InterviewSolution
This section includes InterviewSolutions, each offering curated multiple-choice questions to sharpen your knowledge and support exam preparation. Choose a topic below to get started.
| 8752. |
Which one of the halogens is radioactive ? |
| Answer» SOLUTION :ASTATINE (At) is RADIOACTIVE HALOGEN. | |
| 8753. |
Which of the following has maximum number of unpaired electrons |
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Answer» `Mg^(2+)` |
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| 8755. |
Which of the following are not used as food preservatives ? |
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Answer» Table salt |
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| 8756. |
Which of the following sets contain only copolymers? |
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Answer» SBR, Glyptal, Nylon 6,6 |
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| 8757. |
What are (X) and (Y) in the following reaction? Give the mechanism of formation of (X) and (Y). |
Answer» SOLUTION :
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| 8758. |
The total number of fundamental particles in one atom ofoverset 14(6C) is: |
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Answer» 6 |
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| 8759. |
Zn(s)+Cl_(2)(1atm)toZn^(2+)+2Cl^(-). E_(cell)^(o) of the cell is 2.12 V. To increase E |
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Answer» `[Zn^(2+)]` should be INCREASED `E_(CELL)=E_(cell)^(o)(-0.059)/(2)"LOG"(["Anode"])/(["Cathode"])` At anode`toZntoZ_(n)^(2+)+2e^(-)` At cathode`toCl_(2)+2e^(-)to2Cl^(-)` So, `E_(cell)=2.12(-0.059)/(2)"log"([Zn]^(++))/([Cl^(-)]^(2))` E will be increase when CONCENTRATIONS of both `[Zn]^(++)` and `Cl^(-)` is decreased. |
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| 8760. |
Which of the following reactions depict the nucleophilic substsitution of C_(2)H_(5)Br ? |
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Answer» `C_(2)H_(5)Br+C_(2)H_(5)SN a to C_(2)H_(5)SC_(2)H_(5)+NABR` |
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| 8761. |
Which of the following pairs represents linkage isomers? |
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Answer» <P>`[Cu(NH_(3))_(4)][PtCl_(4)] and [Pt(NH_(3))_(4)][CuCl_(4)]` <BR>`Pd(P Ph_(3))_(2)(NCS)_(2)] and [Pd(P Ph_(3))_(2)(SCN)_(2)]` |
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| 8762. |
Which of the following will give a primary amine on hydrolysis |
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Answer» ALKYL isocyanide |
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| 8763. |
Which one is the strongest bond? |
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Answer» H - CI |
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| 8764. |
Which of the following act as an antiseptic and disinfectant respectiely? |
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Answer» 0.2% PHENOL, 1% phenol |
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| 8765. |
Which of the following has the largest size |
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Answer» `S^(2-)` |
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| 8766. |
Which of the following is a secondary pollutant |
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Answer» `NO_2` |
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| 8767. |
Which one of the vitamin is syntbesised in. our body by using sun rays ? |
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Answer» A |
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| 8768. |
Which of the following is an addictive drug ? |
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Answer» Papaverine |
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| 8769. |
What are Wade's Rule? |
| Answer» Solution :Wade.s rules are USED to rationalize the SHAPE of borane dclusters by calculating the TOTAL number of SKELETAL eletron PAIRS (SEP) available for cluster bonding. | |
| 8770. |
When excess amount of NH_(3) is reagent with Cl_(2)gives :- |
| Answer» Answer :D | |
| 8773. |
Whichis to be used to prevent chemical reaction in food ? |
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Answer» LOW temperature |
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| 8774. |
Which of the following compounds is not chiral |
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Answer» `DCH_(2)CH_(2)CH_(2)Cl` `{:(""H),("|"),(CH_(3)-CH_(2)-C^(**)-D,),("|"),(""Cl):}``{:(""H),("|"),(CH_(3)-C^(**)-CH_(2)-CH_(2)-Cl),("|"),(""D):}` `{:(""H),("|"),(CH_(3)-C^(**)-CH_(2)D),("|"),(""Cl):}` |
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| 8775. |
What are P and Q? Name the reaction occuring in step 1. (i) C_(6)H_(5)-overset(O)overset(||)C- NH_(2)overset(Br_(2)//NaOH)toP (ii) Poverset(NaNO_(2)//HCl,0^(@)C)toQ |
