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85151.

Alcoholic potash is used to bring about

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dehydrohalogenation
dehalogenation
dehydrogenation
dehydration

Solution :Alcohollic POTASH is USED for the preparation of alkenes from haloalkanes
`R- CH_(2) - underset(underset(Cl)(|))(CH) - R' underset(-HCl)OVERSET(alc.KOH)rarr R- CH = CH- R'`
85152.

Alcoholic sol of KOH is used for :

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Dehydration
Dehydrogenation
Dehydrohalogenation
Dehalogenation

Answer :C
85153.

Action of water on calcium carbide gives

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ETHANE
ETHYNE
Ethane
ETHANAL

ANSWER :B
85154.

Action of soap is due to emulsification and micelle formation. Comment

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Solution :Soap stabilises the emulsion between GREASE and water by FORMING micelles AROUND the grease (and DIRT).
85155.

Alcoholic H_(2)PtCl_(6) is also known as

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Speier's CATALYST
BROWN's catalyst
Adam's catalyst
Lindlar's catalyst.

Solution :It is Speir's catalyst. For other catalysts see TEXT.
85156.

Action of soap is due to emulsification and micelle formation, Comment .

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Solution :Soap molecule has two parts : Hydrophobic and hydrophilic. The first one attaches with oily DIRT and the second attaches with water.

(a) Fig. (a) Arrangement of stearate ions on the surface of water at low concentrations of soap (b) Arrangement of stearate ions inside the bulk of water (ionic micelle) at critical micelle concentrations of soap.
As the dirty cloth is agitated in soap solution, several soap molecules arrange themselves radially, each attached with OIL at one end and water on the other end. So, dirt is removed from the cloth and an emulsion of oily dirt and water is formed in the soap solution. Thus, soap HELPS in EMULSIFICATION and washing away of oily dirt from the cloth.

Fig. (a) Grease on cloth (b) Stearate ion arranging around the grease droplet and (c) Grease due.
85157.

Action of RMgX with vinyl chloride gives:

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ALKANE
Alkyne
Alkene
All of these

Answer :D
85158.

Alcoholic fermention of sugar gives 3% glycerol. The yield can be increased to 25% if fermentation is made in presence of :

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`Na_2SO_4`
`Na_3PO_4`
`Na_2S`
None

Answer :C
85159.

Action of PCl_3 on salicylic acid produces

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o-chlorobenzoic ACID
o-chlorobenzoyl CHLORIDE
o - hydroxybenzoyl chloride
NONE of the above

ANSWER :B
85160.

Actionof nitrousacidwith ethylamineproduces

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ETHANE
AMMONIA
ETHYL alcohol
nitroethane

ANSWER :C
85161.

Alcoholic fermentation is ________ process :

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SLOW decomposition
Biocatalysed
Enzyme catalysed
All

Answer :D
85162.

Action of nitrous acid on ethyl amine gives :

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`C_2H_6`
`C_2H_5OH`
`NH_3`
Nitromethane

Answer :B
85163.

Action of NaNO_(2)+dil HCl on ArNH_(2) yields ArN_(2)^(+)Cl^(-). A similar reaction with cyclohexylamine will yield.

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Solution :CYCLOHEXYLAMINE will form cyclohexanol with NITROUS ACID `(NaNO_(2)+HCl)`
85164.

Action of nitrous acid on ethyl amine gives

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`C_2H_6`
`C_2H_5OH`
`NH_3`
Nitromethane

Answer :B
85165.

Action of KI on Benzene diazonium chloride yields

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SYM triiodobenzene
p-diiodobenzene
o-di iodobenzene
iodobenzene

Answer :D
85166.

Alcoholic fermentation is brought about by the action of:

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`CO_(2)`
`O_(2)`
Invertase
Yeast

Answer :D
85167.

Action of hydrogen chloride on CH_3-underset(CH_3)underset|C=CH_2 and on CH-=CH will predominantly give the compounds, reapectively

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`CH_3-undersetunderset(CH_3)(|)CH-CH_2Cl` and `CH_2Cl-CH_2Cl`
`CH_3-undersetunderset(CH_3)|"CCL"-CH_3` and `CH_3-CHCl_2`
`CH_3-undersetunderset(CH_3)(|)CH-CH_2Cl` and `CH_3-CHCl_2`
`CH_3-undersetunderset(CH_3)|CH-CH_3` and `CH_2Cl-CH_2Cl`

SOLUTION :`CH_3-undersetunderset(CH_3)(|)C=CH_2+HCL to CH_3-undersetunderset(CH_3)(|)oversetoverset(CL)(|)C-CH_3`
`CH-=CH+HCl to CH_2 =CH-Cl OVERSET"HCl"to CH_3-CHCl_2`
85168.

