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86201.

Absolute alcohol cannot be obtained by simple fractional distillation because

Answer»

PURE `C_(2)H_(5)OH` is unstable
`C_(2)H_(5)OH` forms chemical BONDING with water
oxidation
it forms AZEOTROPIC mixture with water

Answer :D
86202.

Absolute alcohol can be obtained from rectified spirit

Answer»

By removing the water in using concentrated sulphuric acid
By removing the water using PHOSPHORUS pentoxide
By distilling with the appropriatye amount of benzene
By distiling over PLENTY of QUICK lime

Answer :B
86203.

Absolute alcohol acnnot be obtained by simple fractionation of solution of ethanol and water because:

Answer»

Boiling POINT are very near
Ethanol remains dissolved in water
They form a CONSTANT boiling mixture
Ethanol MOLECULES are solvated

Answer :C
86204.

Abscisic acid is

Answer»

TRIGLYCERIDE of LONG CHAIN alcohol
sesqui terpenes
diterpenes
glycolipids

Answer :B
86205.

Above the inversion temperature, mu(J.T. coefficient):

Answer»

Is positive
Is zero
Is nagative
Depends on the gas

Answer :C
86206.

Above reaction takes place in three steps : Step a Step b Rate determining step (slow step) is/are

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a
B
c
a and c.

Answer :B
86207.

Above reaction takes place in three steps : Step a Step b Consider the following aldehydes {:(HCHO,"CCl"_(3)CHO,CH_(3)CHO,C_(6)H_(5)CHO),("(a)","(b)","(c)","(d)"):} The reaction is not given by

Answer»

a, b
b, c
c, a
only c.

Answer :D
86208.

Above given question, the value of rate constant for appearance of AB(g) is :

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`2.5xx10^(-4)`
`2.5xx10^(-2)`
`1.25xx10^(-2)`
NONE of these

Answer :B
86209.

Above Gauche form is stable when Z is:-

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`-F`
`-OH`
`-OCH_(3)`
All of these

Answer :D
86210.

Above conversion can be achieved by

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`NH_2-NH_(2)//NaOH`
`Zn-Hg//HCl`
`LiAlH_(4)`
`NaBH_(4)`

ANSWER :B
86211.

above compounds (P) & (Q) can be differentiated by :

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amm. `AgNO_(3)`
`NAOH`
`FeCl_(3)`
Both (a) & (b)

Solution :`P OVERSET(AgNO_(3))RARR AgCl darr` (ppt.)
86212.

Above compounds can be differentiated by which of the following chemical test? (used in decreasing order)

Answer»

`NaOH, NaHCO_(3), HCl`
`HCl, NaOH, NaHCO_(3)`
`NaHCO_(3), NaOH, HCl`
`NaOH, HCl, NaHCO_(3)`

Solution :
The mixture is composed of a neutral compound m-nitrobenzene, two acids (m-nitrobenzoic acid and m-nitrophenol), and a base (m-nitroaniline). M-nitrobenzoic acid is strong enough as an acid to DECOMPOSE sodium carbonate, m-nitrophenol is not, but does form a salt with sodium hydroxide. Hence, one way in which a separation may be EFFECTED is as follows. Dissolve the mixture in ether (all components are soluble).
(i) Extract the ETHEREAL solution with aqueous sodium carbonate. Only m-nitrobenzoic acid enters the aqueous layer, and may be recovered on acidification.
(II) Extract the ethereal solution from (i) with aqueous sodium hydroxide. Only m-nitrophenol enters the aqueous layer, and may be recovered on acidification.
(III) Extract the ethereal solution form (ii) with hydrochloric acid. Only m-nitroaniline enters the aqueous layer, and may be recovered on basifying the solution.
(iv) Evaporate off the ether from the ethereal solution from (iii). This leaves m-nitrobenzene.
86213.

Above compounds can be differentiated by using the reagent :

Answer»

`NAOH`, TOLLEN's reagent, `FeCl_(3)`
`CrO_(3)`, Tollen's reagent, `FeCl_(3)`
Tollen's reagent, `CrO_(3), FeCl_(3)`
NA, Tollen's reagent, `FeCl_(3)`

Solution :
86214.

