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85201.

AlCl_(3) is covalent and AiF_(3) is ionic. This fact can be explained on the basic of :

Answer»

Crystal STRUCTURE
Fazan RULES
Lattice ENERGY
Valence BOND theory

Answer :B
85202.

AlCl_3 is a _________ Lewis acid than BCl_3.

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SOLUTION :STRONGER
85203.

Actinides are known as

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5-f SERIES elements
`2^(nd)` inner TRANSITION elements
radio ACTIVE elemenrts
all of these

Solution :We know that, all actinides are RADIOACTIVE. The elements bismuth ONWARDS are radioactive.
85204.

Actinides are called transuranic elements. Explain.

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SOLUTION :HEAVIEST naturally available element is URANIUM. ELEMENTS with `Zgt 92` are called transuranic elements. They are all artificial and most of them were synthesised by Seaberg.
85205.

AlCl_3 in Friedel-Crafts reaction acts as:

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OXIDISING agent
Reducing agent
Acid catalyst
None

Answer :C
85206.

Actinide series is arises due to

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stability of 5f-orbitals
stability of 7s-orbitals
stability of 6d-orbitals
equal stability of 6d and 5f-orbitals

Solution :We know that, in `7 ^(th)` row after 7s-orbitals the next electrons enters into 6d-orbitals. At this STAGE 6d-orbitals stop its spliting and 5f-orbitals, split into 7 orbitals, and BECOME lower energy than, 6d-orbitals. Hence 5f-orbitals are progressively filled and 14 NEW ELEMENTS are ADDED called as actinides.
85207.

Actinide that is naturally available with highest isotopic number

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U
Pu
Cu
Fm

Answer :A
85208.

AlCl_3 exists in dimer because :

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AL has GREATER I.P.
Al has LARGER radius
High CHARGE nucleus
Incomplete `RHO`-orbital

Answer :D
85209.

Actinide series start from

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Ac to Lr
TH to Lr
U to Lr
CF to Lr

Answer :B
85210.

Actinide from

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IONIC COMPOUNDS
COVALENT compounds
co-ordinate compounds
chalates

ANSWER :B
85211.

AlCl_(3) behaves like a lewis acid. Substantiate this statement.

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Solution :In `AlCl_(3)`, AL in electron DEFICIENT it needs two electrons to complete octet so it ACT as lewis ACID `AlCl_(3)` usualy exist as a DIMER to achieve octer by bridged Cl atom electrn deficient compounds are lewis acids.
85212.

AlCl_(2) is solubleis axcessof NaOH formingsodiummetaaluminate Na[Al(OH)_(4)].

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Solution :`AICI_(3) + NaOH RARR 3NaCI + AI(OH)_(3) DARR`
`AI(OH)_(3) + NaOHrarr underset("Soluble")(Na[AI(OH)_(4)])`
HENCE true.
85213.

Acrylonitrile is the other name of

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`H_2C=CHCl`
` H_2C =CHOH`
` H_2C =CHC_6H_5`
` H_2C= CHCN`

ANSWER :D
85214.

Albuterol (used in some commonly prescribed respiratory medications) and vanillin (from vanilla beans) each contain several functional groups. Name the functional groups in albuterol and vanillin and, if appropriate for a given group. classify them as primary (1^(@)), secondary (2^(@)), or tertiary (3^(@)).

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SOLUTION :Albuterol has the FOLLOWING FUNCTIONAL groups: `1^(@)` alcohol, `2^(@)` alcohol, phenol, and `2^(@)` AMINE. VANILLIN has aldehyde, ether, and phenol functional groups.
85215.

…………...act as shock absorber and lubricant

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SOLUTION :hyalronate (or) GLYCOSAMINOGLYCANS
85216.

Albumin protein are most abundant in

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Meat
Milk
EGG
SOYABEAN

ANSWER :C
85217.

Acrylic resins are

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Colourless and transparent
DARK BROWN and thermosetting
Darkbrown and THERMOPLASTIC
White like MILK

ANSWER :A
85218.

Acrylic acid reacts with HBr to give :

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`BR-CH_(2)underset(Br" ")underset(|" ")(CH)-COOH`
`Br-CH_(2)-CH_(2)-COOH`
`CH_(2)=CHCOBr`
`CH_(3)-underset(Br"")underset(|"")(CHCOOH`

ANSWER :B
85219.

Albumin is a _____ type protein.

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ANSWER :GLOBULAR
85220.

