This section includes InterviewSolutions, each offering curated multiple-choice questions to sharpen your knowledge and support exam preparation. Choose a topic below to get started.
| 85301. |
Acidified solution of chromic acid on treatment with H_(2)O_(2) gives blue colour which is due to |
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Answer» `CrO_(3)+H_(2)O+O_(2)` |
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| 85302. |
AlF_(3) is soluble in HF only in the presence of KF. It is due to the formation of |
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Answer» `K_(3)[AlF_(3)H_(3)]` |
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| 85303. |
Acidified sodium fusion extract on addition of ferric chloride solution gives blood red colouration which confirms the presence of |
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Answer» S and CI Sodium metal (if not used in EXCESS) in compounds containig N and S together FORMS sodium thiocyanate. `Na + C + N+ S toNaCNS`(sodium thiocyanate) `Fe^(3+) + CNS^(-)rarr Fe(CNS)_(3)`(blood red ppt.) |
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| 85304. |
AIF_(3)is soluble in HF only in presence of KF . It is dueto the formation of |
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Answer» `K_(3) [AIF_(3) H_(3)]` |
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| 85305. |
[A]:If the activation energy of reaction is zero then the rate of reaction does not depend on temperature. [R]:If the activation energy is less then the rate of reactio is more. |
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Answer» Assertion [A] and REASON [R] both are correct and [R] gives correct explanation of [A] As the activation of energy is less,the fraction of molecule which undergoes fruit full collision with kinetic energy is more,so rate of reaction increase. |
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| 85306. |
Acidified potassium permanganate solution is decolourised by |
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Answer» WHITE vitriol |
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| 85307. |
AIF_(3) ionic while AlCl_(3) is covalent . |
| Answer» SOLUTION :Since `F^(-)` is smaller in size, its polarisability is less and therefore it is having more ionic character. Whereas, CL being large in size is having more polarisability and HENCE more COVALENT character. | |
| 85308. |
Acidified potassium dichromate is treated with hydrogen sulphide, IN this reaction, the oxidation number of chormium : |
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Answer» INCREASE from +3 to +6 |
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| 85309. |
AI_(2)O_(3)is reduced by electrolysisat lowpotentials and high current if 4.0xx10^(4)amperes of curretnis passed through molten AI_(2)O_(3)for 6h what mass of aluminimum is produced ? (Assume 100% currentaluminimumatomicweightof AI=27) |
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Answer» `9.0xx10^(3)` G `therefore E_(AI)=("atomic WEIGHT")/(3)=27/3=9` Now`w =("Eit")/(96500)=(9xx4xx10^(4)xx6xx60xx60)/(96500)` `=8.05 xx10^(4) =8.1 xx10^(4) g` |
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| 85310. |
(A)(i) Arrangethe followingin orderof increasingmolarconductivity 1.Mg[Cr(NH_(3))(CI_(3)) 2. [Cr(NH_(3))CI]_(3) [CoF_(6)1_(2) . 3. [Cr(NH_(3))_(3)Ci_(3)] (ii)Silicon carbideis veryhard. Justifythisstatement. (b)(i)Writethe lawfor thefollowingreactions(a) A reactionthat3//2 orderis x areorderin y. (b)A reactionthat issecond orderin Noand firstorder in Br_(2) (ii) Classifythe followingspeciesintoLewisacidsand lewisbasesand showhowcan actLewisacid //Lewisbase ? (a) OH^(-)ions (b)F^(-) (c _ H^(+) (d ) BCI_(3) |
