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8751.

Vanadium monoxide shows ………………….defect.

Answer»

SOLUTION :SCHOTTKY DEFECT
8752.

Which one of the halogens is radioactive ?

Answer»

SOLUTION :ASTATINE (At) is RADIOACTIVE HALOGEN.
8753.

Which of the following has maximum number of unpaired electrons

Answer»

 `Mg^(2+)`
`TI^(3+)`
`V^(3+)`
`FE^(2+)`

ANSWER :D
8754.

Which one does not belong to ligand:

Answer»

`PH_3`
`NO^+`
`BF_3`
`CI^-`

ANSWER :C
8755.

Which of the following are not used as food preservatives ?

Answer»

Table salt
SODIUM HYDROGEN carbonate
CANE SUGAR
Benzoic acid

Solution :Sodium hydrogen carbonate and cane sugar are not PRESERVATIVES.
8756.

Which of the following sets contain only copolymers?

Answer»

SBR, Glyptal, Nylon 6,6
Nylon 6, Butyl rubber, NEOPRENE
POLYTHENE, Polyester, PVC
MELMAC, Bakelite, Teflon

Answer :A
8757.

What are (X) and (Y) in the following reaction? Give the mechanism of formation of (X) and (Y).

Answer»

SOLUTION :
8758.

The total number of fundamental particles in one atom ofoverset 14(6C) is:

Answer»

6
8
14
20

Answer :D
8759.

Zn(s)+Cl_(2)(1atm)toZn^(2+)+2Cl^(-). E_(cell)^(o) of the cell is 2.12 V. To increase E

Answer»

`[Zn^(2+)]` should be INCREASED
`[Zn^(2+)]` should be decreased
`[Cl^(-)]` should be decreased
`P_(Cl_(2))` should be decreased

Solution :According to Nernst's EQUATION
`E_(CELL)=E_(cell)^(o)(-0.059)/(2)"LOG"(["Anode"])/(["Cathode"])`
At anode`toZntoZ_(n)^(2+)+2e^(-)`
At cathode`toCl_(2)+2e^(-)to2Cl^(-)`
So, `E_(cell)=2.12(-0.059)/(2)"log"([Zn]^(++))/([Cl^(-)]^(2))`
E will be increase when CONCENTRATIONS of both `[Zn]^(++)` and `Cl^(-)` is decreased.
8760.

Which of the following reactions depict the nucleophilic substsitution of C_(2)H_(5)Br ?

Answer»

`C_(2)H_(5)Br+C_(2)H_(5)SN a to C_(2)H_(5)SC_(2)H_(5)+NABR`
`C_(2)H_(5)Br+2HtoC_(2)H_(6)+HB r`
`C_(2)H_(5)Br+AgCN to C_(2)H_(5)NC+AgBr`
`C_(2)H_(5)Br+KOH to C_(2)H_(5)OH+KB r`

Answer :A::C::D
8761.

Which of the following pairs represents linkage isomers?

Answer»

<P>`[Cu(NH_(3))_(4)][PtCl_(4)] and [Pt(NH_(3))_(4)][CuCl_(4)]` <BR>`Pd(P Ph_(3))_(2)(NCS)_(2)] and [Pd(P Ph_(3))_(2)(SCN)_(2)]`
`[Co(NH_(3))_(5)(NO_(3))]SO_(4) and [Co(NH_(3))_(5)(SO_(4))]NO_(3)`
`[PtCl_(2)(NH_(3))_(4)]Br and [PtBr_(2)(NH_(3))_(4)]Cl_(2)`.

Answer :B
8762.

Which of the following will give a primary amine on hydrolysis

Answer»

ALKYL isocyanide
Alkyl cyanide
Oxime
Nitroparaffin

Answer :A
8763.

Which one is the strongest bond?

Answer»

H - CI
CI-CI
C-CI
B-CI

Answer :A
8764.

Which of the following act as an antiseptic and disinfectant respectiely?

