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85301.

Acidified solution of chromic acid on treatment with H_(2)O_(2) gives blue colour which is due to

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`CrO_(3)+H_(2)O+O_(2)`
`CrO_(5)+H_(2)O`
`H_(2)Cr_(2)O_(7)+H_(2)O+O_(2)`
NONE of these

Solution :`H_(2)Cr_(2)O_(7)+4O to underset("BLUE peroxide of chromium")(2CrO_(5))+H_(2)O`
85302.

AlF_(3) is soluble in HF only in the presence of KF. It is due to the formation of

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`K_(3)[AlF_(3)H_(3)]`
`K_(3)[AlF_(6)]`
`AlH_(3)`
`K[AlF_(3)H]`

SOLUTION :`AlF_(3)+3KFtoK_(3)[AlF_(6)]`
85303.

Acidified sodium fusion extract on addition of ferric chloride solution gives blood red colouration which confirms the presence of

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S and CI
N and S
N
S

Solution :ACIDIFIED sodium fusion EXTRACT on ADDITION of ferric chloride solution gives blood red colouration, which confirms the presence of N and S.
Sodium metal (if not used in EXCESS) in compounds containig N and S together FORMS sodium thiocyanate.
`Na + C + N+ S toNaCNS`(sodium thiocyanate)
`Fe^(3+) + CNS^(-)rarr Fe(CNS)_(3)`(blood red ppt.)
85304.

AIF_(3)is soluble in HF only in presence of KF . It is dueto the formation of

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`K_(3) [AIF_(3) H_(3)]`
`K_(3) [AIF_(6)]`
`AIH_(3)`
`K[AIF_(3)H]`

ANSWER :B
85305.

[A]:If the activation energy of reaction is zero then the rate of reaction does not depend on temperature. [R]:If the activation energy is less then the rate of reactio is more.

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Assertion [A] and REASON [R] both are correct and [R] gives correct explanation of [A]
Assertion [A] and reason [R] both are correct but [R] does not give correct explanation of [A]
Assertion [A] is wrong but Reason [R] is wrong
Assertion [A] is wrong but Reason [R]is correct

Solution :If the activation energy (`E_(a)`) is zero then the energy Is not give to reactant to COMPLETE the reaction.It is not necessary to increase the temperature for heat.Therefore the temperatue CHANGE does not affect on RATE of reaction.
As the activation of energy is less,the fraction of molecule which undergoes fruit full collision with kinetic energy is more,so rate of reaction increase.
85306.

Acidified potassium permanganate solution is decolourised by

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WHITE vitriol
Bleaching powder
Laughing gas
Mohr.s salt

Answer :D
85307.

AIF_(3) ionic while AlCl_(3) is covalent .

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SOLUTION :Since `F^(-)` is smaller in size, its polarisability is less and therefore it is having more ionic character. Whereas, CL being large in size is having more polarisability and HENCE more COVALENT character.
85308.

Acidified potassium dichromate is treated with hydrogen sulphide, IN this reaction, the oxidation number of chormium :

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INCREASE from +3 to +6
decreases from + 6 to +3
REMAINS unchanged
decreases from + 6 + 2.

Solution :`Cr_(2)O_(7)^(2-) (+6) to Cr^(3+) (3) `
85309.

AI_(2)O_(3)is reduced by electrolysisat lowpotentials and high current if 4.0xx10^(4)amperes of curretnis passed through molten AI_(2)O_(3)for 6h what mass of aluminimum is produced ? (Assume 100% currentaluminimumatomicweightof AI=27)

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`9.0xx10^(3)` G
`8.1xx10^(4)` g
`2.4 xx10^(3)`g
`1.3 xx10^(4) g`

SOLUTION :The reactionis `AI^(3+) +3e^(-) rarr AI`
`therefore E_(AI)=("atomic WEIGHT")/(3)=27/3=9`
Now`w =("Eit")/(96500)=(9xx4xx10^(4)xx6xx60xx60)/(96500)`
`=8.05 xx10^(4) =8.1 xx10^(4) g`
85310.