Above compounds can be differentiated by the salicylate. Which of the following chemical test ? (used in decreasing order)

Answer»

`NAOH, FeCl_(3), NaHCO_(3)`
AQ. `NaHCO_(3), FeCl_(3), NaOH`
`NAOI, NaOH, NaHCO_(3)`
`NaOH, Na, NaHCO_(3)`

Solution :`FeCl_(3)` test for enol.
86215.

Above1073 K,………… reducesFeOto Fewhilebelow1073K, …………… reducesFe_ 2O _ 3to Fe.

Answer»


ANSWER :COKE , CO
86216.

About "White phosphorous" I. It's ignitiontemperature in very high. II. It glows in the dark due to oxidation. III. White phosphorousis poisonous in nature. IV. It has pungent smell .

Answer»

II and III only
II and IV only
II, I, IV and III
I, II, III and IV

Answer :A::D
86217.

About "Van-Arkel"

Answer»

Van-Arkel method used for refining ZIRCONIUM.
Aluminium is a BAD conductor of heat.
Aluminium shows high resistance to corrosion.
Aluminium is a good conductor of heat

Answer :B
86218.

About the basic open hearth process, which statement is wrong

Answer»

Limestone is ADDED to the charge
Phosphorus impurity cannot be removed by this process
Carbon content of the steel can be UNIFORMLY CONTROLLED over a series of batches
Iron SCRAP can be batches

Answer :A
86219.

about " potassium permanganate "

Answer»

Potassiumpermanganateis PREPARED frompyrolusite ore.
Itmeltsat 513 k
It boilsat `50^(@)C`
It exitsin theformof darkpurple crystals.

Answer :C
86220.

About"Potassiumdichromate " I. It is an orangeredcrystalline solid II.It ismeltsat 671 K . III .It ismoderatleysolublein hotwater . IV It ismuchsoluble in coldwater .

Answer»

I, II and III only
II andIV only
I and II only
I , II , III and IV

ANSWER :C
86221.

About "Nitric acid " I. It is prepared in large scales by ostwald's process. II. It completely misciblewith water forming a constant boiling mixture. III. It boils at 56^(@)C.

Answer»

I, II only
I, II and III only
I and III
I, III only

Answer :A
86222.

About "Phosphine"

Answer»

It is PREPARED by HEATING nitric acid.
It REACTS with halogen to GIVE phosphorous penta halides.
It is a poisonous GAS with rotten fish small.
It is used in Homles signal.

Answer :A::B::C::D
86223.

About half of H_3SO_4 produced in world is used to

Answer»

MANUFACTURE of soap
Manufacture of plastics
Manufacture of paints
Manufacture of fertilizers

Answer :D
86224.

About H_2 SO_4, which of the following statements is incorrect ?

Answer»

REDUCING AGENT
Dehydrating agent
Sulphonating agent
HIGHLY VISCOUS

Answer :A
86225.

About ''Collision theory''

Answer»

Collision theory used to predict the rates of chemical reactions for gases.
This theory is based on the kinetic theory of gases
Chemical reactions occur as a result of collision between the REACTING molecules
Decrease in CONCENTRATION of the reactant brings about more COLLISIONS.

Answer :D
86226.

About "Electrolytic refining"

Answer»

The crude metal is refining by ELECTROLYSIS
The rods of IMPURE metal are USED as cathode
Thin strips of pue metal are used as cathode.
Less electropositive IMPURITIES removed as anode mud.

Answer :B
86227.

About " Ammonia" I. Ammonia is formed by the hydrolysis of urea. II. It is heavier than air. III. It can readily liquefied by at aboutatmospheric pressure. IV. Liquid ammonia resembleswater in its physicalproperties.

Answer»

I, III and IV only
II, I , III and IV
II, I , IV and III
I, II, III and IV

Answer :A::D
86228.

About aminessomestatements are givenbelow, . 1. theypossess towlone pair of electronson nitrogenatom. 2. theseare monoacidic base 3 theirbasicity is one . 4. theycan acceptproton. Among the above , true statements (s) is /are

Answer»

only 2 and 3
only 3 and 4
only 2,3 and 4
all of these

ANSWER :C
86229.

About a gaseous reaction xX+yY to l L +mM which statement is wrong?

