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8551.

(X)C_(4)H_(7)O Cloverset(NH_(3))rarrC_(4)H_(9)ONunderset(KOH)overset(Br_(2))rarrCH_(3)CH_(2)CH_(2)NH_(2): Compound (X) is :

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SOLUTION :(a)
8552.

Which one of the following cations gives a brick red flame by flame test

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`BA^(2+)`
`Sr^(2+)`
`Ca^(2+)`
`Zn^(2+)`

ANSWER :C
8553.

The well known compouns, (+) lactic acid and (-) lactic acid have the same molecular formula, C_(3)H_(6)O_(3). The correct relationship between them is:

Answer»

CONSTITUTIONAL isomerism
geometrical isomerism
optical isomerism
identicalness.

Answer :C
8554.

Which of the following is/are true statements

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Water vapour is absorbed by ANHYDROUS calcium chloride both adsorbed by silica gel.
`NH_(3)` is absorbed by water but adsorbed by charcoal.
Sugar is DECOLOURIZED by animal charcoal based on adsorption.
Water is absorbed by conc `H_(2)SO_(4)` .

Solution :N//A
8555.

Which of the following compound is chiral?

Answer»

1-pentanol
3-pentanol
3-Methyl-1-butanol

Answer :C
8556.

When ferric chloride is treated with potassium ferrocyanide, we get:

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TURNBULL blue
Zeise salt
Prussian blue
None

Answer :C
8557.

The statements regarding N, molecule are I) The Bond energy is 945. 4 KJ/mole II) It has triple bond III)It contains 2sigma and 1pi bond The correct combination is

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Only II is CORRECT
I & II are correct
II and III are correct
All are correct

ANSWER :B
8558.

Which of the following compounds are linear?

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SOLUTION :
8559.

Which one of the following is ethanoic acid ?

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HCOOH
`CH_(3)COOH`
`CH_(3)CH_(2)COOH`
`CH_(3)CH_(2)CH_(2)COOH`

ANSWER :B
8560.

Which statement(s) about conductivity of water is/are correct?

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it possesses almost non-conducting nature
it is obtained by DISTILLATION of water several times.
It is contaminated with LITTLE ACID
None of these

Answer :A::B
8561.

When either enantiomer of 3-chloro-l-butene ((R) or (S)] is subjected to hydrolysis, the products of the reaction are optically inactive. Explain these results.

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Solution :The solvolysis REACTION is `S_N^1` . The INTERMEDIATE ALLYLIC cation is ACHIRAL and therefore reacts with water to give the ENANTIOMERIC 3-buten-2-ols in equal amounts and to give some of the achiral 2-buten-1-ol:
8562.

What will happen if C Cl_(4) is treated with AgNO_(3)

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A white ppt. of AGCL will FORM
`NO_(2)` will be evolved
`C Cl_(4)` will dissolved in `AgNO_(3)`
Nothing will happen

Solution :Because `C Cl_(4)` is a organic solvent and `AgNO_(3)` is insoluble in organic solvent.
8563.

Which of the following carboxylic acids do not undergo decarboxylation simply on heating?

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`F_(3)C-overset(O)overset("||")C-OH`
`H_(2)C=CH-overset(O)overset("||")C-OH`

ANSWER :A::C
8564.

Two moles of ammonia gas are introduced into a previously evacuated 1 L flask in which it partially dissociates at high temperature as:2NH_(3)(g)hArr N_(2)(g)+3H_(2)(g)At equilibrium 1.0 mole of NH_(3)(g)is found. What is K_(c ) ?

Answer»

`0.75`
`1.5`
`1.68
`0.46`

Solution :`{:(,2NH_(3)(g),hArr,N_(2)(g),+,3H_(2)(g)),("INITIAL conc.",2,,0,,0),("At. equal.",1,,0.5,,1.5):}`
`K=([N_(2)][H_(2)]^(3))/([NH_(3)]^(2))`
`=((0.5)(1.5)^(3))/((1)^(2))=1.7`
8565.

Which of the following is trimethyl acetaldehyde ?

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`(CH_(3))_(3) C - CH_(2) - CHO`
`(CH_(3))_(3) C - CH_(2) - CHO`
`(CH_(3))_(3) C - CHO`
`(CH_(3))_(2) CH - CH(CH_(3))CHO`

ANSWER :C
8566.

Which of the following willnot be solube in sodium hydrogen carbonate

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o-Nitrophenol
Benzenesulphonic ACID
2,4,6-trinitrophenol
Benzoic acid

Solution :o-nitrophenol is WEAKER acid than `HCO_(3)^(-)`
8567.

Which of the following is the most basic oxide?

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`Sb_(2)O_(3)`
`Bi_(2)O_(3)`
`SeO_(2)`
`Al_(2)O_(3)`

ANSWER :B
8568.

Which of the following decreasing order is correct in Williamson synthesis of the compounds ?

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II gt IV gt III gt I
I gt II gt III gt IV
IV gt III gt II gt I
III gt II gt I gt IV

SOLUTION :`CH_2=CH-CH_2-BrgtCH_3CH_2CH_2-BrgtCH_3CH_2CH_2-CIgt(CH_3)_3C-Br`(allylic and 1^(@))`,`(1^(@)and C-Br bond)`,`(1^(@)and C-CI bond)`, `(3^(@))`.
8569.