(A)(i) Arrangethe followingin orderof increasingmolarconductivity 1.Mg[Cr(NH_(3))(CI_(3)) 2. [Cr(NH_(3))CI]_(3) [CoF_(6)1_(2) . 3. [Cr(NH_(3))_(3)Ci_(3)] (ii)Silicon carbideis veryhard. Justifythisstatement. (b)(i)Writethe lawfor thefollowingreactions(a) A reactionthat3//2 orderis x areorderin y. (b)A reactionthat issecond orderin Noand firstorder in Br_(2) (ii) Classifythe followingspeciesintoLewisacidsand lewisbasesand showhowcan actLewisacid //Lewisbase ? (a) OH^(-)ions (b)F^(-) (c _ H^(+) (d ) BCI_(3)

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Solution :a (i) Thesecomplexcanionisein solutionas
`Mg[Cr(NH_(3)) (CI_(3)) =Mg^(2+)+ [Cr(NH)_(3)) (CI)_(5)]^(2-)`
`[Cr(NH_(3))_(3)Ci_(3)]=` DOESNOT IONIZE
(ii) silicon carbide isveryhard. It iscovalentsolidcontainsthe atomswhichare bound tegetherin thredimensionalnetworkentirely by covalentbonds.So thecovalentnetworkcrystalsiCis veryhardand havehighmeltingpoint.
b (i) `(a) (3)/(2) x + y` (EXCESS ) `to` PRODUCTS
(b) 2 No+ `Br_(2)to` Products(2NOBr)
(ii) (a) `OH^(-)` ions can domateanelectron pairact aslewisbase.
(b) `BCI_(3)` can acceptsan electronpairsinceBoronatomis electrondeficient .Itis a lewisacid.
85311.

(a) (i) CalculatepHof 10^(-7) M HCI, (ii)Definecorrosion .Giveoneexample. (b)What isadsorptionisotherm Explain aboutFreundlichadsorptionisotherm.

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Solution :(i) If wedo notconsider `[H_(3)O^(+)]` from theionisationof `H_(2)O` then`[H_(3) O^(+)]=[HCI]` i.e., pH=7 whichis a pHof a neutralsolution.Weknowthat HCIsolutionis acidicthiscasethe concentrationof the acidis verylow `(10^(-7) M)`. Hencethe `H_(3) O^(+)(10^(-7 M)`
So in thiscasewe shouldionisation of watercannot be neglected.
(ii) Theredoxprocesswhichcausesthe deteriorationof metalis calledcorrosionRustingof ironis anexampleof corrosion.It isan electrochemicalprocess.
(b)i.Adsorptionisothermsrepresentthe variationof adsorptionat constanttemperatureadsorptionisothemcan bestudiedquatitatively
(ii) A plotbetweenthe amountof adsorbate adn pressureor concentration of .
(iii)Freundichadsorptionisotem.
(IV) thisequationisapplicationfor adsorptionof gaseson solidsurfaces.TheSameequationbecomes `(x)/(m)=ke^(1//n)` whenusedforadsorptionin solutionwith Cas concentration
(v )theseequationquantitivelypredictthe effectof pressure(orconcentration ) on theadsorptionof gasesat constanttemperature.
(vi)Takinglogon bothsidesof equation
`(x)/(m) =kP^(1//n)`
`log(x )/(m)= log k+ (1)/(n )log P`

(VII) Hencetheinterceptrepresentsthe valueof logk andthe slope `(b)/(q)` gives `(1)/(n)`
(vii)thisequationexplainthe increasesof `(x)/(m)` withincreasin pressure.Butexperimentalvaluesshowsthe deviationat lowpressure .
`(IX) LIMITATIONS
(a)Thisequationis purelyempiricalovera limitedpressurerange
85312.

Acidified potassium dichromate is treated with hydrogen sulphide.In the reaction the oxidation number of chromium :

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Increase from +3 to +6
Decreases from +6 to +3
Remains UNCHANGED
Decreases from +6 to +2

Answer :B
85313.

(a)How will you distinguish between Pentan2-one and Pentan-3-one with the help of Iodoform test? (b) How will you bring about following conversions ? (I) Benzoic acid to m-Nitrobenzyl alcohol. (II) Benzaldehyde to Benzophenone. (iii) Benzoic acid to Benzamide.

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SOLUTION :(a) PENTAN -2- ONE givesiodoformtesti.e,yellowppton warmingwith `I_2`and NaOHbutpentan -2- one DOESNOT
85314.

(a)How does Primary amine undergoes carbyl amine reaction? Give chemical equation.(b) How is aniline is prepared by Hoffmann bromamide degradation reaction? Give equation.(c) Write the general formula of diazonium salt.

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Solution :(a) PRIMARY amines on heating with chloroform and alcoholic KOH form carbylamines.
`R-NH_(2)+CHCl_(3) + underset(Alco)(3KOH) to R-NC + 3KCl + 3H_(2)O_(2)`.
(b) When benzenamide is treated with bromine in aqueous solution of sodium hydroxide ANILINE is obtained.
(C) `RN_(2)^(+)`
85315.