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Answer» Solution :a (i) Thesecomplexcanionisein solutionas `Mg[Cr(NH_(3)) (CI_(3)) =Mg^(2+)+ [Cr(NH)_(3)) (CI)_(5)]^(2-)` `[Cr(NH_(3))_(3)Ci_(3)]=` DOESNOT IONIZE (ii) silicon carbide isveryhard. It iscovalentsolidcontainsthe atomswhichare bound tegetherin thredimensionalnetworkentirely by covalentbonds.So thecovalentnetworkcrystalsiCis veryhardand havehighmeltingpoint. b (i) `(a) (3)/(2) x + y` (EXCESS ) `to` PRODUCTS (b) 2 No+ `Br_(2)to` Products(2NOBr) (ii) (a) `OH^(-)` ions can domateanelectron pairact aslewisbase. (b) `BCI_(3)` can acceptsan electronpairsinceBoronatomis electrondeficient .Itis a lewisacid. |
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| 85311. |
(a) (i) CalculatepHof 10^(-7) M HCI, (ii)Definecorrosion .Giveoneexample. (b)What isadsorptionisotherm Explain aboutFreundlichadsorptionisotherm. |
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Answer» Solution :(i) If wedo notconsider `[H_(3)O^(+)]` from theionisationof `H_(2)O` then`[H_(3) O^(+)]=[HCI]` i.e., pH=7 whichis a pHof a neutralsolution.Weknowthat HCIsolutionis acidicthiscasethe concentrationof the acidis verylow `(10^(-7) M)`. Hencethe `H_(3) O^(+)(10^(-7 M)` So in thiscasewe shouldionisation of watercannot be neglected. (ii) Theredoxprocesswhichcausesthe deteriorationof metalis calledcorrosionRustingof ironis anexampleof corrosion.It isan electrochemicalprocess. (b)i.Adsorptionisothermsrepresentthe variationof adsorptionat constanttemperatureadsorptionisothemcan bestudiedquatitatively (ii) A plotbetweenthe amountof adsorbate adn pressureor concentration of . (iii)Freundichadsorptionisotem. (IV) thisequationisapplicationfor adsorptionof gaseson solidsurfaces.TheSameequationbecomes `(x)/(m)=ke^(1//n)` whenusedforadsorptionin solutionwith Cas concentration (v )theseequationquantitivelypredictthe effectof pressure(orconcentration ) on theadsorptionof gasesat constanttemperature. (vi)Takinglogon bothsidesof equation `(x)/(m) =kP^(1//n)` `log(x )/(m)= log k+ (1)/(n )log P` (VII) Hencetheinterceptrepresentsthe valueof logk andthe slope `(b)/(q)` gives `(1)/(n)` (vii)thisequationexplainthe increasesof `(x)/(m)` withincreasin pressure.Butexperimentalvaluesshowsthe deviationat lowpressure . `(IX) LIMITATIONS (a)Thisequationis purelyempiricalovera limitedpressurerange |
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| 85312. |
Acidified potassium dichromate is treated with hydrogen sulphide.In the reaction the oxidation number of chromium : |
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Answer» Increase from +3 to +6 |
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| 85313. |
(a)How will you distinguish between Pentan2-one and Pentan-3-one with the help of Iodoform test? (b) How will you bring about following conversions ? (I) Benzoic acid to m-Nitrobenzyl alcohol. (II) Benzaldehyde to Benzophenone. (iii) Benzoic acid to Benzamide. |
| Answer» SOLUTION :(a) PENTAN -2- ONE givesiodoformtesti.e,yellowppton warmingwith `I_2`and NaOHbutpentan -2- one DOESNOT | |
| 85314. |
(a)How does Primary amine undergoes carbyl amine reaction? Give chemical equation.(b) How is aniline is prepared by Hoffmann bromamide degradation reaction? Give equation.(c) Write the general formula of diazonium salt. |
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Answer» Solution :(a) PRIMARY amines on heating with chloroform and alcoholic KOH form carbylamines. `R-NH_(2)+CHCl_(3) + underset(Alco)(3KOH) to R-NC + 3KCl + 3H_(2)O_(2)`. (b) When benzenamide is treated with bromine in aqueous solution of sodium hydroxide ANILINE is obtained. (C) `RN_(2)^(+)`
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| 85315. |
Acidified permanganate solution does not oxidise: |
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Answer» `C_(2)O_(4)^(2-)` (aq.) |
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| 85316. |
Acidified KMnO_(4) solution is decolourized by |
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Answer» TOLUENE |
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| 85317. |
Alcohols are isomeric with |
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Answer» Acids |
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| 85318. |
(a)Haematite-Gravity separation process (b)Copper pyrite-Froth floatation (c )Bauxite-Leaching process (d)Pyrolusite-Magnetic separation process |
