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85051.

Addition of 0.643 g of a compound to 50 mL of benzene (density : 0.879 g/ml) lowers the freezing point from 5.51^(@)C to 5.03^(@)C. If K_(f) for benzene is 5.12,calculate the molecular weight of the compound.

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SOLUTION :`w_(2)=0.643g, w_(1)=50xx0.879 G = 43.95g.`
85052.

Addition of 0.643 g of a compound to 50 mL of benzene (density 0.679 h/mL) lower the freezing point from 5.51^(@)C to 5.03^(@)C. If K_(f)=5.12 km^(-1), calculate the molecular mass of the compound.

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Solution :`W_(B)=0.643g, W_(A)=(50 mL)XX(0.879" g mL"^(-1))=43.95g=0.04395 kg`
`Deltat_(F)=5.51-5.03=0.48^(@)C=0.48 K, K_(f)=5.12" K kg mol"^(-1)`
`M_(B)=(W_(B)xxK_(f))/(DeltaT_(f)xxW_(A))=((5.12" g kg mol"^(-1))xx(0.643g))/((0.48 K)xx(0.04395 kg))=156" g mol"^(-1)`
85053.

Adding powdered Pb and Fe to a solution containing 1.0 M each of Pb^(+2) and Fe^(+2) ions would result in the formation of :

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More of PB and `FE^(+2)` ions
More of Fe and `Pb^(2+)` ions
More of Fe and Pb both
More of `Fe^(+2 )and Pb^(+2)` ions

Answer :A
85054.

alculate the wavenumber for the shortest wavelength transition in the Balmer series of atomic hydrogen.

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SOLUTION :`27419 CM^(-1)`
85055.

Addison's disease can be cured by

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GLUCOCORTICOIDS
THYROXINE
NOREPINEPHRINE
NORADRENALINE

SOLUTION :Glucocorticoids
85056.

Adding powdered lead and iron to a solution that is 1M in both Pb^(2+) and Fe^(2+)ions, would results to a reaction in which (E^@ Fe^(2+)//Fe = -0.44V, E^@Pb^(2+)//Pb = -0.13V)

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more AMOUNT of PB and FE is formed
more amount of `Pb^(2+)` and `Fe^(2+)` formed
more amount of Pb and `Fe^(2+)`is formed
more amount of `Pb^(2+)` and Fe is formed.

Answer :B
85057.

Aldehyde 'A' and 'B' are :

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both (a) and (B)
NONE is CORRECT

ANSWER :A
85058.

Adding of Cl_2 to benzene in the presence of AlCl_3 is an example of

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Addition
Halogenation
Substitution
Elimination

Solution :
85059.

Adding alum to turbid water, impurties are removed due to -

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Coagulation
Brownian movement
Electrophoresis
Tyndall effect

Answer :A
85060.

Alcohols which can give white turbidity immediately on reaction with Lucas reagent are :

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`Ph_(3)C-OH`
`H_(3)C-OH`
`H_(3)C-UNDERSET(H)underset(|)OVERSET(CH_(3))overset(|)C-OH`

Solution :N//A
85061.

Adding a few drops of dilute HCl to freshly precipated ferric hydroxide produces a red-coloured colloidal solution. This phenomenon is known as

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PROTECTIVE action
peptization
dialysis
dissociation

Answer :B
85062.

Addition of excess of sodium hydroxidesolution to a solution of nickel sulphate result in the formation of a:

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GREEN precipitate
Pink colouration
Blue precipitate
Violet colouration

Answer :A
85063.

Alcohols undergo dehydration in the following sequence :

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`1^@ gt 2^@ gt 3^@`
`3^@ gt 2^@ gt 1^@`
`1^@ gt 3^@ gt 2^@`
`3^@ gt 1^@ gt 2^@`

ANSWER :B
85064.