Acidified permanganate solution does not oxidise:

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`C_(2)O_(4)^(2-)` (aq.)
`NO_(3)^(-)` (aq.)
`S^(2-)` (aq.)
`F^(-)`(aq.)

SOLUTION :Practically `F^(-)` ION beinga very R.A has no reducing property.
85316.

Acidified KMnO_(4) solution is decolourized by

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TOLUENE
`MnSO_(4)`
`H_(2)O_(2)`
`KI `

Answer :C
85317.

Alcohols are isomeric with

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Acids
Ethers
Esters
Aldehydes

Answer :B
85318.

(a)Haematite-Gravity separation process (b)Copper pyrite-Froth floatation (c )Bauxite-Leaching process (d)Pyrolusite-Magnetic separation process

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SOLUTION :(B)COPPER pyrite-froth FLOATATION PROCESS
85319.

A_((g))toB_((g)) is a first order reaction. The initial concentration of A is 0.2 mol. "lit"^(-1). After 10 minutes the concentration of B is found to be 0.18"mol. lit"^(-1). The rate constant ("in min"^(-1)) for the reaction is

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`0.2303`
`2.303`
`0.693`
`0.01`

ANSWER :A
85320.

Ag_((s))|AgBr_((s))|Br^(-)(0.011M)||Cl^(-)(0.2M)|AgCl_((s))|Ag_((s)) if K_(sp) of AgBr & AgCl at 25^(@)C are 10^(-12) & 10^(10) respectively find which is/are true for above cell at 25^(@)C(log2=0.3)

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As `E_(Ag^(+)//Ag)^(@)` is not given so `E_("CELL")` cannot be determined
`E_("cell")` is `0.0413` volt
`/_\Glt0`
`E^(@)=0`

SOLUTION :`E_(cl^(-)//AgCl//Ag)^(@)=E_(Ag^(+)//Ag)^(@)+(RT)/F IN K_(sp)`………..(i)
`E_(Br^(-))^(@)//AgBr//Ag=E_(Ag^(+)//Ag)^(@)+(RT)/F In K_(sp)`…..(II)
as `E_(Ag^(+)//Ag)^(@)` will be cancelled onn subtractions (i) & (ii)
So `E_("cell")` can be determined
85321.

Acidified KMnO_4 oxidizes nitrites to

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`N_2`
`NO_3`
`NO_3^(-)`
NO

Answer :C
85322.

Ag(s)|Ag^(+)(aq)(0.01M)||Ag^(+)(aq)(0.1M)|Ag(s)E^(@)|Ag(s)Ag_((aq))^(@)=0.80 volt

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Cellcannot function as anode and cathode are of the same MATERIAL
`E_("cell")=0.0591V`
`E_("cell")=0.80V`
`E_("cell")=0.0296V`

Solution :It is a concentration cell
`E_("cell")=(0.0591)/(n)"LOG" (C_(2)(RHS))/(C_(1)(LHS))`
`=(0.0591)/(1)"log"(0.1)/(0.01)=0.0591V`
85323.

Ag_((s))|Ag_((aq))^(+)(0.01M)||Ag_((aq))^(+)(0.1M)|Ag_((s))E_(Ag_((s))//Ag_((aq)))^(@)=0.80volt

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CELL cannot function as anode and cathode are of same MATERIAL
`E_(cell)=0.0592V`
`E_(cell)=0.80V`
`E_(cell)=0.0296V`

Solution :For an electrolytic concentration cell,
`E_(cell)=(0.0591)/(n)"LOG"(C_(1)(R.H.S.))/(C_(2)(L.H.S.))`
`=(0.0591)/(1)"log"(0.1)/(0.01)=0.0591log10=0.0591V`.
85324.

Acidified KMnO_4 is decolourised by:

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OXYGEN
Hydrogen
Nitric oxide
Nascent hydrogen

Answer :D
85325.

Acidified KMnO_(4) is a very strong oxidising agent. Prove it.

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SOLUTION :(i) In the presence of dilute sulphuric acid, potassium permanganate acts as a very strong oxidising agent. Permanganate ion is converted into `MN^(2+)` ion.
`MnO_(4)^(-)+ 8H^(+) + 5e^(-) + Mn^(2+) + 4H_(2)O`
(ii) Permanganate oxidises FERROUS salt to ferric salt.
`2MnO_(4)^(-)+10Fe^(2+) + 16H^(+) to2Mn^(2+) + 10Fe^(3+) + 8H_(2)O`
85326.

