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951.

Thiokol is used as

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rubber
for makinghuman hair WIGS
HELMETS
bullet proof WINDOWS

Answer :A
952.

Which metal has a greater tendency to form metal oxide ?

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AL
Ca
Cr
Fe

Solution :The formation and STABILITY of metal OXIDES can be explained on the basis of lattice ENERGY effects . `Al^(3+)` ion being a small ion has strong positive field around it and can stabilise `O^(2)` BETTER.
953.

The reagent (X) in the given reaction is phenol underset(273K)overset("''X''")(rarr) Parabromophenol

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`Br_(2)//CH_(3)COOH`
`Br_(2)//FeBr_(3)`
Bromine water
`Br_(2)//CS_(2)`

Answer :D
954.

Three arrangements are shown for the complex [Co(e n) (NH_(3))_(2)Cl_(2)]^(+)pick up the correct statement:-

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II and III are optical isomers
I & III are optical isomers
I & II ONE geometrical isomers
II & III are geometrical isomers

Solution :(i) I & II are G.I. (ii) II & III are optical isomer
955.

Which one of the following is / true :- (i) At critical temp the surface separating two phases disappears (ii) below critical temperature a gas is called vapour (iii) A gas can't be liquified below critical temp. (iv) Higher the critical temp. difficult to liquify a gas

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(i),(II),(IV)
(i),(ii),(iv)
(III),(iv)
(i),(ii)

ANSWER :D
956.

The solubility of AgCl will be minimum in……….

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`0.001 M AgNO_3`
PURE water
`0.01 M CaCl_2`
`0.01 M NACL`

Solution :`0.01M CaCl_2` gives maximum `Cl^-` ions to keep `K_(sp)` of AGCL constant, decreases in `[Ag^+]` will be maximum.
957.

The stability of coordination compounds is related to ______ , ______ and exotropy terms.

Answer»


ANSWER :GIBB's ENERGY, ENTHALPY
958.

Which of the following dimensions of a unit cell represent a cubic unit

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`a=b=c,alpha=BETA=GAMMA=90^(@)`
`a=b=c,alpha=beta=90^(@)NE gamma`
`a=bnec, alpha=gamma=90^(@)`
`anebnec,alphane beta ne gamma`

ANSWER :A
959.

Which is not poisonous ?

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`NH_3`
`PH_3`
`AsH_3`
`SbH_3`

ANSWER :A
960.

Which one of the following platinum complexes is used in cancer chemotherapy?

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CIS[`PtCl_(2)(NH_(3))_(2)]`
trans-`[PtCl_(2)(NH_(3))]`
`{t(NH_(3))_(4)]^(2+)`
`[Pt(Cl_(4))]^(2-)`

ANSWER :A
961.

Which of the following compounds has highest boiling point ?

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Propan-1-ol
n-Butane
Chloroethane
Propanal

ANSWER :A
962.

Which statement is false.

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`NH_3` is a LEWIS base
`NH_3` molecule is triangular planar
`NH_3` does not ACT as reducing AGENT
`NH_3` (liquid) is used as a solvent

Answer :B
963.

What is HDPE? Give its preparation and use.

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Solution : (i) HDPE is high density polyethylene. It is prepared by the POLYMERISATION of ethylene at 373k and 6 to 7 ATM. USING zeiglar Natta Catalyst)
`underset([TiCl_4 + (C_2H_5)_3 AL])(nCH_2=CH_2 underset(6-7 "atm. Pr.")overset(373K)to (--CH_2 -CH_2--)_n)`
(iii) It is used to make bottles, pipes.
964.

Which of the following rubber if not a polydiene

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POLYISOPRENE
POLYCHLOROPRENE
Thiokolrubber
Synthesiezer

ANSWER :C
965.

You are required to match all the metallurgical extractions given in column-I with the processes given in column-II. {:("Column-I","Column-II"),("(Metallurgical extraction)","(Process involved in metallurgical extraction)"),((A)Al_2O_3. 2H_2OtoAl,(p)"Leaching"),((B)KCl.MgCl_2. 6H_2O,(q)"self reduction"),((C )Ag_2S to Ag,(r)"Electrolytic reduction(molten state)"),((D)PbStoPb,(s)"Roasting"),(,(t)"Displacement method"):}