Add 4.00 xx 10^(-2) , 3.26 xx 10^(-3)and 1 xx 10^(-6)to the correct number of significant digits :

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`4.3261 XX 10^(-2)`
`4.33 xx 10^(-2)`
`4.3 xx 10^(-2)`
cannot be CALCULATED

SOLUTION :`{:(4.00 xx 10^(-2)),(0.326 xx 10^(-2) ),(0.0001 xx 10^(-2) ) (overline(4.3261 xx 10^(-2) )):}`
` = 4.33 xx 10^(-2)`
(upto two decimal PLACES as in `4.00 xx 10^(-2)`)
85065.

Adam's catalyst is :

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PT and PtO
Pt
Pt and `PtO_2`
`Pt_2O` and PtO

Answer :A
85066.

Acylic stereioisomers having the molecular formula C_(4)H_(7)Cl are classified and tabulated. Find out the correct set of numbers

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`{:("Geometrical",,"Optical"),(""6,,""2):}`
`{:("Geometrical",,"Optical"),(""4,,""2):}`
`{:("Geometrical",,"Optical"),(""6,,""0):}`
`{:("Geometrical",,"Optical"),(""5,,""2):}`

Solution :Acyclic stereoisomers having molecular formula `C_(4)H_(7)CL`
`{:(""Cl),("|"),(CH_(2)=CH-C_(**)-CH_(3)),("|"),(""underset("one asymmetric carbon")(H)):}`
THEREFORE, number of optical ISOMERS `= 2^(n) = 2^(1) = 2`. Two geometrical isomers of each compound are possible for the following structures.
`ClHC = CH-CH_(2)-CH_(3), ClH_(2)C-CH=CH-CH_(3)`
and `{:(CH_(3)-C=CH-CH_(3)),("|"),(""Cl):}`
85067.

Acylation process is preferred than direct alkylation because (by the Friedel-Craft's reaction)

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In alkylation, a poisonous gas is evolved
In alkylation , LARGE AMOUNT of heat is evolved
In alkylation, polyalkylated PRODUCT is formed
Alkylation is very costly

Answer :C
85068.

Alcohols reacts with sodium metal to release hydrogen gasTrue/False

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ANSWER :T
85069.

Acylation of —NH_2 group in aniline reduces its reactivity in electrophilic substitution reactions.

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ANSWER :T
85070.

Alcohols react with Grignard reagent to form

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Alkanes
Alkenes
Alkynes
All of these

Solution :
85071.

Acylation of benzene to produce aliphatic aromatic ketones is known as

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BENZOIN condensation
Hydroformylation
Clemmensen reduction
Friedel-Cralft 's REACTION

Solution :`underset"BENZENE"(C_6H_6)+underset"ACETYL chloride"(CH_3COCl)undersetDeltaoverset(anhd. AlCl_3)to underset"(aliphatic aromatic ketone)"underset"Acetophenone"(C_6H_5COCH_3+HCl)`
This is Friedel-Craft's reaction
85072.

Alcohols react with ceric ammonium nitrate reagent and give :

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BLUE ppt
yellow colouration
pink red colouration
bluish green colouration

Solution :`2ROH + (NH_4)_2Ce(NO_3)_6 to UNDERSET("Pink red colour")((ROH)_2Ce(NO_3)_4) + 2NH_4NO_3`
85073.

Acylation of alkyl phenyl ether gives

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2-alkoxy alkyl PHENYL KETONE (MAJOR)
4-alkoxy alkyl phenyl ketone (minor)
4-alkoxy alkyl phenyl ketone (major)
3-alkoxy alkyl phenyl ketone (major)

ANSWER :C
85074.

Alcohols react with active metals e.g., Na, K, etc. To give corresponding alkoxides. Write down the decreasing order of reactivity of sodium metal towards primary, secondary and tertiary alcohols.

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SOLUTION :Decreasing ORDER of REACTIVITY of sodium metal is :
`1^(@) gt 2^(@) gt 3^(@)`
85075.