Acidified K_2Cr_2O_7 solution turns green when Na_2SO_3 is added to it. This is due to the formation of

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`Cr_(2)(SO_4)_3`
`CrO_(4)^(2-)`
`Cr_(2)(SO_3)_3`
`CrSO_(4)`

Answer :A
85327.

Find out the incorrect pair(a)Gold ore-Cyanide leaching (b)Nickel ore-Ammonia leaching ( c)Aluminium ore-Alkali leaching (d)silver ore-Acid leaching

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SOLUTION :(d)SILVER ore-Acid LEACHING
85328.

Acidified KMnO_(4) can be decolourised by (a)_____.

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ANSWER :`Fe^(2+)or C_(2)O_(4)^(2-),SO_(3)` etc
85329.

AgO actually exists as Ag[AgO_(2)], which is diamagnetic in nature. Then which of the following statements is true regarding AgO?

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The arrangement of `O^(2-)` ions AROUND `Ag^(+)` ion is square PLANAR
The arrangement of `O^(2-)` ions around `Ag^(+)` ion is tetrahedral
The arrangement of `O^(2-)` ions around `Ag^(+)` ion is square planar.
Both `(B)` and `(C )` are correct.

Solution :It EXISTS as square planar structure.
85330.

By passing Na_2SO_(3) to the solution of K_(2)Cr_(2)O_(7), it turns green due to the formation of

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`Cr_(2)(SO_(4))_(3)`
`CrO_(4)^(2-)`
`Cr_(2)(SO_(3))_(3)`
`CrSO_(4)`

Solution :`K_(2)Cr_(2)O_(7) + 3NA_(2)SO_(3) + 4H_(2)SO_(4) to 3Na_(2)SO_(4) + K_(2)SO_(4) + Cr_(2)(SO_(4))_(3)`
85331.

Acidified K_(2)Cr_(2)O_(7) turns green by

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`CO_(2)`
CO
`SO_(2)`
HCl

Answer :C
85332.

AgOH solution was neutralized using HNO_(3)solution. If pH of the solution at 50% neutralization point is 8 at 25^(@)C, then pK_(b)of AgOH is:

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`4.00`
`5.52`
`6.00`
`9.48`

Solution :As at half NEUTRALIZATION point
`POH= 14-pH= 14-8= 6`
`rArr pK_(B)= 6`……for AgOH
85333.

AgO in Ag(II) complex is

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Diamagnetic
paramagnetic
Ferromagnetic
Neutral

Answer :A
85334.

Acidified K_2Cr_2O_7 solution turns green by:

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`CO_2` GAS
`SO_2` gas
HCL gas
`H_2S` gas

SOLUTION :`SO_2` gas turns ACIDIFIED `K_2Cr_2O_7` solution GREEN
85335.

AgNO_(3)given white ppthypo changing to blackofter sometime .Black ppt is of

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`Ag_(2)S_(2)O_(3)`
`Ag_(2)SO_(4)`
`Ag_(2)S_(4)O_(6)`
`Ag_(2)S`

Answer :d
85336.

Acidified K_(2)Cr_(2)O_(7) reacts with H_(2)O_(7) to give "…............." coloure due to the formation of "…...................".

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ANSWER :DEEP BLUE, `CrO_(5)`
85337.

AgNO_(3(aq) was added to an aqueous KCl solution gradully and the conductivity of the solution was measured. The plot of conductance (Lambda) versus the volume of AgNO_(3) is

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Solution :(d) The plot(s) REPRESENTS the correct trend. The reaction is a PRECEPITATION reaction
`underset(("White ppt"))(AgNO_(3)(aq))+KCl(aq) to AgCl(s)+KNO_(3(aq))`
`Ag^(+)(aq)+NO_(3)^(-)(aq)+K^(+)(aq)+Cl^(-)(aq) to AgCl(s)+K^(+)(aq)+NO_(3)^(-)(aq)`
In this titration, known as conductometric litration, initially the conductance of the solution does not change much because the `Cl^(-)` ions are getting precipitated as AgCl and are replaced by `NO_(3)^(-)` ions Both the ions have nearly the same ionic conductnace Once the precipitation reaction is complete, the further ADDITION of `AgNO_(3)` will increase the concentration of `NO_(3)^(-)`ions in the solution. As a result, the conductance of solution will increase sharply as shown in the curve(s).
85338.

Acidified K_2 Cr_2 O_7 turns green by

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`SO_(2)`
CO
`SiO_(2)`
`HCl`

SOLUTION :`K_(2)Cr_(2)O_(7)` turns green by `SO_(2)` DUE to its reduction
`K_(2)Cr_(2)O_(7)+H_(2)SO_(4)+3SO_(2) to K_(2)SO_(4)+underset("Green")(Cr_(2)(SO_(4))_(3))+H_(2)O`
85339.

