)G^(@)=-193 kJ mol^(-1) is used for oxidizing M^(+) as M^(+)rarrM^(3+)+2e^(-), E^(@)=-0.25 V Under standard conditions, the number of moles of M^(+) oxidized when one mole of X is converted to Y is [f=96500 C mol^(-1)]

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Solution :`m^(+)rarrm^(3+)+2E^(-)`
`DeltaG^(@)=-nFE^(@)" For 1 mole of "m^(+)`
`DeltaG^(@)=-2xx96500xx(-0.25)J`
`=+48250 J//"mole"=48.25KJ//"mole"`
ENERGY released by conversion of 1 mole of
`XRARRY DeltaG=-193 KJ`
Hence mole of `m^(+)` convert `(193)/(48.25)=4`
84479.

All the elements, on the basis of long form of periodic table, can be divided into four blocks, s,p, d and f. the ionization energies, electron affinities, electronegativities, atomic and ionic radii and other physical properties usually shown a regular pattern of change within a group or along period with some irregularities. Q. Which of the following element has the maximum value of electronegativity?

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Aluminium
Silicon
Phosphorus
Sulphur

Answer :D
84480.

All the elements, on the basis of long form of periodic table, can be divided into four blocks, s,p, d and f. the ionization energies, electron affinities, electronegativities, atomic and ionic radii and other physical properties usually shown a regular pattern of change within a group or along period with some irregularities. Q. Which of the following element has the maximum electron affinity?

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Nitrogen
Oxygen
Fluorine
Chlorine

Answer :D
84481.

All the elements, on the basis of long form of periodic table, can be divided into four blocks, s,p, d and f. the ionization energies, electron affinities, electronegativities, atomic and ionic radii and other physical properties usually shown a regular pattern of change within a group or along period with some irregularities. Q. On moving from Li to F in the second period, there would be a decrease in :

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non-metallic property
atomic radius
ionization potential
electronegativity

Answer :B
84482.

All the elements of the oxygen family are:

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NON- metal
Metalloids
Radioactive
Polymorphic

Answer :D
84483.

All the elements in a group (family) have a common valency. For example , all the elements of the carbon family (carbon, silicon , germanium , tin and lead) have common valency four . However , some of these elements can also have valency two . Which of the following can have valency two ?

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Silicon , germanium and tin
Only germanium and tin
Germanium , tin and LEAD
Only tin and lead

Solution :`{:(GE - +2 "," +4) , (Sn - + 2 "," + 4), (PB- + 2 "," + 3):}`
84484.

All the elements belonging to second period are:

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NORMAL elements
Transition elements
Stable elements
Halogens

Answer :A
84485.

All the element from nitrogen family have two paired s-electron and three unpaired p-electron in their valence shell thus exhibit three covalence, by sharing of three electron pair to attain stable noble gas configuration except nitrogen all have got vacant d-orbital. All the element of this group exhibit +3 oxidation state in hydride. The tendency to show-3 ionic nature is not possible due to high energy consideration. However, nitrogen being smallest and most electronegative and thus forms N^(3) ion in nitrides such as Mg_(3)N_(2). Ca_(3)N_(2) etc. Rest of all shows -3 oxidation state in covalent compounds. The +3 oxidation state are covalent and ionic both. The +5 oxidation states are covalent as they can not from M^(+5) ions due to high energy involve there in. The tendency to show M^(+3) ionic state however increase down the group due to inert pair effect. The most unstable hydride among the following is:

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`NH_(3)`
`PH_(3)`
`AsH_(3)`
`BiH_(3)`

Answer :D
84486.

All the element from nitrogen family have two paired s-electron and three unpaired p-electron in their valence shell thus exhibit three covalence, by sharing of three electron pair to attain stable noble gas configuration except nitrogen all have got vacant d-orbital. All the element of this group exhibit +3 oxidation state in hydride. The tendency to show-3 ionic nature is not possible due to high energy consideration. However, nitrogen being smallest and most electronegative and thus forms N^(3) ion in nitrides such as Mg_(3)N_(2). Ca_(3)N_(2) etc. Rest of all shows -3 oxidation state in covalent compounds. The +3 oxidation state are covalent and ionic both. The +5 oxidation states are covalent as they can not from M^(+5) ions due to high energy involve there in. The tendency to show M^(+3) ionic state however increase down the group due to inert pair effect. Pick up incorrect statement:

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`PH_(4)^(+)` ion tetrahedral LIKE `NH_(4)^(+)` and is obtained when `PH_(3)` is bonded to proton.
`PH_(4)I` is most stable containing phosphonium ion, it is also more stable than ammonium salt.
`PH_(4)l` is a decomposed by WATER to form `PH_(3)`.
`PH_(3)` converts SILVER salts in solution to silver phosphide which subsequently reach to give free metal.

