This section includes InterviewSolutions, each offering curated multiple-choice questions to sharpen your knowledge and support exam preparation. Choose a topic below to get started.
| 85051. |
Addition of 0.643 g of a compound to 50 mL of benzene (density : 0.879 g/ml) lowers the freezing point from 5.51^(@)C to 5.03^(@)C. If K_(f) for benzene is 5.12,calculate the molecular weight of the compound. |
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Answer» |
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| 85052. |
Addition of 0.643 g of a compound to 50 mL of benzene (density 0.679 h/mL) lower the freezing point from 5.51^(@)C to 5.03^(@)C. If K_(f)=5.12 km^(-1), calculate the molecular mass of the compound. |
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Answer» `Deltat_(F)=5.51-5.03=0.48^(@)C=0.48 K, K_(f)=5.12" K kg mol"^(-1)` `M_(B)=(W_(B)xxK_(f))/(DeltaT_(f)xxW_(A))=((5.12" g kg mol"^(-1))xx(0.643g))/((0.48 K)xx(0.04395 kg))=156" g mol"^(-1)` |
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| 85053. |
Adding powdered Pb and Fe to a solution containing 1.0 M each of Pb^(+2) and Fe^(+2) ions would result in the formation of : |
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Answer» More of PB and `FE^(+2)` ions |
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| 85054. |
alculate the wavenumber for the shortest wavelength transition in the Balmer series of atomic hydrogen. |
| Answer» SOLUTION :`27419 CM^(-1)` | |
| 85055. |
Addison's disease can be cured by |
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Answer» GLUCOCORTICOIDS |
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| 85056. |
Adding powdered lead and iron to a solution that is 1M in both Pb^(2+) and Fe^(2+)ions, would results to a reaction in which (E^@ Fe^(2+)//Fe = -0.44V, E^@Pb^(2+)//Pb = -0.13V) |
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Answer» more AMOUNT of PB and FE is formed |
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| 85058. |
Adding of Cl_2 to benzene in the presence of AlCl_3 is an example of |
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Answer» Addition
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| 85059. |
Adding alum to turbid water, impurties are removed due to - |
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Answer» Coagulation |
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| 85060. |
Alcohols which can give white turbidity immediately on reaction with Lucas reagent are : |
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Answer»
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| 85061. |
Adding a few drops of dilute HCl to freshly precipated ferric hydroxide produces a red-coloured colloidal solution. This phenomenon is known as |
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Answer» PROTECTIVE action |
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| 85062. |
Addition of excess of sodium hydroxidesolution to a solution of nickel sulphate result in the formation of a: |
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Answer» GREEN precipitate |
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| 85063. |
Alcohols undergo dehydration in the following sequence : |
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Answer» `1^@ gt 2^@ gt 3^@` |
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| 85064. |
Add 4.00 xx 10^(-2) , 3.26 xx 10^(-3)and 1 xx 10^(-6)to the correct number of significant digits : |
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Answer» `4.3261 XX 10^(-2)` ` = 4.33 xx 10^(-2)` (upto two decimal PLACES as in `4.00 xx 10^(-2)`) |
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| 85065. |
Adam's catalyst is : |
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Answer» PT and PtO |
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| 85066. |
Acylic stereioisomers having the molecular formula C_(4)H_(7)Cl are classified and tabulated. Find out the correct set of numbers |
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Answer» `{:("Geometrical",,"Optical"),(""6,,""2):}` `{:(""Cl),("|"),(CH_(2)=CH-C_(**)-CH_(3)),("|"),(""underset("one asymmetric carbon")(H)):}` THEREFORE, number of optical ISOMERS `= 2^(n) = 2^(1) = 2`. Two geometrical isomers of each compound are possible for the following structures. `ClHC = CH-CH_(2)-CH_(3), ClH_(2)C-CH=CH-CH_(3)` and `{:(CH_(3)-C=CH-CH_(3)),("|"),(""Cl):}` |
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| 85067. |
Acylation process is preferred than direct alkylation because (by the Friedel-Craft's reaction) |
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Answer» In alkylation, a poisonous gas is evolved |
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| 85068. |
Alcohols reacts with sodium metal to release hydrogen gasTrue/False |
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Answer» |
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| 85069. |
Acylation of —NH_2 group in aniline reduces its reactivity in electrophilic substitution reactions. |
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| 85070. |
Alcohols react with Grignard reagent to form |
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Answer» Alkanes
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| 85071. |
Acylation of benzene to produce aliphatic aromatic ketones is known as |
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Answer» BENZOIN condensation This is Friedel-Craft's reaction |
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| 85072. |
Alcohols react with ceric ammonium nitrate reagent and give : |
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Answer» BLUE ppt |
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| 85073. |
Acylation of alkyl phenyl ether gives |
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Answer» 2-alkoxy alkyl PHENYL KETONE (MAJOR) |
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| 85074. |
Alcohols react with active metals e.g., Na, K, etc. To give corresponding alkoxides. Write down the decreasing order of reactivity of sodium metal towards primary, secondary and tertiary alcohols. |
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Answer» SOLUTION :Decreasing ORDER of REACTIVITY of sodium metal is : `1^(@) gt 2^(@) gt 3^(@)` |
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| 85075. |
Alcohols react with active metals, e.g., Na, K etc. to give corresponding alkoxides. Write down the decreasing order of reactivity of sodium metal primary, secondary and tertiary, |
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Answer» Solution :`to` The ORDER of reactivity of alcohols with sodium metal is of order: `"Primary alcohol"GT"Secondary alcohol" gt"Tertiary alcohol"` `to`The +I effect of the alkyl groups increases the electron density on the OXYGEN atom as a result of which the electropositive HYDROGEN of -OH group is more tightly held by the molecule which makes the release of H+ difficult. The effect if more pronounced if the alkyl groups are more in the molecule. Thus, tertiary alcohol is least acidic.