Across the lanthanide series, the basic strength of the lanthanide hydroxides

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INCREASES
DECREASES
FIRST increases and then decreases
First decreases and then increases

Answer :B
85221.

Alanyl glycine is ______.

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DIPEPTIDE
tripephide
POLYPEPTIDE
NUCLEIC ACID

SOLUTION :dipeptide
85222.

Acrosols reduce primary productivity by

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Destroying LEAF tissue
Premature leaf fall
Reducing crop yields
All of these

Solution :Aerosol is PRODUCED by jet aeroplanes, trucks and other vehicles . It can DECREASE the GROWTH and productivity of plant and also cause abscission of leaves.
85223.

Alanine is :

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an enzyme
purine BASE of nucleic ACID
`alpha`-AMINO acid
HORMONE .

Answer :C
85224.

Acrolein test is positive for:

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POLYSACCHARIDES
proteins
oils and fats
reducing SUGARS

ANSWER :C
85225.

Alane is chemically:

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`AlH_3`
`(AlH_3)_n`
`LiAlH_4`
None

Answer :B
85226.

Acrolein test is positive for

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Polysaccharides
Proteins
Oils and fats
Reducing sugars

Solution :When a fat is heated strongly in the PRESENCE of a dehydrating agent such as `KHSO_(4)`, the GLYCEROL portion of the molecule is dehydrated to FORM the unsaturated aldehyde acrolein, `CH_(3)CH=CHCHO`, which has the peculiar odour of burnt grease. This is the standard TEST for fats.
85227.

Al^(3+) has a lower radius than Mg^(2+) ion because

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Mg atom has less number of neutron than Al
`Al^(3+)` has higher nuclear CHARGE than `Mg^(2+)`
their electronegatives are different
Al has a lower IONIZATION potential than Mg atom.

Solution :`Al^(3+)` has a higher nuclear charge `(+13)` than `Mg^(2+) (+12)`.
85228.

Acrolein on reduction by using H_2/Ni gives

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ANSWER :A
85229.

Al^(3+)(aq)+3e^(-) rarr Al(s)E^(@)=-1.66V Cu^(2+)(aq)+2e^(-) rarr Cu(s)E^(@) = + 0.34V What voltage is produced under standard conditions to give a spontaneous reactions by combination of these two half-cells ?

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1.32 V
`-1.32V`
2.00 V
`-2.00V`

ANSWER :C
85230.

Acrolein on complete reduction gives:

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ALLYL alcohol
Propan-1-ol
Propanal
None

Answer :B
85231.

Al_(2)O_(3) to AlN to A(OH)_(3) toAl_(2)O_(3). The sequence of these products involved in

Answer»

Bayer's PROCESS
Serpecks process
Hall's process
Hope's process

Solution :The Serpeck.s process is `Al_(2)O_(3)+3C+N_(2) overset(180^(@)C) to 2AIN+3CO`
`SiO_(2)+2C to Si+ 2CO`
`AIN+3H_(2)O to Al(OH)_(3)+NH_(3)`
`2Al (OH)_(3) overset(DELTA)to Al_(2)O_(3)+3H_(2)O`
85232.

Al_(2)O_(3) to AIN to Al(OH)_(2) to Al_(2)O_(3). The sequence of these products involved in

Answer»

BAYER's PROCESS
Serpeck's process
Hall's process
Hoope's process

Answer :B
85233.

Al_(2)O_(3)+N_(2)+Crarr X+CO, X+H_(2)Orarr Y+Z 'Y' is an amphoteric substance. When aqueous 'Z' is treated with AICI_(3) solution again 'Y' is formed. What are X, Y and Z?

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Solution :`X = AlN`, which on hydrolysis gives Al(OH), and AMMONIA. `Y = Al(OH)_(3) and Z=NH_(3)`
Ammonium chloride precipitates ALUMINIUM hydroxide with aqueous ammonia.
`AlCl_(3)+3NH_(4)OH rarr Al(OH)_(3)+3NH_(4)Cl`
85234.

Acrolein is obtained when glycerol is dehydrated with :

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`KHSO_4`
`P_2O_5`
CONC.`H_2SO_4`
All are correct

Answer :D
85235.