| Answer» SOLUTION :(B)COPPER pyrite-froth FLOATATION PROCESS | |
| 85319. |
A_((g))toB_((g)) is a first order reaction. The initial concentration of A is 0.2 mol. "lit"^(-1). After 10 minutes the concentration of B is found to be 0.18"mol. lit"^(-1). The rate constant ("in min"^(-1)) for the reaction is |
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Answer» `0.2303` |
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| 85320. |
Ag_((s))|AgBr_((s))|Br^(-)(0.011M)||Cl^(-)(0.2M)|AgCl_((s))|Ag_((s)) if K_(sp) of AgBr & AgCl at 25^(@)C are 10^(-12) & 10^(10) respectively find which is/are true for above cell at 25^(@)C(log2=0.3) |
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Answer» As `E_(Ag^(+)//Ag)^(@)` is not given so `E_("CELL")` cannot be determined `E_(Br^(-))^(@)//AgBr//Ag=E_(Ag^(+)//Ag)^(@)+(RT)/F In K_(sp)`…..(II) as `E_(Ag^(+)//Ag)^(@)` will be cancelled onn subtractions (i) & (ii) So `E_("cell")` can be determined |
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| 85321. |
Acidified KMnO_4 oxidizes nitrites to |
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Answer» `N_2` |
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| 85322. |
Ag(s)|Ag^(+)(aq)(0.01M)||Ag^(+)(aq)(0.1M)|Ag(s)E^(@)|Ag(s)Ag_((aq))^(@)=0.80 volt |
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Answer» Cellcannot function as anode and cathode are of the same MATERIAL `E_("cell")=(0.0591)/(n)"LOG" (C_(2)(RHS))/(C_(1)(LHS))` `=(0.0591)/(1)"log"(0.1)/(0.01)=0.0591V` |
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| 85323. |
Ag_((s))|Ag_((aq))^(+)(0.01M)||Ag_((aq))^(+)(0.1M)|Ag_((s))E_(Ag_((s))//Ag_((aq)))^(@)=0.80volt |
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Answer» CELL cannot function as anode and cathode are of same MATERIAL `E_(cell)=(0.0591)/(n)"LOG"(C_(1)(R.H.S.))/(C_(2)(L.H.S.))` `=(0.0591)/(1)"log"(0.1)/(0.01)=0.0591log10=0.0591V`. |
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| 85324. |
Acidified KMnO_4 is decolourised by: |
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Answer» OXYGEN |
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| 85325. |
Acidified KMnO_(4) is a very strong oxidising agent. Prove it. |
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Answer» SOLUTION :(i) In the presence of dilute sulphuric acid, potassium permanganate acts as a very strong oxidising agent. Permanganate ion is converted into `MN^(2+)` ion. `MnO_(4)^(-)+ 8H^(+) + 5e^(-) + Mn^(2+) + 4H_(2)O` (ii) Permanganate oxidises FERROUS salt to ferric salt. `2MnO_(4)^(-)+10Fe^(2+) + 16H^(+) to2Mn^(2+) + 10Fe^(3+) + 8H_(2)O` |
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| 85326. |
Acidified K_2Cr_2O_7 solution turns green when Na_2SO_3 is added to it. This is due to the formation of |
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Answer» `Cr_(2)(SO_4)_3` |
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| 85327. |
Find out the incorrect pair(a)Gold ore-Cyanide leaching (b)Nickel ore-Ammonia leaching ( c)Aluminium ore-Alkali leaching (d)silver ore-Acid leaching |
| Answer» SOLUTION :(d)SILVER ore-Acid LEACHING | |
| 85328. |
Acidified KMnO_(4) can be decolourised by (a)_____. |
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Answer» |
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| 85329. |
AgO actually exists as Ag[AgO_(2)], which is diamagnetic in nature. Then which of the following statements is true regarding AgO? |
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Answer» The arrangement of `O^(2-)` ions AROUND `Ag^(+)` ion is square PLANAR |
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| 85330. |
By passing Na_2SO_(3) to the solution of K_(2)Cr_(2)O_(7), it turns green due to the formation of |
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Answer» `Cr_(2)(SO_(4))_(3)` |
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| 85332. |
AgOH solution was neutralized using HNO_(3)solution. If pH of the solution at 50% neutralization point is 8 at 25^(@)C, then pK_(b)of AgOH is: |