Answer»

X litres of X combines with y litre of Y to give L and M
x MOLES of X combines with y moles of Y to give L and M
x number of MOLECULES of X combine y molecules of Y to form L and M
x g of X combines with y g of Y to give M and L

Answer :D
86230.

About aliphatic hydrocarbon some statements are given below, 1. chlorination takes place slowly in drak 2. idoination is carried in the presence of HgO 3. photochlorination is a electrophilic substitution reaction 4. direct iodination of alkane is ir-reversible reaction Among the above, the correct statement(s) is /are

Answer»

only 3
only 1, 2 and 3
only2 and 3
only 1 and 2

Answer :D
86231.

About 78% of earth atmosphere contains, ……………… .

Answer»

P
As
N
Bi

Solution :N
86232.

About 3 dm^(3) gastric juice are produced per day in a human body from other body fluids such as blood whose pH = 7.4 at 37^(@) C. What is the minimum work in kJ required to produce 3 dm^(3) gastric juice at the body temperature? The pH of gastric juice =1

Answer»


ANSWER :`0111`
86233.

About 3 dm^(3) gastric juice are produced per day in a human body from other body fluids such as blood whose pH = 7.4at 37^(@)C. What is the minimum work in kJ required to produce 3 dm^(3) gastric juice at the body temperature ? The pH of gastric juice =1.

Answer»


ANSWER :`0111`
86234.

About 20 km above the earth there is an ozone layer. Which one of the following statements about ozone and ozone layer is true?

Answer»

OZONE layer is BENEFICIAL to us because ozone cuts out the ULTRAVIOLET radiation of the sun
The conversion of ozone to oxygen is an endothermic REACTION.
Ozone has a triatomic LINEAR molecule.
Ozone layer is harmful to us because it cuts out the radiation useful for photosynthesis.

Solution :Ozone layer protects us from harmful ultraviolet radiations of Sun.
86235.

Abnormal molar mass is produced by

Answer»

ASSOCIATION of solute
DISSOCIATION of solute
both association and dissociation of solute
separation by SEMI PERMEABLE membrane

Answer :C
86236.

Abnormal colligative properties are obtained when the solute :

Answer»

undergoes association.
undergoes dissociation.
both (a) and (b).
NEITHER (a) nor (b)

Answer :C
86237.

(a)Between CH_(3)NH_(2)and C_(6)H_(5)NH_(2) which is more base? Give reason. (b) (i) Name the main product when aniline is heated with alcoholic KOH and chloroform. (ii) Give the IUPAC name of (CH_(3))_(2)N-C_(2)H_(5).(c ) Complete the chemical equation.CH_(3)CONH_(2) overset(Br_(2)//NaOH )to

Answer»

SOLUTION :(a)`CH_(3)NH_(2)` because in methylamine, `CH_(3)` GROUP is ELECTRON donating Which increases the electron density on nitrogen atom due to +I effect.
(B)(i)Phenyl isocyamide.
(ii) N, N-dimethylethanamine.
(c)`CH_(3)CONH_(2) overset(Br_(2)//NAOH )to CH_(3)NH_(2) + 2NaBr +Na_(2)CO_(3) + 2H_(2)O`
86238.

A,B,C,and D are four elements whose standard oxidation potentials are +2.82V , +2.71V ,+1.67V and -2.87V. The strongest reducing agent is

Answer»

A
B
C
D

Solution :APPLICATION of EMF SERIES.
86239.

A,B,C and D elements form compounds AC, A_(2)D and BD. If AC and A_(2)D are radioactive and BD is not radioactive compound, then which among the following pair of compounds may not be radioactive:

Answer»

`A_(2) and BD`
`BD and B_(2)C`
`AD and C_(2)D`
`B_(@)C and AD`

ANSWER :B
86240.

Find out the correct pair: (a)Bauxite-Iron (b)Siderite-Aluminium (c )Malachite-Copper (d)Argentite-Gold

Answer»

SOLUTION :(C )Malachite-Copper
86241.

AB_(2) andA_(2)B_(3) are two compounds of the elements A and B 0.15 mole of each of these compounds weights 9.3and 15.9g respectively. Find the atomic masses of A and B.