AgNO_(3(aq)) was added to an aqueous KCl solution gradually and the conductivity of the solution was measured. The plot of conductance A versus the volume of AgNO_3 is

Answer»

<P>(P)
(Q)
(R)
(S)

ANSWER :D
85340.

Acidified K_2Cr_2O_7 changes to green on reactions with

Answer»

`SO_2`
`FeSO_4`
Kl and then ADDING HYPO
`NaCl + CONC. H_2SO_4`

Solution :`Cr_(2)O_(7)^(-2) + SO_(2) rarr UNDERSET("(green)")(Cr_2(SO_4)_3`
`Cr_2O_7^(-2) + FE^(+2) rarr Cr^(+3) +Fe^(+3)`
85341.

Acidified K_2Cr_2O_7 on oxidation by H_2O_2 gives:

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BLUE SOLUTION
`CrO_5`
CHROMIUM peroxide
All of these

Answer :D
85342.

AgNO_(3) overset(Delta)(to)(W)+(X)+O_(2) (X)+H_(2)O to HNO_(2)+HNO_(3) (W)+HNO_(3) to Y+NO+H_(2)O (Y)+Na_(2)S_(2)O_(3)("excess") to (Z)+NaNO_(3) Identify (W) to (Z).

Answer»

`W=AG, X=N_(2)O,Y=AgNO_(3),Z=Na_(2)[Ag(S_(2)O_(3))_(2)]`
`W=Ag_(2)O, X=NO,Y=AgNO_(3),Z=Na_(3)[Ag(S_(2)O_(3))_(2)]`
`W=Ag, X=NO_(2),Y=AgNO_(3),Z=Na_(3)[Ag(S_(2)O_(3))_(2)]`
`W=Ag_(2)O, X=N_(2),Y=AgNO_(3),Z=NA[Ag(S_(2)O_(3))_(2)]`

Solution :`Na_(2)[overset(II)(FE)(NO)(CN)_(5)]+Na_(2)S to Na[overset(II)(Fe)(CN)_(5)(NOS)]`
85343.

Acidified iodates are reduced to…..by SO_2

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Iodites
Iodide
Iodine
None

Answer :C
85344.

AgNO_(3) solution can't be stored in copper vessels, because. . . .

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`E_(Ag^(+)|Ag)^(Theta) gt E_(Cu^(2+)|Cu)^(Theta)`
`E_(Ag^(+)|Ag)^(Theta) lt E_(Cu^(2+)|Cu)^(Theta)`
`E_(Ag^(+)|Ag)^(Theta) ne E_(Cu^(2+)|Cu)^(Theta)`
Ag is precious metal.

SOLUTION :Following reaction occur and `Cu^(2+)` ions are formed in solution.
`2AgNO_(3)+Cu_((S)) to Ag_((S)) +Cu_((aq))^(2+)+2NO_(3(aq))^(-)`
`E_(Ag^(+)|Ag)^(Theta)=0.80V, E_(Cu^(2+)|Cu)^(Theta)=0.34V`
So, reduction of `Ag^(+)` occur. And `Ag^(+)` is oxidizing AGENT. oxidation of `Cu^(2+)` occur and reaction occur for those WHOSE `E_(cell)^(Theta)` is LESS.
85345.

Acidification results in cleavage of bond at___carbon.

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ANSWER :2
85346.

AgNO_3 gives yellow ppt. with:

Answer»

`KIO_3`
KI
`CHI_3`
`CH_2I_2`

ANSWER :B
85347.

AgNO_(3) gives yellow ppt with

Answer»

`KIO_(3)`
KI
`CHI_(3)`
`CH_(2)I_(2)`

Answer :B
85348.

AgNO_(3) gives red precipitate with

Answer»

Nal
KCI
`NaNO_(3)`
`Na_(2)CrO_(4)`

Answer :D
85349.

Acidifed K_(2)Cr_(2)O_(7) oxidises H_(2)S to :

Answer»

`SO_(2)`
`SO_(3)`
S
`H_(2)SO_(4) + S`

Solution :`3H_(2)S + Cr_(2)O_(7)^(2-) + 8H^(+) to 2Cr^(3+) + 3S + 7H_(2)O`
85350.

AgNO_(3) gives a red ppt. with

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`KI`
`NABR`
`NaNO_(3)`
`K_(2)CrO_(4)`

Solution :`2AgNO_(3)+K_(2)CrO_(4)rarrunderset("(Red)")(Ag_(2)CrO_(4))+2KNO_(3)`