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Solution :(A)`Al_2O_3(s)+3H_2O(l)+2NAOH(aq)to2Na[Al(OH)_4](aq)`
`2Na[Al(OH)_4](aq)+CO_2(g)toAl_2O_3 xH_2O(s)+2NaHCO_3`(aq)
`Al_2O_3 xH_2O(s)overset(1470K)toAl_2O_3(s)+xH_2O(g)`
ELECTROLYTIC reduction of molten pure `Al_2O_3` mixed with `Na_3AIF_6 or CaF_2` Method is known as Hall-Heroult PROCESS
Cathode: `Al^(3+)('melt")+3e^(-)toA(l)`
Anode: `C(s)+O^(2-)("melt")toCO(g) +2e^(-)`
`C(s)+2O^(2-)("melt")toCO_2(g) +4e^(-)`
(B)Electroytic reduction of molten anhydrous carnalite.
`MgCl_2 hArr 2Na[Ag(CN)_2]+Na_2S`
`{:("At cathode",Mg^(2+)+2e^(-)toMg(99% pure)),("At anode" , 2Cl^(-)toCl_2+2e^(-)):}`
( C)`Ag_2S+4NaCN hArr 2Na[Ag(CN)_2]+Na_2S`
`Na_2S+2O_2 to Na_2SO_4`
`2Na[Ag(CN)_2]+Zn to Na_2[Zn(CN)_4]+2Ag darr`
(D)`2PbS+3O_2oversetDeltato2PbO +2SO_2`
`2PbO+PbSto 3Pb+SO_2`
966.

Which will not give acetamide on reaction with ammonia

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ACETIC acid
Acetyl chloride
Acetic anhydride
Methyl formate

Answer :D
967.

Which of the following is known as camphor substitute ?

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`C_(2)Cl_(6)`
`CHCl_(3)`
`CF_(3).CHClBr`
`CF_(2)Cl_(2)`

SOLUTION :`C_(2)Cl_(6)` is known as artificial CAMPHOR.
968.

Which is not an alcohol :

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`CH_2=CHCH_2OH`
`CH_2OHCH_2OH`
`C_6H_5CH_2OH`
`C_6H_5OH`

ANSWER :D
969.

Write the formulas of the following coordination compounds : (i) Tetraamminediaquacobalt (III) chloride (ii) Potassium tetracyanonickelete (II) (iii) Tris(ethane-1, 2-diamine) platinum (II) nitrate (iv) Amminebromidochloridonitrito-N-platinate (II) (v) Dichloridobis (ethane-1, 2-diamine) platinum (IV) nitrate (vi) Iron (III) hexacyanoferrate (II)

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Solution :(i) `[Co(NH_(3))_(4)(H_(2)O)_(2)]Cl_(3)`(ii) `K_(2)[Ni(CN)_(4)]` (III) `[Cr(en)_(3)]Cl_(3)`
(iv) `[Pt(NH_(3))BrCl(NO_(2))]^(-)` (v) `[PtCl_(2)(en)_(2)](NO_(3))_(2)`(vi) `Fe_(4)[FE(CN)_(6)]^(3)`
970.

Which of the following reagents or process are suitable to distinguish MeOH and EtOH ?

Answer»

NaCl

anhydrous `ZnCl_(2)`+conc. HCL
Victor Meyer's process

Solution :EtOH gives+ve test with salicylic ACID and form WINTER oil FREEN.
971.

Which ion has 5.93 BM magnetic moment?

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`MN^(2+)`
`Fe^(2+)`
`Cr^(2+)`
`V^(3+)`

Solution :For `Mn^(2+)` will be `3D^(5)`
`:. mu= sqrt(5(5+2)) = sqrt35= 5.92BM`
972.

Transition metals are widely used as catalysts in industrial processes. Why do the transition elements exhibit greater similarity in properties compared to main group elements along the period as well as down the group?

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Solution :In transition METALS, the last electron is added to INNER b-orbital. Since the outer electronic configuration remain the same for a series, they SHOW greater similarity in properties along a period. In a group, these ELEMENTS do not differ much in SIZE. So they show greater similarity in properties in a group.
973.

Which type of particles satisfy primary valency?

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SOLUTION :NEGATIVELY CHARGED PARTICLES.
974.

Which of the following respond to chromyl chloride test

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`SnCl_(2)`
`NACL`
`PbCl_(2)`
`AGCL`

Solution :Chronyl chloride TEST for only free chloride ions `(Cl^(-))`
975.

The value of Henry's constantkmu is"__________."

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greater for GASES with HIGHER solubility.
greater for gases with lower solubility.
constant for all gases.
not related to the solubility of gases.

Answer :B
976.

Which reactants are involved in Mendius reaction?

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RCN and `LiAIH_4`
RCN and `H_2O //HCI`
RCN and `Zn//NH_4Cl`
RCN and `SnCI_4//HCI`

ANSWER :1
977.

Whichone is the natural polyamide polymer ?

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CUPRAMMONIUM SILK
Wool
Perlon-L
Jute

Answer :B
978.

The value ofLambda_(m)^(@)" for "NH_(4) Cl, NaOH and NaCl" are 129.8, 248.1 and 126.4 Ohm"^(-1)" cm"^(2)" mol"^(-1) respectively. Calculate Lambda_(m)^(@) for NH_(4)OH solution.