Answer»

0.2% PHENOL, 1% phenol
1% phenol, 0.2% phenol
2% phenol, 20% phenol
20% phenol, 2% phenol

SOLUTION :0.2% phenol, 1% phenol
8765.

Which of the following has the largest size

Answer»

`S^(2-)`
`Se^(2-)`
`O^(2-)`
`TE^(2-)`

SOLUTION :Size increases down the GROUP.
8766.

Which of the following is a secondary pollutant

Answer»

`NO_2`
`CO`
`O_3`
`SO_2`

SOLUTION :OZONE `(O_3)` is SECONDARY pollutants which is formed by the interaction of PRIMARY air pollutants.
8767.

Which one of the vitamin is syntbesised in. our body by using sun rays ?

Answer»

A
B complex
C
D

Answer :C
8768.

Which of the following is an addictive drug ?

Answer»

Papaverine
Pencilline
Sulphadiazine
ASPIRIN

ANSWER :A
8769.

What are Wade's Rule?

Answer»

Solution :Wade.s rules are USED to rationalize the SHAPE of borane dclusters by calculating the TOTAL number of SKELETAL eletron PAIRS (SEP) available for cluster bonding.
8770.

When excess amount of NH_(3) is reagent with Cl_(2)gives :-

Answer»

`NH_(4)CL`
`N_(2)`
`NCl_(3)`
(1) & (2) both

Answer :D
8771.

XeF_2 has a bent shape.

Answer»

SOLUTION :FALSE
8772.

Which of the following is a liquid?

Answer»

`SCl_(4)`
`SF_(6)`
`SF_(4)`
`OF_(2)`

Answer :A
8773.

Whichis to be used to prevent chemical reaction in food ?

Answer»

LOW temperature
High temperature
Salting
All of these

Answer :D
8774.

Which of the following compounds is not chiral

Answer»

`DCH_(2)CH_(2)CH_(2)Cl`
`CH_(3)CH_(2)CHDCl`
`CH_(3)CHDCH_(2)CH_(2)Cl`
`CH_(3)CHClCH_(2)D`

SOLUTION :`DCH_(2)-CH_(2)-CH_(2)-Cl` OTHERS are CHIRAL
`{:(""H),("|"),(CH_(3)-CH_(2)-C^(**)-D,),("|"),(""Cl):}``{:(""H),("|"),(CH_(3)-C^(**)-CH_(2)-CH_(2)-Cl),("|"),(""D):}`
`{:(""H),("|"),(CH_(3)-C^(**)-CH_(2)D),("|"),(""Cl):}`
8775.

What are P and Q? Name the reaction occuring in step 1. (i) C_(6)H_(5)-overset(O)overset(||)C- NH_(2)overset(Br_(2)//NaOH)toP (ii) Poverset(NaNO_(2)//HCl,0^(@)C)toQ

Answer»

SOLUTION :`P=CH_(3)NH_(2)` (Methanamine) `Q=CH_(3)OH` (METHYL ALCOHOL)
STEP- 1 reaction is Hoffmann bromomide degradation reaction.
8776.

Ultra microscope works on the principle of

Answer»

LIGHT reflection
Light absorption
Light scattering
Light polarization

Answer :C
8777.

Which elements in first transition series has maximum third ionization enthalpy?

Answer»

ZN
Cu
Mn
Cr

Solution :`Zn^(2+)` has `d^(10)` CONFIGURATION
8778.

Write the empirical formulae of the following : (i) N_(2)O_(4) (ii)C_(6)H_(6)(iii)C_(6)H_(12)O_(6)(iv)H_(2)O_(2)(v)H_(2)O (vi) Na_(2)CO_(3) (vii)CH_(3)COOH

Answer»

Solution :`(i)NO_(2) (II)CH (iii)CH_(2)O (iv)HO (v) H_(2)O (vi)Na_(2)CO_(3)`
8779.