Alcohols react with active metals, e.g., Na, K etc. to give corresponding alkoxides. Write down the decreasing order of reactivity of sodium metal primary, secondary and tertiary,

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Solution :`to` The ORDER of reactivity of alcohols with sodium metal is of order:
`"Primary alcohol"GT"Secondary alcohol" gt"Tertiary alcohol"`
`to`The +I effect of the alkyl groups increases the electron density on the OXYGEN atom as a result of which the electropositive HYDROGEN of -OH group is more tightly held by the molecule which makes the release of H+ difficult. The effect if more pronounced if the alkyl groups are more in the molecule. Thus, tertiary alcohol is least acidic.
85076.

Acylation and benzoylation of Aniline aer……………. Reactions.

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ANSWER :NUCLEOPHILIC SUBSTITUTION or SCHOTTEN Baumann
85077.

Alcohols react with activemetals, e.g., Na, K, etc. to give corresponding alkoxides. Wriite down the decreasing order of reactivity of sodium metal towards primary, secondary and tertiary alcohols.

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Solution :Alkyl GROUPS have +I-effect. As the number of alkyl groups increases from 1 to 2 3 in going from `1^(@)` to `2^(@)` to `3^(@)` alcohols, the electron density in the O-H BOND increases and the bond BECOMES stronger and stronger. In other words, acidic character of alcohols decreases from `1^(@)` to `2^(@)gt3^(@)`

Since Na metal is basiic and alcohols are acidic in nature, therefore, reactivity of Na metal towads alcohols decreases as the acidic strenth of alcohols decreases, i.e., in the ORDER: `1^(@) gt 2^(@) gt 3^(@)`
85078.

Acyl halides are prepared by the action of _____on carboxylic acids.

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Solution :Thiony chloride `(SOCl_(2))`. Or PHOSPHORUS pentachloride or TRICHLORIDE `(PCl_(5)` or `PCl_(3))`
85079.

Acyl halide is formed by reacting PCl_(5) with :

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alcohol
ester
amide
acid

Answer :D
85080.

Actylene reacts with ammonical Cu_(2)Cl_(2) to give precipitate of

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RED colour
Yellow colour
White colour
Blue colour

Answer :1
85081.

Actully 18-crown- 6 ether means,

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18-oxygen and 6 carbon
12-carbon and 6-oxygen
12-carbon and 12-oxygen
6-oxygen and 6-carbon

Answer :B
85082.

Activity of disinfectant is expressed by .......

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KETONE COEFFICIENT
phenon coefficient 
PHENOL coefficient 
ALCOHOL coefficient 

SOLUTION :phenol coefficient
85083.

Alcohols of low molecular weight are :

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SOLUBLE in WATER
Soluble in water on heating
Insouluble in all solvents
Soluble in all solvents

Answer :A
85084.

Actone and acetophenone can be identified by :

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Burning the compound on SPATULA
Adding a saturated SOLUTION of `NaHSO_3`
HCN
All are CORRECT

ANSWER :A
85085.

Alcohols of high molecular masses are

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HIGH B.P. and excessible SOLUBILITY
LOW B.P. and EXCESSIVE solubility
high B.P. and low solubilit
low B.P. and low solubility

Answer :C
85086.

Activity of a radioactive substance is A_(1) at time t_(1) and A_(2) at time t_(2)(t_(2) gt t_(1)) , then the ratio of f(A_(2))/(A_(1)) is:

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`E^(LAMBDA(t_(2)+t_(1)))`
`e^(lambda(t_(1)-t_(2)))`
`e^(-lambda(t_(1)+t_(2)))`
`(t_(2))/(t_(1))`

Answer :B
85087.

Activity of 1g carbonobtained from ancient Egyptian wooden article is 3.5 count/min/g. Activity of 1 g carbon obtained from fresh wooden sample at Japan near to horishima Nagasaki is 15.5 counts/min/g. This fresh sample has 10% more activity than other fresh samples (not affected by any radiation) dueto atom bomb blst during the second world war. Half life of C""^(14) is 5770 years. Age of Egyptian wooden article is nearly

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2885 years
5770 years
11540 years
12500 years

Solution :`t/t""^(1//2)=2,t=2xx5770`
85088.