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Answer» SOLUTION :`P=CH_(3)NH_(2)` (Methanamine) `Q=CH_(3)OH` (METHYL ALCOHOL) STEP- 1 reaction is Hoffmann bromomide degradation reaction. |
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| 8776. |
Ultra microscope works on the principle of |
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Answer» LIGHT reflection |
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| 8777. |
Which elements in first transition series has maximum third ionization enthalpy? |
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Answer» ZN |
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| 8778. |
Write the empirical formulae of the following : (i) N_(2)O_(4) (ii)C_(6)H_(6)(iii)C_(6)H_(12)O_(6)(iv)H_(2)O_(2)(v)H_(2)O (vi) Na_(2)CO_(3) (vii)CH_(3)COOH |
| Answer» Solution :`(i)NO_(2) (II)CH (iii)CH_(2)O (iv)HO (v) H_(2)O (vi)Na_(2)CO_(3)` | |
| 8779. |
Which of the following reactions are disproportionation reactions? (a) Cu^(+) rarr Cu^(2+) + Cu (b) MnO_(4)^(2-) + 4H^(+) rarr 2MnO_(4)^(-) + MnO_(2) + 2H_(2)O (c ) 2KMnO_(4) rarr K_(2)MnO_(4) + MnO_(2) + O_(2) (d) 2MnO_(4)^(-) + 3Mn^(2+) + 2H_(2)O rarr 5MnO_(2) + 4H^(+) |
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Answer» a,b `{:(MnO_(4)^(2-),+,4H^(+),rarr,2MnO_(4)^(-),+,MnO_(2),+,2H_(2)O),((+6),,,,(+7),,(+4),,):}` |
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| 8780. |
Whichof thefollowingstands TURE formolecularityof a reaction? |
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Answer» It ISTHE SUMOF exponentsof themolarconcentrationof thereactantsin therateequation |
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| 8781. |
When an atom X absorbs radiation with a photon energy than the ionization energy of the atom, the atom is ionized to generate an ion X^(+) and the electron (called a photoelectron) is ejected at the same time. In this event, the energy is conserved as shown in Figure 1, that is, Photon energy (h)=ionization energy (IE) of X+ kinetic energy of photoelectron. When a molecule, for example, H_(2), absorbs short-wavelength light, the photoelectron is ejected and an H_(2), ion with a variety of vibrational states is produced. A photoelectron spectrum is a plot of the number of photoelectrons as a function of the kinetic energy of the photoelectrons. Figure-2 shows a typical photoelectron spectrum when H_(2) in the lowest vibrational level is irradiated by monochromatic light of 21.2 eV. No photoelectrons are detected above 6.0 eV. (eV is a unit of energy and 1.0 eV is equal to 1.6xx10^(-19) J) Figure 1 Schematic diagram of photoelectron spectroscopy. Figure 2 Photoelectron spectrum of H_(2). The energy of the incident light is 21.2 eV ul("Calculate") the speed u (m s^(-1)) of the hydrogen atoms generated in the above reaction. H_(2) is assumed to be at rest. If you were unable to determine the value for E_(C), then use 5.0 eV for E_(C) |
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Answer» `1/2 m u^(2)=8.35 eV=1.34xx10^(-18) J` |
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| 8782. |
What is true for acetophenone ? |
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Answer» It REACTS with alkaline `KMnO_(4)` FOLLOWED by acidic hydrolysis and forms benzoic acid |
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| 8783. |
Which of the following volume (V) - temperature (T) plots represents the behaviour of one mole of an ideal gas at one atmospheric pressure? |
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Answer»
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| 8784. |
Which statement is incorrect about D? |
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Answer» D can produce yellow ppt. on reaction with `OVERSET(Theta)" OH"//I_(2)` |
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| 8785. |
When an atom X absorbs radiation with a photon energy than the ionization energy of the atom, the atom is ionized to generate an ion X^(+) and the electron (called a photoelectron) is ejected at the same time. In this event, the energy is conserved as shown in Figure 1, that is, Photon energy (h)=ionization energy (IE) of X+ kinetic energy of photoelectron. When a molecule, for example, H_(2), absorbs short-wavelength light, the photoelectron is ejected and an H_(2), ion with a variety of vibrational states is produced. A photoelectron spectrum is a plot of the number of photoelectrons as a function of the kinetic energy of the photoelectrons. Figure-2 shows a typical photoelectron spectrum when H_(2) in the lowest vibrational level is irradiated by monochromatic light of 21.2 eV. No photoelectrons are detected above 6.0 eV. (eV is a unit of energy and 1.0 eV is equal to 1.6xx10^(-19) J) Figure 1 Schematic diagram of photoelectron spectroscopy. Figure 2 Photoelectron spectrum of H_(2). The energy of the incident light is 21.2 eV Considering an energy cycle, ul("determine") the bond energy E_(D)( eV) of H_(2)^(+) to the first decimal place. If you were unable to determine the values for E_(B) and E_(C), then use 15.0 eV and 5.0 eV for E_(B) and E_(C), respectively. |