What are the raw materials required for the manufacture of bakelite?

Answer»

ETHANE 1,2-diol + BENZENE 1,4 - dicarboxylic acid
phenol + METHANAL
adipic acid + hexamethylene DIAMINE
isoprene + methanal

Solution : phenol + methanal
8570.

which of the following statements , about the advantage of roasting of sulphide ore before reduction is not true ?

Answer»

The `Delta_fG^@` of the SUPHIDE is GREATER than those for `CS_2 and H_2S`
The `Delta_fG^@` is negative for roasting of sulphite ore to oxide .
Roasting of the SULPHIDE to the oxide is thermodynamically feasible.
Carbon and HYDROGEN are SUITABLE reducing agents for metal sulphides.

Answer :D
8571.

Which will undergo reaction with ammonical AgNO_(3) :

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`CH_(3)-CH=CH-C-=CH`
`CH_(3)-CH_(2)-CH=CH-CH_(2)-CH_(3)`
`CH_(2)=CH-CH_(2)-CH_(3)`

SOLUTION :N//A
8572.

Which species has the maximum ionic radius :

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`NA^+`
`O^(2-)`
`F^-`
`Mg^(2+)`

Answer :B
8573.

Which is the correct order of increasing basic strength ?

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`MgOltBeOltCaOltBaO`
`BeOltMgOltCaOltBaO`
`BaOltCaOltMgOltBeO`
`CaOltBaOltBeOltMgO`

ANSWER :B
8574.

Which of the following is a ketohexose ?

Answer»

FRUCTOSE
GLUCOSE
RIBOSE
STARCH .

ANSWER :A
8575.

The sum of the first and second ionisation enthalpies and those of third and fourth ionisation enthalpies of nickel and platinum are given below: {:(,,IE_(1)+IE_(2)(kJ mol^(-1)),,IE_(3)+IE_(4)(kJ mol^(-1))),(Ni,,2.49,,8.80),(Pt,,2.66,,6.70):} Taking these values into account write : (i) the most common oxidation state for Ni and Pt and its reason. (ii) the name of the metal (Ni or Pt) which can form compounds in +4 oxidation state more easily and why?

Answer»

Solution :(i) Ni SHOWS +2 oxidation STATE because of LOWER `(IE_(1)+IE_(2))`. Platinum shows +4 oxidation state because extra ENERGY `IE_(3)+IE_(4)` is balanced by HYDRATION energy.
(ii) Pt can form compounds in +4 oxidation state because the energy required to remove four electrons is less in case of Pt than Ni.
8576.

Write structures and IUPAC names of the amide which gives propanamine by Hoffmann bromamide recation.

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SOLUTION :Propanamine contains three carbon atoms. Hence the AMIDE MOLECULE should contain FOUR carbon atoms. It is butanamide. Its structure is
`CH_(3)-CH_(2)-CH_(2)-CONH_(2)`.
8577.

The two isomers X and Y with the formul Cr(H_(2)O_(5))ClBr_(2) were taken for experiment on depression in freezing point. It was found that one mole of X gave depression corresponding to 2 moles of particles and one mole of Y gave depression due to 3 moles of particles. The structural formulae of X and Y respectively are

Answer»

`[Cr(H_(2)O)_(5)Cl]Br_(2) , [Cr(H_(2)O)_(4)Br_(2)]Cl.H_(2)O`
`[Cr(H_(2)O)_(5)Cl]Br_(2) , [Cr(H_(2)O)_(3)ClBr_(2)].2H_(2)O`
`[Cr(H_(2)O)_(5)Br]BrCl , [Cr(H_(2)O)_(4)ClBr]Br.H_(2)O`
`[Cr(H_(2)O)_(4)Br_(2)]Cl.H_(2)O, [Cr(H_(2)O)_(5)Cl]Br_(2)`

Solution :Depression in FREEZING point is a colligative property that depends upon the number of moles of ions which a comples may give in solution. X gave depression corresponding to 2 moles of particles. It means 2 mol of ions of a complexis present in solution, which is only possible when comples is in the FORM `[Cr(H_(2)O)_(4)Br_(2)]Cl. H_(2)O` or `[Cr(H_(2)O)_(4)Br_(2)]^(+)Cl^(-)`. SIMILARLY, Y complex will be `[Cr(H_(2)O)_(5)Cl]Br_(2)` or `[Cr(H_(2)O)_(5)Cl]^(+)+2Br^(+)`.
8578.

Total number of isomers of [Pt(NH_(3))(Br)(Cl)(py)] are

Answer»


Solution :Mabcd (sqr. Planar)
(ab)(CD)
(ac)(BD)
(AD)(bc)
8579.

What is the oxidation number ofcarbonyl carbon in methanal ?

Answer»

`+3`
`+2`
`+4`
0

Solution :`H-overset(O)overset(||)(C)-HorHCHO`
`+1+x-2+1=0`
or x=0
8580.

Which one of the following inhibits bacterial cell wall biosynthesis?