Al_(2)O_(3) is reduced by electrolysis at low potentials and high currents. If 4.0xx10^(4) ampere of current is passed through molten Al_(2)O_(3) for 6 hours, what mass of aluminium is produced ? (Assume 100% current efficiency. At. Mass of Al=27g mol^(-1))

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`8.1xx10^(4)g`
`2.4xx10^(5)g`
`1.3xx10^(4)g`
`9.0xx10^(3)g`

Solution :`Al^(3+)+3e^(-)toAl`
QUANTITY of electricity PASSED
`=(4.0xx10^(4)A)xx(6xx60xx60s)`
`=864xx10^(6)`coulombs
3F, i.e., `3xx96500C` produce `Al=1` mole, i.e., 27g
`therefore864xx10^(6)C` will produce Al ltbRgt `=(27)/(3xx96500)xx864xx10^(6)g`
`=8.058xx10^(4)g=8.1xx10^(4)g`.
85236.

Acrilon is hard , horny and a high melting material . Which of the following represents its structure ?

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ANSWER :A
85237.

Al_2O_3 formation involves large quantity of heat evolution which makes its use in :

Answer»

Deoxidiser
Thermite welding
Confectionary
INDOOR photography

Answer :B
85238.

Acrilan is a hard, horny and a high melting material. Which of the following represents its structure?

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`(--CH_2- underset(COOCH_3)underset|overset(CH_3)overset|C--)_n`
`(--CH_2-underset(COOC_2H_5)underset|CH--)_n`
`(--CH_2-undersetunderset(CL)|CH--)_n`
`(--CH_2-undersetunderset(CN)|CH--)_n`

ANSWER :D
85239.

Al_(2)O_(3)+C+N_(2)overset(Delta)to X+Y. If X is a solid and Y is a gas, the correct statement is

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Both X and Y are combustable
X and hydrolysis gives AMMONIA
Y on reduction gives METAL
Both X and Y are ACIDIC

Answer :2
85240.

Acrilan is a hard , horny and a high melting material. Which of the following represents its structure ?

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ANSWER :A
85241.

Al reduces most of the metallic oxides due to its greater affinity for :

Answer»

Metals
Oxygen
Electrons
Protons

Answer :B
85242.

Acrilan is a hard , horny and a high melting material. Its stucture is

Answer»




SOLUTION :Acrilan is a CYANIDE COMPOUND. The structure is `[--CH_(2)-underset(CN)underset(|)(C)H--]_(N)`
85243.

Acrilan fibre used for cloth, carpets and blankets, it the polymer of

Answer»

acrylonitrile
ethylacrylate
styrene
monochlorotrifluoro ethane

Answer :A
85244.

Al (OH)_(3) is also used like which of the following to neutralise exucess acid in the gastric juice?

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`NaHCO_(3)`
`MgCO_(3)`
ALUMINUM phosphate
All of these

Answer :D
85245.

Acquired immune deficiency syndroms (AIDS) is characterised

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Killer T-cells
Reduction in number of helper T-shells
An AUTOIMMUNE disease
Inability of BODY to PRODUCE interferons

Answer :B
85246.

Al element X belongs to fourth period and fifteenth group of the periodic table. Which of the following statements is true?

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It has a completely FILLED s-orbital and a partially filled d-orbital
It has completely filled s- and p- ORBITALS anre a partially filled d-orbital
It has completely filled s- and p- orbitals and a half filled d-orbital.
It has a half-filled p-orbital and completely filled s- and d-orbitals.

Solution :Element X is arsenic (As) and its electronic configuration is `[AR]3d^(10) 4s^(2) 4p^(3)`.
85247.

Al dissolves in molten NaOH with the formation of :

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ALUMINIUM hydroxide
SODIUM META ALUMINATE `(NaAlO_2)`
Sodium aluminate `(Na_3AlO_3)`
Alumina

Answer :C
85248.

Acqueous solution of nickel sulphate on treating with pyridine and then adding a solution of sodium nitrate gives dark blue crystals of

Answer»

`[NI(PY)_(4)]SO_(4)`
`[Ni(py)_(2)(NO_(2))_(2)]`
`[Ni(py)_(4)](NO_(2))_(2)`
`[Ni(py)^(3)(NO_(2))_(2)]SO_(4)`

SOLUTION :`NiSO_(4)+4py+2NaNO_(3)toNa_(2)SO_(4)+underset("Blue")([Ni(py)_(4)](NO_(2))_(2))`
85249.

Al-Bronze contains Al and :

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Zn
Sb
Ni
Cu

Answer :D
85250.

(a)Copper-Least reactive (b)Clay-Mineral of Al (c )bauxite-Mineral of Al (d)Gangue-Impurity

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SOLUTION :(C )Bauxite-Mineral of AL