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Answer» `E_(D)=E_(B)+E_(C)-DeltaE_(A1)=13.6+4.5-15.4=2.7 EV` |
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| 8786. |
Which alkyl halide from the following pairs would you expect to react more rapidly by an S_N2 mechanism ? Explain your answer. (i) underset((A))(CH_3CH_2Br) " or " underset((B))underset(Br)underset(|)(CH_3CH_2CHCH_3) (ii) underset((C))underset(Br)underset(|)(CH_3CH_2CHCH_3) "or" underset((D))underset(CH_3)underset(|)(H_3C-C-Br) (iii) underset((E))underset(CH_(3))underset(|)(CH_3CHCH_2CH_2Br) "or" underset((F))underset(CH_3)underset(|)(CH_3CH_2CHCH_2Br) |
| Answer» SOLUTION :(i) A, (II) C and (III) E | |
| 8787. |
When an atom X absorbs radiation with a photon energy than the ionization energy of the atom, the atom is ionized to generate an ion X^(+) and the electron (called a photoelectron) is ejected at the same time. In this event, the energy is conserved as shown in Figure 1, that is, Photon energy (h)=ionization energy (IE) of X+ kinetic energy of photoelectron. When a molecule, for example, H_(2), absorbs short-wavelength light, the photoelectron is ejected and an H_(2), ion with a variety of vibrational states is produced. A photoelectron spectrum is a plot of the number of photoelectrons as a function of the kinetic energy of the photoelectrons. Figure-2 shows a typical photoelectron spectrum when H_(2) in the lowest vibrational level is irradiated by monochromatic light of 21.2 eV. No photoelectrons are detected above 6.0 eV. (eV is a unit of energy and 1.0 eV is equal to 1.6xx10^(-19) J) Figure 1 Schematic diagram of photoelectron spectroscopy. Figure 2 Photoelectron spectrum of H_(2). The energy of the incident light is 21.2 eV ul("Calculate") the threshold energy E_(E) (eV) of the following dissociative reaction to the first decimal place: H_(2) rarr H^(**) (n=2) +H^(+)+e^(-) If you were unable to determine the values for E_(B) and E_(C), then use 15.0 eV and 5.0 eV for E_(B) and E_(C) respectively. When H_(2) absorbs monochromatic light of 21.2 eV, the following dissociation process occurs at the same time. H_(2) overset(21.2 eV)(rarr)H(n=1)+H(n=1) Two hydrogen atoms move in opposite direction with the same speed. |
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Answer» From figure `3` above, the threshold energy `E_(E)` for the dissociative IONIZATION reaction `H_(2) RARR H^(**)(n=2)+H^(+)+e^(-)` is `E_(B)+E_(C)+10.2 EV=13.6+4.5+10.2=28.3 eV. E_(E)=28.3 eV` |
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| 8788. |
Which is the possible number of stereo isomers for the following formula ? CH_(2)OH(CHOH)_(3)CHO |
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Answer» 4 |
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| 8789. |
When an atom X absorbs radiation with a photon energy than the ionization energy of the atom, the atom is ionized to generate an ion X^(+) and the electron (called a photoelectron) is ejected at the same time. In this event, the energy is conserved as shown in Figure 1, that is, Photon energy (h)=ionization energy (IE) of X+ kinetic energy of photoelectron. When a molecule, for example, H_(2), absorbs short-wavelength light, the photoelectron is ejected and an H_(2), ion with a variety of vibrational states is produced. A photoelectron spectrum is a plot of the number of photoelectrons as a function of the kinetic energy of the photoelectrons. Figure-2 shows a typical photoelectron spectrum when H_(2) in the lowest vibrational level is irradiated by monochromatic light of 21.2 eV. No photoelectrons are detected above 6.0 eV. (eV is a unit of energy and 1.0 eV is equal to 1.6xx10^(-19) J) Figure 1 Schematic diagram of photoelectron spectroscopy. Figure 2 Photoelectron spectrum of H_(2). The energy of the incident light is 21.2 eV ul("Determine") the bond energy E_(C)(eV) of H_(2) to the first decimal place. |
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Answer» Thus, the binding energy of a hydrogen molecule `E_(C)=4.5 eV` |
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| 8790. |
Which is the correct formula of freon 12? |
| Answer» Answer :A | |
| 8791. |
Which of the following is chemisorption |
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Answer» ADSORPTION of `H_2` on NI at high temperature |
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| 8792. |