Alcoholic fermentation is brought about by the action of

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`CO_2`
`O_2`
INVERTASE
YEAST

ANSWER :D
85169.

Action of HNO_(2) on CH_(3)NH_(2) gives

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`CH_(3)OH`
`CH_(3)-O-CH_(3)`
`CH_(3)-O-N=O`
B and C both

Solution :
85170.

Action of heavy water (D_2O) on methylmagnesium bromide gives

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`CD_(4)`
`CH_(3) D`
`CH_2 D_2`
`CHD_(3)`

SOLUTION :`CH_3 Mg Br + D_2O to CH_3 D + Mg (OD)Br`
85171.

Actionof heaton a mixtureof sodiumpropionateandsodalimeprodues :

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METHANE
ethane
propane
ethylene

Answer :B
85172.

Alcoholic fermentation by starch or sugar is braught about by :

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`CO_2`
SODIUM bicarbonate
Yeast
Phosphates

Answer :C
85173.

Action of HCl on Benzene diazonium chloride in the presence of copper powder gives

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p-chloro BENZENE DIAZONIUM chloride
o-chloro benzene diazonium chloride
Chloro benzene
0-dichloro benzene

Answer :C
85174.

Alcoholic beverages contain

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`CH_(3)OH`
`C_(2)H_(5)OH`
`C_(3)H_(7)OH`
`CH_(3)OOH`

SOLUTION :ALCOHOLIC BEVERAGES contain `C_(2)H_(5)OH`.
85175.

Action of copper alkyl on vinyl chloride gives:

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ALKANE
Alkene
Alkyne
All of these

Answer :B
85176.

Alcohol which gives red colour with Victor Meyer test is

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`C_(2)H_(5)OH`
`CH_(3)-underset(OH)underset(|)CH-CH_(3)`
`C(CH_(3))_(3)OH`
None of these

Answer :A
85177.

Action of caustic soda and chlorine on ethyl alcohol gives

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Chloroform
Dichloromethane
Trichloroethane
Ethylenechloride

Answer :A
85178.

Alcoholic "AgNO"_(3) does not give precipitate with:

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`C_(6)H_(5)CH_(2)`CL
`C_(6)H_(5)CH_(2)`Cl
`C_(6)H_(5)"Cl"_(3)`
`(CH_(3))_(3)` CCl

Answer :C
85179.

Alcohol is sometimes used in :

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BAKING powder
Paints
Thermometers
Weighting

Answer :C
85180.

Actinoid contraction is more than lanthanoid contraction because

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Energy of 4 f and 5f ORBITALS are same
5 f orbitals are more diffused as COMPARED to 4 f orbitals
Actinoids show greater range of oxidation STATES than lanthanoids
Actinoids are highly reactive

Answer :B
85181.

Actinoid contraction is greater from elements to element than landthanoid contraction. Why?

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SOLUTION :This is because of POOR SHEILDING by 5f-electrons in the ACTINOIDS than that by 4f-electrons in the LANTHANOIDS
85182.

Alcohol is not used in making :

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Chloral
Chloroform
Benzene
Acetaldehyde

Answer :C
85183.

Alcohol has….vapour pressure than water at the same temperature

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more
less
same
none

Solution :Alcohol has LOW b.pt. than `H_(2)O,`
Lower is b.pt. of SOLVENT more is vapour PRESSURE.
85184.

Alcohol has ………. Vapour pressure than water at the same temperature :

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More
Less
Same
None

Answer :A
85185.

Actinoid contraction is greater from element to element than lanthanoid contraction. why?

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Solution : The decrease in atomic radii in actinoid ELEMENTS is GREATER than lanthanoid contraction because 5f electrons have poor shielding effect as COMPARED to 4f electrons. Therefore, the effect of increased NUCLEAR CHARGE leading to contraction in size is more in case of actinoid elements.
85186.