Answer»

Solution :LET atomic masses of A and B be 'a' and 'b' respectively.
`THEREFORE 0.15(a+2b)=9.3g`
0.15(2a+3b)=15.9g
i.e., a+2b=62
On SOLVING EQUATIONS (i) and (ii)
b=18 and a=26
86242.

AB to A+B is a zero order reaction,if K=4xx10^(-1) "molelitre"^(-1)"second"^(-1),then how much will be the production rate in mole "litre"^(-1)"second"^(-1) for A?

Answer»

`2xx10^(-1)`
`4XX10`
`1.6xx10^(-3)`
`2xx10^(-2)`

Answer :B
86243.

AB is an ionic solid. If the ratio of ionic radii of A^(+) and B^(+) is 0.52. What is the co-ordination number of B?

Answer»

2
3
6
8

Answer :C
86244.

AB crystallizes in a body centred cubic lattice with edge length 'a' eqal to 387 pm. The distance between two oppositely charged ions in the lattice is :

Answer»

200pm
300pm
335pm
250pm

Solution :DISTANCE between oppositely CHARGED IONS in bcc
`= ( sqrt( 3))/( 2) a = ( 1.732 xx ( 387p m))/( 2) = 335 `pm
86245.

AB crystallises in a bcc lattice with edge length ‘a’ equal to 387 pm. The distance between two oppositely charged ions in the lattice is

Answer»

335 PM
250 pm
200 pm
300 pm

Answer :A
86246.

AB crystallizes in a body centred cubic lanice with edge length 'a' equal to 387 pm. The distance between two oppositely charged ions in the Janice is :

Answer»

335 pm
250 pm
200 pm
300 pm

Solution :For bcc LATTICE BODY diagonal `=asqrt3`
the distance between the two oppositely charged ions.
`=(a)/(2)sqrt(3)`
`=(387xx1.732)/(2)=335` pm.
86247.

A,B and C are ideal gases. Their molecular weights are 2,4 and 28 respectively. The rate of diffusion of these gases follow the order

Answer»

`C gt A gt B`
`C gt B gt A`
`A = B=C`
`A gt B gt C`

Solution :According to GRAHAM's LAW of diffusion, rate of diffusion `prop (1)/(sqrt("molecular weight"))`
As the molecular weight of the gas increases, rate of diffusion decreases.
86248.

AB, A_2 and B_2 are diatomic molecules. If the bond enthalpies A_2 AB and B_2 are in the ratio 1:1:0.5 and the enthalpy of formation of AB fron A_2 and B_2 is -100 kJ mol^-1, what is the bond enthalpy of A_2:

Answer»

200 KJ `mol^-1`
200 kJ `mol^-1`
100 kJ `mol^-1`
300 kJ `mol^-1`

ANSWER :A
86249.

(a)Azulene has an appreciabel dipole moment.Write the reasonance structure that explains the dipole moment and its aromaticity. (b)In the cse of halogen-substituted azulenes,a halogen atom onC-6can be displace bynucleophile while one onC-1is unreactive towards nucleophile .Rationalise this differemce in behaviou.

Answer»

Solution :
The major CONTRIBUTION to the HYBRID must be one that involves charge separation ,having aromatic five-and seven-membered rings.
(b)
`ArSN` intermediate reaction is favoured by five-membered ring WOTH cyclopentadienyl anion character(aromatic).
In the second case`BAR(e)`discoalisation into the other (seven-membered)ring result in eight`bar(e)`-in that ring ,which DOESNOT stablise it.
86250.

A(aq)rarrB(aq)+C(aq) is first order reaction. "Time"""t""oo "moles of reagent " ""n_(1)""n_(2) Reaction prgress is measured with the help of titration of reagent 'R'. If all A, B and C react with reagent and have 'n' factors [n factor,eq. mass=("mol.mass")/(n) in the ratio of 1:2:3 with the reagent, the k in terms of t, n_(1) and n_(2) is :

Answer»

`k=10/tln(n_(2)/(n_(2)-n_(1)))`
`k=1/tln.((2n_(2))/(n_(2)-n_(1)))`
`k=1/tln.((4n_(2))/(n_(2)-n_(1)))`
`k=1/tln.((4n_(2))/(5(n_(2)-n_(1))))`

ANSWER :D