Which of the following reactions are disproportionation reactions? (a) Cu^(+) rarr Cu^(2+) + Cu (b) MnO_(4)^(2-) + 4H^(+) rarr 2MnO_(4)^(-) + MnO_(2) + 2H_(2)O (c ) 2KMnO_(4) rarr K_(2)MnO_(4) + MnO_(2) + O_(2) (d) 2MnO_(4)^(-) + 3Mn^(2+) + 2H_(2)O rarr 5MnO_(2) + 4H^(+)

Answer»

a,b
a,b,C
b,c,d
a,d

Solution :`{:(Cu^(+), rarr, Cu^(2+) ,+, Cu),((+1),,(+2),,(0)):}`
`{:(MnO_(4)^(2-),+,4H^(+),rarr,2MnO_(4)^(-),+,MnO_(2),+,2H_(2)O),((+6),,,,(+7),,(+4),,):}`
8780.

Whichof thefollowingstands TURE formolecularityof a reaction?

Answer»

It ISTHE SUMOF exponentsof themolarconcentrationof thereactantsin therateequation
It mayhavea fractionalvalue
It isthe numberof moleculesof thereactantstakingpartin a singlestepchemicalreaction
It isdeterminedexperimentally .

Answer :C
8781.

When an atom X absorbs radiation with a photon energy than the ionization energy of the atom, the atom is ionized to generate an ion X^(+) and the electron (called a photoelectron) is ejected at the same time. In this event, the energy is conserved as shown in Figure 1, that is, Photon energy (h)=ionization energy (IE) of X+ kinetic energy of photoelectron. When a molecule, for example, H_(2), absorbs short-wavelength light, the photoelectron is ejected and an H_(2), ion with a variety of vibrational states is produced. A photoelectron spectrum is a plot of the number of photoelectrons as a function of the kinetic energy of the photoelectrons. Figure-2 shows a typical photoelectron spectrum when H_(2) in the lowest vibrational level is irradiated by monochromatic light of 21.2 eV. No photoelectrons are detected above 6.0 eV. (eV is a unit of energy and 1.0 eV is equal to 1.6xx10^(-19) J) Figure 1 Schematic diagram of photoelectron spectroscopy. Figure 2 Photoelectron spectrum of H_(2). The energy of the incident light is 21.2 eV ul("Calculate") the speed u (m s^(-1)) of the hydrogen atoms generated in the above reaction. H_(2) is assumed to be at rest. If you were unable to determine the value for E_(C), then use 5.0 eV for E_(C)

Answer»


ANSWER :The excess ENERGY is `16.7 eV (=21.2 eV-4.5 eV)`. Because two hydrogen atoms are GENERATED upon dissociation, half of this excess is released as translation energy of the hydrogen atoms.
`1/2 m u^(2)=8.35 eV=1.34xx10^(-18) J`
8782.

What is true for acetophenone ?

Answer»

It REACTS with alkaline `KMnO_(4)` FOLLOWED by acidic hydrolysis and forms benzoic acid
It reacts with iodine and NaOH to form triidomethane
It is prepared by the reaction of benzene with benzoyl chloride in presence of anhydrous ALUMINIUM chloride
It does not react with freshly prepared ammoniacal silver nitrate solution.

Answer :B
8783.

Which of the following volume (V) - temperature (T) plots represents the behaviour of one mole of an ideal gas at one atmospheric pressure?

Answer»




ANSWER :A
8784.

Which statement is incorrect about D?

Answer»

D can produce yellow ppt. on reaction with `OVERSET(Theta)" OH"//I_(2)`
D can be prepared by `Ph-C-=CH` on reaction with `Hg^(2+)//H^(+)//H_(2)O`
D can form geometrically isomeric oximes on reaction with `NH_(2)-OH`
D can be converted into ALCOHOL on reaction with `Zn(Hg)//HCl`.

Answer :D
8785.