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| 85076. |
Acylation and benzoylation of Aniline aer……………. Reactions. |
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| 85077. |
Alcohols react with activemetals, e.g., Na, K, etc. to give corresponding alkoxides. Wriite down the decreasing order of reactivity of sodium metal towards primary, secondary and tertiary alcohols. |
Answer» Solution :Alkyl GROUPS have +I-effect. As the number of alkyl groups increases from 1 to 2 3 in going from `1^(@)` to `2^(@)` to `3^(@)` alcohols, the electron density in the O-H BOND increases and the bond BECOMES stronger and stronger. In other words, acidic character of alcohols decreases from `1^(@)` to `2^(@)gt3^(@)` Since Na metal is basiic and alcohols are acidic in nature, therefore, reactivity of Na metal towads alcohols decreases as the acidic strenth of alcohols decreases, i.e., in the ORDER: `1^(@) gt 2^(@) gt 3^(@)` |
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| 85078. |
Acyl halides are prepared by the action of _____on carboxylic acids. |
| Answer» Solution :Thiony chloride `(SOCl_(2))`. Or PHOSPHORUS pentachloride or TRICHLORIDE `(PCl_(5)` or `PCl_(3))` | |
| 85079. |
Acyl halide is formed by reacting PCl_(5) with : |
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Answer» alcohol |
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| 85080. |
Actylene reacts with ammonical Cu_(2)Cl_(2) to give precipitate of |
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Answer» RED colour |
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| 85081. |
Actully 18-crown- 6 ether means, |
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Answer» 18-oxygen and 6 carbon |
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| 85082. |
Activity of disinfectant is expressed by ....... |
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Answer» KETONE COEFFICIENT |
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| 85083. |
Alcohols of low molecular weight are : |
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Answer» SOLUBLE in WATER |
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| 85084. |
Actone and acetophenone can be identified by : |
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Answer» Burning the compound on SPATULA |
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| 85085. |
Alcohols of high molecular masses are |
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Answer» HIGH B.P. and excessible SOLUBILITY |
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| 85086. |
Activity of a radioactive substance is A_(1) at time t_(1) and A_(2) at time t_(2)(t_(2) gt t_(1)) , then the ratio of f(A_(2))/(A_(1)) is: |
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Answer» `E^(LAMBDA(t_(2)+t_(1)))` |
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| 85087. |
Activity of 1g carbonobtained from ancient Egyptian wooden article is 3.5 count/min/g. Activity of 1 g carbon obtained from fresh wooden sample at Japan near to horishima Nagasaki is 15.5 counts/min/g. This fresh sample has 10% more activity than other fresh samples (not affected by any radiation) dueto atom bomb blst during the second world war. Half life of C""^(14) is 5770 years. Age of Egyptian wooden article is nearly |
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Answer» 2885 years |
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| 85088. |
Alcohols may behave as : |
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Answer» BRONSTED base |
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| 85089. |
Active mass of 5.6 g CaO(s) is |
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Answer» 0.1 |
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| 85090. |
Active mass is |
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Answer» gm moles per UNIT volume |
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| 85091. |
Activation of charcoal : |
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Answer» Can be achieved only with charcoal form nut shells |
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| 85092. |
Three alcohols (i) CH_3CH_2CH_2OH, (ii) CH_3-CHOH-CH_3and (iii) CH_3-C(CH_3)(OH)-CH_3 were treated seperately with Lucas reagent (Conc. HCl+ZnCl_2) . What results do you expect at room temperature. |
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Answer» (II) and (iii) react immediately and (i) in about 5 MINUTES . |
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| 85093. |
Activation of benzene ring in aniline can be decreased by treating with |
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Answer» Dil. HCl |
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| 85094. |
Alcohols (i) CH_(3)CH_(2)CH_(2)OH, (ii) CH_(3)-CHOH-CH_(3) and (iii) CH_(3)-C(CH_(3))(OH)-CH_(3) were treated with Lucas reagent (Conc. HCl+ZnCl_(2)). What results do you expectat room temperature |
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Answer» (ii) and (III) react immediately and (i) in about 5 MINUTES |
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| 85095. |
Activation energy or Energy or activation. |
| Answer» SOLUTION :The DIFFERENCE between the energy of the transition state and the energy of the REACTANTS is CALLED activation energy. | |
| 85096. |
Alcohols gives alkyl halides, treatment with |
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Answer» `PX_3` `ROH + PX_5 overset(Delta)to RX + POX_3 + HX` `ROH + HX overset(Delta)to RX + H_2O` |
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| 85097. |
Alcohols exhibit |
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Answer» CHAIN ISOMERISM |
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| 85098. |
Activation of benzene ring by-NH_(2) in aniline can be decreased by treating with |
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Answer» DILUTE HCI
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| 85099. |
Alcohols CANNOT be prepared from __________. |
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Answer» `C_2H_2Br + aq. KOH to ` |
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| 85100. |
Activation energy of forward and backward non catalysed reaction arex and x. respectively.If they are done using catalyst the activation energy of forward and backward reactions are y and y. respectively ,then which of the following relation is true? |
| Answer» Answer :A | |