Alcohols may behave as :

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BRONSTED base
Lewis base
Neutral
All

Answer :D
85089.

Active mass of 5.6 g CaO(s) is

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0.1
2
0.2
1

Answer :3
85090.

Active mass is

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gm moles per UNIT volume
gm atoms per unit volume
gm ATOMIC number per unit volume
gm EQUIVALENT PERUNIT volume

Answer :A
85091.

Activation of charcoal :

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Can be achieved only with charcoal form nut shells
Increases the adsorbing POWER of the charcoal
Is accomplished by GIVING POWDERED charcoal an electrical charge
Is achieved by HEATING the charcoal in air

Answer :B
85092.

Three alcohols (i) CH_3CH_2CH_2OH, (ii) CH_3-CHOH-CH_3and (iii) CH_3-C(CH_3)(OH)-CH_3 were treated seperately with Lucas reagent (Conc. HCl+ZnCl_2) . What results do you expect at room temperature.

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(II) and (iii) react immediately and (i) in about 5 MINUTES .
(iii) reactsimmediately , (ii) reacts in about 5 MINUTESAND (i) not at all.
(i) reacts immediately , (ii) reacts in about 5 minutesand (iii) not at all.
(i) reacts in about 5 minutes , (ii) reacts in about 15 minutesand (iii) not at all.

Answer :B
85093.

Activation of benzene ring in aniline can be decreased by treating with

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Dil. HCl
Ethyl alcohol
Acetic acid
Acetyl chloride.

Solution :The activating effect of the AMINE GROUP is REDUCED by acetylations. The acetyl group being electron withdrawing attracts the lone pair of electrons of the N-atoms TOWARDS itself.
85094.

Alcohols (i) CH_(3)CH_(2)CH_(2)OH, (ii) CH_(3)-CHOH-CH_(3) and (iii) CH_(3)-C(CH_(3))(OH)-CH_(3) were treated with Lucas reagent (Conc. HCl+ZnCl_(2)). What results do you expectat room temperature

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(ii) and (III) react immediately and (i) in about 5 MINUTES
(iii) REACTS immediately, (ii) reacts in about 5 minutes and (i) not at all
(i) reacts immediately , (ii) reacts in about 5 minutes and (iii) not at all
(i) reacts in about 5 minutes, (ii) reacts in about 15 minutes and (iii) not at all

Answer :A
85095.

Activation energy or Energy or activation.

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SOLUTION :The DIFFERENCE between the energy of the transition state and the energy of the REACTANTS is CALLED activation energy.
85096.

Alcohols gives alkyl halides, treatment with

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`PX_3`
`PX_5`
HX
all of these

Solution :`3ROH + PX_3 OVERSET(Delta)to 3RX + H_3PO_3`
`ROH + PX_5 overset(Delta)to RX + POX_3 + HX`
`ROH + HX overset(Delta)to RX + H_2O`
85097.

Alcohols exhibit

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CHAIN ISOMERISM
position isomerism
OPTICAL isomerism
all of these

ANSWER :D
85098.

Activation of benzene ring by-NH_(2) in aniline can be decreased by treating with

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DILUTE HCI
Ethyl alcohol
Acetic acid
Acetyl chloride

Solution :
85099.

Alcohols CANNOT be prepared from __________.

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`C_2H_2Br + aq. KOH to `
`(CH_3)_2C=O overset(LiAlH_4)to`
`H_3C-UNDERSET(O)underset(||)C-OCH_3 underset(H_2O)overset(H^(+))to `
`CH_3CH_2Cl overset(H_2O)to`

ANSWER :D
85100.

Activation energy of forward and backward non catalysed reaction arex and x. respectively.If they are done using catalyst the activation energy of forward and backward reactions are y and y. respectively ,then which of the following relation is true?

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x-x.=y-y.
x-x.`LT` y-y.
x-x. `GT` y-y.
x-x. `LE` y-y.

Answer :A