When an atom X absorbs radiation with a photon energy than the ionization energy of the atom, the atom is ionized to generate an ion X^(+) and the electron (called a photoelectron) is ejected at the same time. In this event, the energy is conserved as shown in Figure 1, that is, Photon energy (h)=ionization energy (IE) of X+ kinetic energy of photoelectron. When a molecule, for example, H_(2), absorbs short-wavelength light, the photoelectron is ejected and an H_(2), ion with a variety of vibrational states is produced. A photoelectron spectrum is a plot of the number of photoelectrons as a function of the kinetic energy of the photoelectrons. Figure-2 shows a typical photoelectron spectrum when H_(2) in the lowest vibrational level is irradiated by monochromatic light of 21.2 eV. No photoelectrons are detected above 6.0 eV. (eV is a unit of energy and 1.0 eV is equal to 1.6xx10^(-19) J) Figure 1 Schematic diagram of photoelectron spectroscopy. Figure 2 Photoelectron spectrum of H_(2). The energy of the incident light is 21.2 eV Considering an energy cycle, ul("determine") the bond energy E_(D)( eV) of H_(2)^(+) to the first decimal place. If you were unable to determine the values for E_(B) and E_(C), then use 15.0 eV and 5.0 eV for E_(B) and E_(C), respectively.

Answer»


Answer :From Fig. `3` below
`E_(D)=E_(B)+E_(C)-DeltaE_(A1)=13.6+4.5-15.4=2.7 EV`
8786.

Which alkyl halide from the following pairs would you expect to react more rapidly by an S_N2 mechanism ? Explain your answer. (i) underset((A))(CH_3CH_2Br) " or " underset((B))underset(Br)underset(|)(CH_3CH_2CHCH_3) (ii) underset((C))underset(Br)underset(|)(CH_3CH_2CHCH_3) "or" underset((D))underset(CH_3)underset(|)(H_3C-C-Br) (iii) underset((E))underset(CH_(3))underset(|)(CH_3CHCH_2CH_2Br) "or" underset((F))underset(CH_3)underset(|)(CH_3CH_2CHCH_2Br)

Answer»

SOLUTION :(i) A, (II) C and (III) E
8787.

When an atom X absorbs radiation with a photon energy than the ionization energy of the atom, the atom is ionized to generate an ion X^(+) and the electron (called a photoelectron) is ejected at the same time. In this event, the energy is conserved as shown in Figure 1, that is, Photon energy (h)=ionization energy (IE) of X+ kinetic energy of photoelectron. When a molecule, for example, H_(2), absorbs short-wavelength light, the photoelectron is ejected and an H_(2), ion with a variety of vibrational states is produced. A photoelectron spectrum is a plot of the number of photoelectrons as a function of the kinetic energy of the photoelectrons. Figure-2 shows a typical photoelectron spectrum when H_(2) in the lowest vibrational level is irradiated by monochromatic light of 21.2 eV. No photoelectrons are detected above 6.0 eV. (eV is a unit of energy and 1.0 eV is equal to 1.6xx10^(-19) J) Figure 1 Schematic diagram of photoelectron spectroscopy. Figure 2 Photoelectron spectrum of H_(2). The energy of the incident light is 21.2 eV ul("Calculate") the threshold energy E_(E) (eV) of the following dissociative reaction to the first decimal place: H_(2) rarr H^(**) (n=2) +H^(+)+e^(-) If you were unable to determine the values for E_(B) and E_(C), then use 15.0 eV and 5.0 eV for E_(B) and E_(C) respectively. When H_(2) absorbs monochromatic light of 21.2 eV, the following dissociation process occurs at the same time. H_(2) overset(21.2 eV)(rarr)H(n=1)+H(n=1) Two hydrogen atoms move in opposite direction with the same speed.

Answer»


ANSWER :`(##RES_PHY_CHM_V01_XI_C02_E01_411_A01##)`
From figure `3` above, the threshold energy `E_(E)` for the dissociative IONIZATION reaction
`H_(2) RARR H^(**)(n=2)+H^(+)+e^(-)` is `E_(B)+E_(C)+10.2 EV=13.6+4.5+10.2=28.3 eV. E_(E)=28.3 eV`
8788.

Which is the possible number of stereo isomers for the following formula ? CH_(2)OH(CHOH)_(3)CHO

Answer»

4
8
12
16

Solution :`2^(3)=8`
8789.