Answer :B
84487.

All the element from nitrogen family have two paired s-electron and three unpaired p-electron in their valence shell thus exhibit three covalence, by sharing of three electron pair to attain stable noble gas configuration except nitrogen all have got vacant d-orbital. All the element of this group exhibit +3 oxidation state in hydride. The tendency to show-3 ionic nature is not possible due to high energy consideration. However, nitrogen being smallest and most electronegative and thus forms N^(3) ion in nitrides such as Mg_(3)N_(2). Ca_(3)N_(2) etc. Rest of all shows -3 oxidation state in covalent compounds. The +3 oxidation state are covalent and ionic both. The +5 oxidation states are covalent as they can not from M^(+5) ions due to high energy involve there in. The tendency to show M^(+3) ionic state however increase down the group due to inert pair effect. Collectively the element of group 15 are called

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Pnicopens
Pnicogens
Nicopen
Pnictide

ANSWER :B
84488.

All the element from nitrogen family have two paired s-electron and three unpaired p-electron in their valence shell thus exhibit three covalence, by sharing of three electron pair to attain stable noble gas configuration except nitrogen all have got vacant d-orbital. All the element of this group exhibit +3 oxidation state in hydride. The tendency to show-3 ionic nature is not possible due to high energy consideration. However, nitrogen being smallest and most electronegative and thus forms N^(3) ion in nitrides such as Mg_(3)N_(2). Ca_(3)N_(2) etc. Rest of all shows -3 oxidation state in covalent compounds. The +3 oxidation state are covalent and ionic both. The +5 oxidation states are covalent as they can not from M^(+5) ions due to high energy involve there in. The tendency to show M^(+3) ionic state however increase down the group due to inert pair effect. Pick out the incorrect statement:

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Red phosphorus cansist of complex CHAIN structure is BLACK phosphorus has layer structure.
Nitrogen shows LITTLE tendency for catenation becauser H-N bond is very strong.
The maximum number of covalent bond formed by nitrogen is four, it has no d-orbitals in its valence shell.
The group 15 element do not form `M^(+5)` ion but +5 oxidation state is realized only TROUGH covalent bonding.

Answer :B
84489.

All the compounds listed in column I react with water. Match the result of the respective reactions with the appropriate options listed in column II.

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ANSWER :A::B::C::D
84490.

All the compounds listed in Column I react with water. Match the result of the respective reactions with the appropriate options listed in column II

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ANSWER :A::B::C::D
84491.

All the complexes of Pt(+II)" and "Au(+III) with strong field as well as with weak field ligands are square planar. Statement-2: The crystal field splitting Delta_(0) is larger for second and third row transition elements, and for more highly charged species. This larger value of Delta_(0) energetically favours the pairing of electron for square planar geometry.

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Statement-1 is TRUE, Statement-2 is True , Statement-2 is a CORRECT EXPLANATION for Statement-1.
Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for Statement-1.
Statement-1 is True, Statement-2 is FALSE.
Statement-1 is False, Statement-2 is True.

Answer :A
84492.

All the boron trihalides exceptBI_(3) may be prepared by direction between the elements. Boron trihalides consist of trigonal-planar BX_(3) molecules. Unlike the halides of the other elements in the group they are monomeric in the gas, liquid and solid states, BF_(3) and BCl_(3) are gases, BBr_(3) is a volatile liquid and BI_(3) is a solid. Boron trihalides are Lewis acids because they form simple Lewis complexes with suitable bases, as in the reaction: BF_(3)(g)+NH_(3)(g)toF_(3)B-NH_(3)(s) However, boron chlorides, bromides and iodides are susceptible (sensitive) to protolysis by mild proton sources such as water, alcohols and even amines, for example BCl_(3) undergoes rapid hydrolysis: BCl_(3)(g)+3H_(2)O(l)toB(OH)_(3)(aq)+3HCl (aq)It is supposed that the first step in the above reaction is the formation of the complex Cl_(3)B larr OH_(2) which then eliminates HCl and reacts with water. Which of the following reactions is incorrect ?

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`BF_(3)(g) +F^(-)(aq)rarr [BF_(4)]^(-)(aq)`
`BCl_(3)(g)+3EtOH(l)toB(OEt)_(3)(l)+3HCL (g)`
`BBr_(3)(l)+F_(3)BN(CH_(3))_(3)(s)toBF_(3) (g)+Br_(3)BN(CH_(3))_(3)(s)`
`BCl_(3) (g)+2 C_(5)H_(5)N (l)toCl_(3)B(C_(5)H_(5)N)_(2) (s)`

Solution :Since `BCl_(3)` can accept only one lone pair hence `Cl_(3)B(C_(5)H_(5)N)_(2)` is not possible.
84493.