Answer»

ERYTHROMYCIN
AZITHROMYCIN
PENICILLIN
cetrizine

Solution : penicillin
8581.

Which of the following expressions correctly represents the equivalent conductance at infinite dilution of Al_(2)(SO_(4))_(3)? Given that Lambda_(Al^(3+))^(@) and Lambda_(SO_(4)^(2-))^(@)are the equivalent conductances at infinite dilution of the respective ions ?

Answer»

`2Lambda_(Al^(3+))^(@) + 3Lambda_(SO_(4)^(2-))^(@)`
`Lambda_(Al^(3+))^(@) + Lambda_(SO_(4)^(3-))^(@)`
`(Lambda_(Al^(3+))^(@) + Lambda_(SO_(4)^(2-))^(@) + Lambda_(SO_(4)^(2-))^(@)) XX 6`
`1/3 Lambda_(Al^(3+))^(@) + 1/2 Lambda_(SO_(4)^(2-))^(@)`

Answer :B
8582.

Whichof the followingis correctstatement aboutbasicityof amine ?

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ANSWER :B
8583.

The van der Waals' constants for four gases P,Q,R and S are 4.17 , 3.59, 6.71 and 3.8 atm L^(2) mol^(-2) respectively. The ascending order for their liquefication is

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<P>`R lt P lt S lt Q`
`Q lt S lt R lt P `
`Q lt S lt P lt R `
`R lt P lt Q lt S`

Solution :GREATER is the value of van DER Waals CONSTANT, easier is the liquefication.
8584.

Which of the following is amorphous in nature?

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QUARTZ
`CuSO_(4).5H_(2)O`
Dry ice
Fused silica glass

Answer :D
8585.

The strongest base is :

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`CL^-`
`CH_3COO^-`
`SO_4^(2-)`
`NO_2^-`

ANSWER :B
8586.

Which one is more paramagnetic: Fe^(3+) or Fe^(3+) ?

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SOLUTION :`FE^(3+)`
8587.

What is the product when C_(6)H_(5)CH_(2)NH_(2) reacts with HNO ?

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Solution :When benzylamine is treated with `HNO_(2)`, bynzylidiazonium CHLORIDE is formed formed which being unstable decomposes to FORM benzyl alcohol.
`UNDERSET("Benzylamine")(C_(6)H_(5)CH_(2)NH_(2)) underset(HCl)overset(HNO_(2))to underset(("unstable"))([C_(6)H_(5)CH_(2)-overset(+)(N)-=N]Cl^(-)) underset(-N_(2)-HCl)overset(H_(2)O)to underset("Benzyl alcohol")(C_(6)H_(5)CH_(2)OH)`
8588.

Tincture of iodine (2-3% I_2 in water/alcohol) is

Answer»

ANTISEPTIC
Disinfectant
Analgesic
ANTIPYRETIC

ANSWER :A
8589.

Which contains ionic as well as covalent bonds?

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LICI
`(NH_4)_2S`
`PC l_5`
`CaF_2`

ANSWER :B
8590.

Which of the following has maximum bond energy ?

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`O_2`
`O_2^+`
`O_2^(2-)`
`O_(2)^(-)`

ANSWER :B
8591.

What is the anion present in pyrosilicates?

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SOLUTION :`Si_2O_7^(6-)`
8592.

Which carbohydrate is an essential constituent of plant cells ?

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STARCH
SUCROSE
Cellulose
Maltose.

ANSWER :C
8593.

Which of the statement with regard to Isotopes and Isobars is/are correct ? 1. Isotopes have same mass number. 2. Isobars have same atomic number. Select the correct answer using the code given below :

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1 only
2 only
Both 1 and 2
Neither 1 nor 2

Answer :D
8594.

When a piece of copper wire is immersed in a solution of aqueous silver nitrate, the solution becomes blue. This is a consequence of :

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OXIDATION of silver
oxidation of copper
formation of copper complex
reduction of copper

Solution :(B) CU (s) is oxidised to `Cu^(2+)` ions.
8595.

Which of the following is non-biodegradable ?

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SOAP
Paper
Polyethene
WOOD

ANSWER :C
8596.

Which loses charge at cathode

Answer»

IONS
cations
ANIONS
both anions and cations

SOLUTION :Cations carrying positive charge move TOWARDS cathode where they get DISCHARGED .
8597.

What is physical adsorption ?

Answer»

SOLUTION :If the adsorbate is held on a surface by WEAK VAN der Walls forces, the adsorption is CALLED physical adsorption.
8598.

Which of the following is not a mixture of hydrocarbons?

Answer»

CANDLE WAX
Kerosene
Vegetable oils
Paraffin oil

Answer :D
8599.

Write down the steps involved in a metallurgical process.

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Solution :The extraction of a metal from its ORE CONSISTS the following METALLURGICAL PROCESS.
(i) Concentration of the ore
(II) Extraction of crude metal
(iii) Refining of crude metal
8600.

Whichof the following antiseptics is used to cure wounds ?

Answer»

PENCILLIN
CHLORAMPHENICOL
TETRACYLINE
FURACINE

ANSWER :D