When an atom X absorbs radiation with a photon energy than the ionization energy of the atom, the atom is ionized to generate an ion X^(+) and the electron (called a photoelectron) is ejected at the same time. In this event, the energy is conserved as shown in Figure 1, that is, Photon energy (h)=ionization energy (IE) of X+ kinetic energy of photoelectron. When a molecule, for example, H_(2), absorbs short-wavelength light, the photoelectron is ejected and an H_(2), ion with a variety of vibrational states is produced. A photoelectron spectrum is a plot of the number of photoelectrons as a function of the kinetic energy of the photoelectrons. Figure-2 shows a typical photoelectron spectrum when H_(2) in the lowest vibrational level is irradiated by monochromatic light of 21.2 eV. No photoelectrons are detected above 6.0 eV. (eV is a unit of energy and 1.0 eV is equal to 1.6xx10^(-19) J) Figure 1 Schematic diagram of photoelectron spectroscopy. Figure 2 Photoelectron spectrum of H_(2). The energy of the incident light is 21.2 eV ul("Determine") the bond energy E_(C)(eV) of H_(2) to the first decimal place.

Answer»


ANSWER :`24.9 eV`= BINDING energy of a HYDROGEN molecule `+10.2 eV+10.2 eV`
Thus, the binding energy of a hydrogen molecule `E_(C)=4.5 eV`
8790.

Which is the correct formula of freon 12?

Answer»

`"CCl"_(2)F_(2)`
`CF_(3)`Cl
`CHCl_(2)`F
`"CCl"_(3)`F

Answer :A
8791.

Which of the following is chemisorption

Answer»

ADSORPTION of `H_2` on NI at high temperature
adsorption of `H_2` on charcoal 
adsorption of MOISTURE on SILICA gel 
DEHYDRATION by using anhydrous `CaCl_2`

Answer :A
8792.

When an atom X absorbs radiation with a photon energy than the ionization energy of the atom, the atom is ionized to generate an ion X^(+) and the electron (called a photoelectron) is ejected at the same time. In this event, the energy is conserved as shown in Figure 1, that is, Photon energy (h)=ionization energy (IE) of X+ kinetic energy of photoelectron. When a molecule, for example, H_(2), absorbs short-wavelength light, the photoelectron is ejected and an H_(2), ion with a variety of vibrational states is produced. A photoelectron spectrum is a plot of the number of photoelectrons as a function of the kinetic energy of the photoelectrons. Figure-2 shows a typical photoelectron spectrum when H_(2) in the lowest vibrational level is irradiated by monochromatic light of 21.2 eV. No photoelectrons are detected above 6.0 eV. (eV is a unit of energy and 1.0 eV is equal to 1.6xx10^(-19) J) Figure 1 Schematic diagram of photoelectron spectroscopy. Figure 2 Photoelectron spectrum of H_(2). The energy of the incident light is 21.2 eV {:a) ul("Determine") the energy difference E_(A1) (eV) between H_(2)(v=0) and H^(+)(V_(ion)=0) to the first decimal place. v and v_(ion) denote the vibrational quantum numbers of H_(2) and H^(+), respectively. {:b) ul("Determine") the energy difference E_(A2) (eV) between H^(+) (v_(ion)=0) and H^(+)(v_(ion)=3) to the first decimal place. The electronic energy levels E_(n)^(H) of a hydrogen atom are given by the equation E_(n)^(H)=-(Ry)/n^(2) "" (n=1, 2, 3 ....) Here n is a principal quantum number, and Ry is a constant with dimensions of energy. The energy from n=1 to n=2 of the hydrogen atom is 10.2 eV.

Answer»


Answer :(a) The spectral peak at `5.8 eV` in Fig `2` corresponds to the ELECTRON with the highest kinetic ENERGY, which is generated by the REACTION
`H_(2)(V=0) rarr H_(2)^(+)(V_(ion)=0)+e`
Accordingly,
`DeltaE_(A1)=21.2 eV-5.8 eV=15.4 eV`
(b) One can estimate from Fig. `2` that the energy DIFFERENCE `DeltaE_(A2)` between `H_(2)^(+)(V_(ion)=0)` and `H_(2)^(+)(V_(ion)=3)` is approximately `0.8 eV`.
The answer are as follows: `DeltaE_(A1)=15.4 eV`
`DeltaE_(A2)=0.8 eV`
8793.