All the boron trihalides exceptBI_(3) may be prepared by direction between the elements. Boron trihalides consist of trigonal-planar BX_(3) molecules. Unlike the halides of the other elements in the group they are monomeric in the gas, liquid and solid states, BF_(3) and BCl_(3) are gases, BBr_(3) is a volatile liquid and BI_(3) is a solid. Boron trihalides are Lewis acids because they form simple Lewis complexes with suitable bases, as in the reaction: BF_(3)(g)+NH_(3)(g)toF_(3)B-NH_(3)(s) However, boron chlorides, bromides and iodides are susceptible (sensitive) to protolysis by mild proton sources such as water, alcohols and even amines, for example BCl_(3) undergoes rapid hydrolysis: BCl_(3)(g)+3H_(2)O(l)toB(OH)_(3)(aq)+3HCl (aq)It is supposed that the first step in the above reaction is the formation of the complex Cl_(3)B larr OH_(2) which then eliminates HCl and reacts with water. Which is correct about the hydrolysis of BX_(3)?

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All `BX_(3)` UNDERGO hydrolysis to produce `B(OH)_(3) (aq)` and `HX(aq)`.
`BF_(3)` does not undergo complete hydrolysis due to formation of `HBF_(4)`
`BBr_(3)` does not undergo hydrolysis at all because it cannot FORM `H`-bonds with water.
All the above are correct

Solution :Some of the total `BF_(3)` combine with `HF` formed during hydrolysis to form `HBF_(4)`.
84494.

All the boron trihalides exceptBI_(3) may be prepared by direction between the elements. Boron trihalides consist of trigonal-planar BX_(3) molecules. Unlike the halides of the other elements in the group they are monomeric in the gas, liquid and solid states, BF_(3) and BCl_(3) are gases, BBr_(3) is a volatile liquid and BI_(3) is a solid. Boron trihalides are Lewis acids because they form simple Lewis complexes with suitable bases, as in the reaction: BF_(3)(g)+NH_(3)(g)toF_(3)B-NH_(3)(s) However, boron chlorides, bromides and iodides are susceptible (sensitive) to protolysis by mild proton sources such as water, alcohols and even amines, for example BCl_(3) undergoes rapid hydrolysis: BCl_(3)(g)+3H_(2)O(l)toB(OH)_(3)(aq)+3HCl (aq)It is supposed that the first step in the above reaction is the formation of the complex Cl_(3)B larr OH_(2) which then eliminates HCl and reacts with water. Which of the following is the correct prediction about observed B-X bond length, in BX_(3) molecules?

Answer»

`B-F` bonf length in `BF_(3)` is FOUND to be less than theoretical value because the electronegativity values of `B(2.04)` and `F(4.0)` suggest the bond to be ionic and hence the attraction between oppositely charged ions MUST decrease the bond length
`BF_(3)` and `[BF_(4)]^(-)` have EQUAL `B-F` bond length
The decrease in the `B-F` bond length in `BF_(3)` is DUE to delocalised `p_(pi)-p_(pi)` bonding between VACANT `'2p'` orbital of `B` and filled `'2p'` orbital of `F`.
The correct `B-X` bond length order is `B-FgtB-ClgtB-BrgtB-I`

Solution :N//A
84495.

All the actinoids are ................ and most of them have .......... half lives.

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SOLUTION :RADIOACTIVE, SHORT
84496.

All terpenes have carbon skeletons made up of:

Answer»

Isoprenes UNITS
VINYL units
ALKENES
ETHYLENE units

ANSWER :A
84497.

The correct order of solubility of the sulphates of alkaline earth metals in water is

Answer»

`Mg GT CA gt BA gt Be gt SR`
`Be gt Mg gt Ca gt Sr gt Ba`
`Be gt Ca gt Mg gt Ba gt Sr`
`Mg gt Be gt Ba gt Ca gt Sr`

Answer :B
84498.

All spinel structures do not have

Answer»

CCP array of anions
Simple CUBIC STRUCTURE
BCC array of anions
HCP array of anions

Answer :B::C::D
84499.

All sixteen possible aldohexose have been isolated or synthesised. Only three occurin nature thereare :

Answer»

D-glucose
D-galatose
D-mannose
L-mannose

Solution :N//A
84500.

All reactions which have chemical disintegration

Answer»

Is REVERSIBLE
Is reversible and ENDOTHERMIC
Is EXOTHERMIC
Is reversible or IRREVERSIBLE and endothermic or exothermic

ANSWER :D