When an atom X absorbs radiation with a photon energy than the ionization energy of the atom, the atom is ionized to generate an ion X^(+) and the electron (called a photoelectron) is ejected at the same time. In this event, the energy is conserved as shown in Figure 1, that is, Photon energy (h)=ionization energy (IE) of X+ kinetic energy of photoelectron. When a molecule, for example, H_(2), absorbs short-wavelength light, the photoelectron is ejected and an H_(2), ion with a variety of vibrational states is produced. A photoelectron spectrum is a plot of the number of photoelectrons as a function of the kinetic energy of the photoelectrons. Figure-2 shows a typical photoelectron spectrum when H_(2) in the lowest vibrational level is irradiated by monochromatic light of 21.2 eV. No photoelectrons are detected above 6.0 eV. (eV is a unit of energy and 1.0 eV is equal to 1.6xx10^(-19) J) Figure 1 Schematic diagram of photoelectron spectroscopy. Figure 2 Photoelectron spectrum of H_(2). The energy of the incident light is 21.2 eV {:a) ul("Determine") the energy difference E_(A1) (eV) between H_(2)(v=0) and H^(+)(V_(ion)=0) to the first decimal place. v and v_(ion) denote the vibrational quantum numbers of H_(2) and H^(+), respectively. {:b) ul("Determine") the energy difference E_(A2) (eV) between H^(+) (v_(ion)=0) and H^(+)(v_(ion)=3) to the first decimal place. The electronic energy levels E_(n)^(H) of a hydrogen atom are given by the equation E_(n)^(H)=-(Ry)/n^(2) "" (n=1, 2, 3 ....) Here n is a principal quantum number, and Ry is a constant with dimensions of energy. The energy from n=1 to n=2 of the hydrogen atom is 10.2 eV. |
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Answer» `H_(2)(V=0) rarr H_(2)^(+)(V_(ion)=0)+e` Accordingly, `DeltaE_(A1)=21.2 eV-5.8 eV=15.4 eV` (b) One can estimate from Fig. `2` that the energy DIFFERENCE `DeltaE_(A2)` between `H_(2)^(+)(V_(ion)=0)` and `H_(2)^(+)(V_(ion)=3)` is approximately `0.8 eV`. The answer are as follows: `DeltaE_(A1)=15.4 eV` `DeltaE_(A2)=0.8 eV` |
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| 8793. |
Write the Haworth's structure of -D(+) Glucose. |
Answer» SOLUTION :
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| 8794. |
When an atom X absorbs radiation with a photon energy than the ionization energy of the atom, the atom is ionized to generate an ion X^(+) and the electron (called a photoelectron) is ejected at the same time. In this event, the energy is conserved as shown in Figure 1, that is, Photon energy (h)=ionization energy (IE) of X+ kinetic energy of photoelectron. When a molecule, for example, H_(2), absorbs short-wavelength light, the photoelectron is ejected and an H_(2), ion with a variety of vibrational states is produced. A photoelectron spectrum is a plot of the number of photoelectrons as a function of the kinetic energy of the photoelectrons. Figure-2 shows a typical photoelectron spectrum when H_(2) in the lowest vibrational level is irradiated by monochromatic light of 21.2 eV. No photoelectrons are detected above 6.0 eV. (eV is a unit of energy and 1.0 eV is equal to 1.6xx10^(-19) J) Figure 1 Schematic diagram of photoelectron spectroscopy. Figure 2 Photoelectron spectrum of H_(2). The energy of the incident light is 21.2 eV ul("Calculate") the ionization energy E_(B)( eV) of the hydrogen atom to the first decimal place. The energy threshold for the generation of two electronically excited hydrogen atoms H^(**) (n=2) from H_(2)(v=0) has been derived to be 24.9 eV by an experiment. |
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Answer» `DeltaE_(n=2larr n=1)=`^(3)//_(4) RY`` `DeltaE_(n=2 larr n=1)=Ry` Thus, the energy required for the ionization is `4/3` TIMES larger than the TRANSITION energy of the Lyman `alpha`-LINE. `E_(B)=10.2 eVxx4/3=13.6 eV` |
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| 8795. |
Which of the followingreagentswill be able to disguish between allyl bromide and n- propylbromide? |
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Answer» Aqueous `AgNO_(3)`<BR>`NaOH, AgNO_(3)` a. `Aq. AgNO_(3)` wil give test for `Br^(o-)` by both. b. `G.R` wil react with both. d. Tollens reagent will not react with both. |
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| 8796. |
Which of these is true regarding the 3d orbital ? |
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Answer» It possesses TWO radial nodes |
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| 8798. |
When excess of FeSO_(4) is added to sodium extract the compound formed "is" // "are" |
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Answer» `Na_(2)[Fe(CN)_(6)]` `Na_(2)S + FeSO_(4) to Fes + Na_(2)SO_(4)`. |
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| 8799. |
Which alkene on ozonolysis givenCH_3CH_2CHO and CH_3 COCH_3? |
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Answer» `CH_3CH_2CH = C(CH_3)_2` |
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| 8800. |
Which of the following colligative property can provide molar mass of proteins (or polymers or colloids) with greatest precision? |
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Answer» RELATIVE lowering in vapour pressure |
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