Alcohol containing least number of carbon which can be prepared using Gringnard reagent is :

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`(CH_3)_2CHOH`
`(CH_3)_3COH`
`CH_3OH`
`CH_3CH_2OH`

ANSWER :D
85187.

Actinoid contraction is greater from element to element than the lanthanoid contraction, why?

Answer»

Solution :(i) Actinoid contraction is greater from ELEMENT to element than lanthanoid contraction. The 5f orbitals in Actinoids have a very poorer shielding effect than 4f orbitals in lanthanoids.
(ii) Thus, the effective nuclear charge experienced by electron in valence shells in CASE of k actinoids is MUCH more than that experienced by lanthanoids.
(iii) n actinoids, electrons are shielded by 5d, 4f, 4d and 3d whereas in lanthanoids, electrons are shielded by 4d, 4f only.
(iv) Hence, the size contraction in actinoids is greater as COMPARED to that in lanthanoids.
85188.

Alcohol CANNOT be used in the manufacture of _________.

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chloral
CHLOROFORM
benzene
ACETALDEHYDE

ANSWER :C
85189.

Alcohol can act as Bronsted base. Prove this statemen.

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Solution :ALCOHOLS can also act as a BRONSTED bases. It is due to the presenee of unshared electron PAIRS on oxygen which make them to accept PROTON. So proton aceeptor are Bronsted bases. i.e., alcohols are Bronsted bases.
85190.

Actinoid contraction is greater from element to element than lanthanoid contraction . Why ?

Answer»

SOLUTION :This is DUE to poor shieldingby 5f ELECTRONS in the actinoids than that by 4F electrons in the lanthanoids.
85191.

Alcohol can act as Bronsted base. Prove this statement.

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Solution :Alcohols can also ACT as a Bronsted bases. It is due to the presence of UNSHARED electron pairs on oxygen which MAKE them to accept PROTON. So proton acceptor are Bronsted bases.
i.e., alcohols are Bronsted bases.
85192.

Actinoid contraction is greater from element to element than lanthanoid contraction. Why ?

Answer»

Solution :This is due to poor SHIELDING by 5F electrons in the ACTINOIDS than that by 4f electrons in the lanthanoids.
85193.

Alcohol are stronger acids than alkanes. This is clear fromthe reaction

Answer»

`2ROH + 2 Na to 2RO^(-)Na^(+)+H_(2)`
`ROH +R' MgX to R'H +RO -MgX`
`ROH +R'COOHto R'COOR+H_(2)O`
`ROH +R' COCL to R' COOR +H_(2)O`

Answer :B
85194.

Actinodcontractionis greaterfrom elementto elementthan thelanthanoidcontraction, why ?

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SOLUTION :Actinoidcontractionis greaterthanelementto elementthanlanthanoidcontraction. Thesesf ORBITALS have a poorershieldingeffectthan4forbitals . Thusthe effectivenuclearchangeexperiencedby ELECTRONSIS muchmore THANTHAT experiencedby LANTHANOID .Soactinoidshowgreatercontraction.
85195.

Alcohol A (C_(10)H_(18)O) is converted into mixture of alkene B and C on heating with conc. H_(3)PO_(4). Catalytic hydrogenation of B and C yields the same product. Assuming that dehydration of alcohol A proceed without rearrangement. Alkene B on ozonolysis form cyclopentanone. Identify the correct options.

Answer»




ANSWER :A,B,D
85196.

Actinides form oxocation because of

Answer»

actinide contraction
RADIOACTIVE NATURE
reducing property q
high charge density in higher OXIDATION state

ANSWER :D
85197.

Actinides have higher tendency to form complexes than Lanthanides, due to

Answer»

HIGHER CHARGE and SMALLER SIZE
Smaller charge and LARGER size
they are radioactive
they are electropositive

Answer :A
85198.

Alcohl can be prepared by which of the following methods ?

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By HYDRATION of alkene
By reduction of carbonyl compounds
By reaction of primary aliphatic amines with nitrous ACID
By hydrolysis of esters.

ANSWER :A,B,C,D
85199.

Actinides exhibits oxidation state

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`+3 and +4`
`+4 and 5`
`+5 and +6`
`+2` to `+7`

Answer :D
85200.

AlCl_3 on hydrolysis gives :

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`Al_2O_3. H_2O`
`AL(OH)_3`
`Al_2O_3`
`AlCl_3. 6H_2O`

ANSWER :B