Write the Haworth's structure of -D(+) Glucose.

Answer»

SOLUTION :
8794.

When an atom X absorbs radiation with a photon energy than the ionization energy of the atom, the atom is ionized to generate an ion X^(+) and the electron (called a photoelectron) is ejected at the same time. In this event, the energy is conserved as shown in Figure 1, that is, Photon energy (h)=ionization energy (IE) of X+ kinetic energy of photoelectron. When a molecule, for example, H_(2), absorbs short-wavelength light, the photoelectron is ejected and an H_(2), ion with a variety of vibrational states is produced. A photoelectron spectrum is a plot of the number of photoelectrons as a function of the kinetic energy of the photoelectrons. Figure-2 shows a typical photoelectron spectrum when H_(2) in the lowest vibrational level is irradiated by monochromatic light of 21.2 eV. No photoelectrons are detected above 6.0 eV. (eV is a unit of energy and 1.0 eV is equal to 1.6xx10^(-19) J) Figure 1 Schematic diagram of photoelectron spectroscopy. Figure 2 Photoelectron spectrum of H_(2). The energy of the incident light is 21.2 eV ul("Calculate") the ionization energy E_(B)( eV) of the hydrogen atom to the first decimal place. The energy threshold for the generation of two electronically excited hydrogen atoms H^(**) (n=2) from H_(2)(v=0) has been derived to be 24.9 eV by an experiment.

Answer»


Answer :The ionization energy corresponds to `n=oo`. Accordingly,
`DeltaE_(n=2larr n=1)=`^(3)//_(4) RY``
`DeltaE_(n=2 larr n=1)=Ry`
Thus, the energy required for the ionization is `4/3` TIMES larger than the TRANSITION energy of the Lyman `alpha`-LINE.
`E_(B)=10.2 eVxx4/3=13.6 eV`
8795.

Which of the followingreagentswill be able to disguish between allyl bromide and n- propylbromide?

Answer»

Aqueous `AgNO_(3)`<BR>`NaOH, AgNO_(3)`
`Alk. KMnO_(4)`
Tollens reagent

Solution :
a. `Aq. AgNO_(3)` wil give test for `Br^(o-)` by both.
b. `G.R` wil react with both.
d. Tollens reagent will not react with both.
8796.

Which of these is true regarding the 3d orbital ?

Answer»

It possesses TWO radial nodes
It possesses two conical nodes
It possesses ZERO angular nodes
All of the aboveare correct STATEMENTS

ANSWER :B
8797.

When phenol is heated with zinc dust, the product is

Answer»


ANSWER :BENZENE
8798.

When excess of FeSO_(4) is added to sodium extract the compound formed "is" // "are"

Answer»

`Na_(2)[Fe(CN)_(6)]`
`Fe(OH)_(2)`
`Na_(2)SO_(4)`
`Na_(2)[Fe(SCN)]`

SOLUTION :`6NaCN + FeSO_(4) to Na_(4)[Fe(CN)_(6)] + Na_(2)SO_(4)`
`Na_(2)S + FeSO_(4) to Fes + Na_(2)SO_(4)`.
8799.

Which alkene on ozonolysis givenCH_3CH_2CHO and CH_3 COCH_3?

Answer»

`CH_3CH_2CH = C(CH_3)_2`
`CH_3CH_2CH = CHCH_2CH_3`
`CH_3CH_2CH = CHCH_3 `
`(CH_3)_2C=CHCH_3 `

ANSWER :A
8800.

Which of the following colligative property can provide molar mass of proteins (or polymers or colloids) with greatest precision?

Answer»

RELATIVE lowering in vapour pressure
Elevation of boiling point
Depression in FREEZING point
OSMOTIC pressue

Solution :is the correct answer.