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Answer» `4.00` `POH= 14-pH= 14-8= 6` `rArr pK_(B)= 6`……for AgOH |
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| 85333. |
AgO in Ag(II) complex is |
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Answer» Diamagnetic |
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| 85334. |
Acidified K_2Cr_2O_7 solution turns green by: |
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Answer» `CO_2` GAS |
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| 85335. |
AgNO_(3)given white ppthypo changing to blackofter sometime .Black ppt is of |
| Answer» Answer :d | |
| 85336. |
Acidified K_(2)Cr_(2)O_(7) reacts with H_(2)O_(7) to give "…............." coloure due to the formation of "…...................". |
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Answer» |
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| 85337. |
AgNO_(3(aq) was added to an aqueous KCl solution gradully and the conductivity of the solution was measured. The plot of conductance (Lambda) versus the volume of AgNO_(3) is |
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Answer» `underset(("White ppt"))(AgNO_(3)(aq))+KCl(aq) to AgCl(s)+KNO_(3(aq))` `Ag^(+)(aq)+NO_(3)^(-)(aq)+K^(+)(aq)+Cl^(-)(aq) to AgCl(s)+K^(+)(aq)+NO_(3)^(-)(aq)` In this titration, known as conductometric litration, initially the conductance of the solution does not change much because the `Cl^(-)` ions are getting precipitated as AgCl and are replaced by `NO_(3)^(-)` ions Both the ions have nearly the same ionic conductnace Once the precipitation reaction is complete, the further ADDITION of `AgNO_(3)` will increase the concentration of `NO_(3)^(-)`ions in the solution. As a result, the conductance of solution will increase sharply as shown in the curve(s). |
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| 85338. |
Acidified K_2 Cr_2 O_7 turns green by |
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Answer» `SO_(2)` `K_(2)Cr_(2)O_(7)+H_(2)SO_(4)+3SO_(2) to K_(2)SO_(4)+underset("Green")(Cr_(2)(SO_(4))_(3))+H_(2)O` |
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| 85339. |
AgNO_(3(aq)) was added to an aqueous KCl solution gradually and the conductivity of the solution was measured. The plot of conductance A versus the volume of AgNO_3 is |
| Answer» ANSWER :D | |
| 85340. |
Acidified K_2Cr_2O_7 changes to green on reactions with |
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Answer» `SO_2` `Cr_2O_7^(-2) + FE^(+2) rarr Cr^(+3) +Fe^(+3)` |
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| 85341. |
Acidified K_2Cr_2O_7 on oxidation by H_2O_2 gives: |
| Answer» Answer :D | |
| 85342. |
AgNO_(3) overset(Delta)(to)(W)+(X)+O_(2) (X)+H_(2)O to HNO_(2)+HNO_(3) (W)+HNO_(3) to Y+NO+H_(2)O (Y)+Na_(2)S_(2)O_(3)("excess") to (Z)+NaNO_(3) Identify (W) to (Z). |
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Answer» `W=AG, X=N_(2)O,Y=AgNO_(3),Z=Na_(2)[Ag(S_(2)O_(3))_(2)]` |
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| 85343. |
Acidified iodates are reduced to…..by SO_2 |
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Answer» Iodites |
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| 85344. |
AgNO_(3) solution can't be stored in copper vessels, because. . . . |
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Answer» `E_(Ag^(+)|Ag)^(Theta) gt E_(Cu^(2+)|Cu)^(Theta)` `2AgNO_(3)+Cu_((S)) to Ag_((S)) +Cu_((aq))^(2+)+2NO_(3(aq))^(-)` `E_(Ag^(+)|Ag)^(Theta)=0.80V, E_(Cu^(2+)|Cu)^(Theta)=0.34V` So, reduction of `Ag^(+)` occur. And `Ag^(+)` is oxidizing AGENT. oxidation of `Cu^(2+)` occur and reaction occur for those WHOSE `E_(cell)^(Theta)` is LESS. |
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| 85349. |
Acidifed K_(2)Cr_(2)O_(7) oxidises H_(2)S to : |
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Answer» `SO_(2)` |
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| 85350. |
AgNO_(3) gives a red ppt. with |
| Answer» Solution :`2AgNO_(3)+K_(2)CrO_(4)rarrunderset("(Red)")(Ag_(2)CrO_(4))+2KNO_(3)` | |