Answer»

215.5
251.5
244.7
351.5

Answer :B
979.

Which of the following is correct regarding the reaction of fluorine with water ? 2F_(2)(g) + 2H_(2)O(l) to 4H^(+) (aq) + 4F^(-) (aq) + O_(2)(g)

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Fluorine is oxidized to `F^(-)`
WATER is oxidized to `O_(2)`
Water is REDUCED to `H^(+)`
Oxidation state of fluorine does not change

Solution :In the given reaction `F_(2)` is an oxidising agent which oxides `H_(2)O` to `O_(2)`. Oxidation state of fluorine changes 0 to `-1`.
980.

Which of the following detergent belong to ABS-group-

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SODIUM Lauryl sulphate
Sodium dodecyl benzene sulphonate
Cetytrimethyl ammonium BROMIDE
Pentaerythrityl stearate

ANSWER :B
981.

Which of the following imparts green colour to the glass

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`Cu_(2)O`
`CDS`
`MnO_(2)`
`Cr_(2)O_(3)`

Answer :D
982.

When calomel electrode acts as an anode then the reaction is

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`2 HG + 2 Cl^(-) to Hg_(2) Cl_(2) + 2e^(-)`
`Hg_(2) Cl_(2) to 2 Hg^(+) + Cl_(2) + 2e^(-)`
`Hg_(2) Cl_(2) + 2e ^(-) to 2 Hg + Cl_(2)`
`Hg_(2)Cl_(2) + 2e^(-) to 2 Hg + 2 Cl^(-)`

Solution :The cell REACTIONS are at ANODE (oxidation)
`2 Hg + 2 Cl^(-) to Hg_(2) Cl_(2) + 2 e^(-)`
983.

Which is used as a drug to reduce fever?

Answer»

Diethyl ETHER
ACETONE
Acetophenone
PARACETAMOL

SOLUTION :Paracetamol
984.

Which one of the following is square planar in structure and has diamagnetic property ?

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`[NI(H_2O)_6]^(2+)`
`[Ni(CO)_4]`
`[Ni(CN)_4]^(2-)`
`[NiCl_4]^(2-)`

Answer :D
985.

What is a condensation polymer ? Give one example.

Answer»

Solution :Condensation polymers are FORMED by repeated condensation reaction between two bifunctional or trifunctional monomer units usually with the elimination of small molecules like water, ALCOHOL, AMMONIA , carbon dioxide , hydrogen chloride , ETC. For example, nylon 6,6polyester , bakelite, etc.
986.

What is photochemical smog? What are its consequences?

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ANSWER :49 MG
987.

Which metal is present in vitamin B_(12) ?

Answer»

Iron
Cobalt
Manganese
Copper

Answer :A::B::C
988.

What is the order of basic nature of hydrides of VA group elements?

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`AsH_(3) GT SbH_(3) gt PH_(3) gt NH_(3)`
`NH_(3) gt SbH_(3) gt PH_(3) gt AsH_(3)`
`NH_(3) gt PH_(3) gt AsH_(3) gt SbH_(3)`
`PH_(3) gt NH_(3) gt SbH_(3) gt AsH_(3)`

ANSWER :3
989.

Which of the followingare sulpha drugs ?

Answer»

Sulphapyridine
PRONTOSIL
Salvarsan
Nardil

Solution :Sulpha drugs kills bacteria and fungi by interfering with their metabolism.
(a) Sulphapyridine is a sulphonamide antibacterial drug. It is no longer precribed for the treatmentof infections in humans. It isgood antibacterial drug., but its WATER solubility is very pH DEPENDENT. Thus, there is a risk of crystallisation within the baldder or urethra, which could lead to pain or blockage.
(b) Prontosil is also called sulphamidochrysoidine. It is USED inthe treatment of general bacterial infection in humans.
Salversan is arsenic BASED antibacterial drug. It is used inthe treatment of syphills.
(d) Nardil is an antidepressant drug.
990.

which of the following orbitals has three angular nodes?

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2s
4s
3d
6f

Answer :D
991.

Which of the following oil can be used for the preparation of soap by alkaline hydrolysis

Answer»

PARAFFIN OIL
COCONUT oil
Kerosine oil
Turpentine oil

Answer :B
992.

Which of the following compound is optically active

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`C_(2)H_(5)-OH`
`(CH_(3))_(2)CHCH_(3)-Cl`
`CH_(3)-CHClC_(2)H_(5)`
`C Cl_(2)F_(2)`

Answer :C
993.

When of the following can reduce Fehling's solution?

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FORMIC acid
Formaldehyde and acetaldehyde
ACETIC acid
acetaldehyde

SOLUTION :Only acetic acid does not REDUCE FEHLING's solution.
994.

When one mole of an alkene on ozonolysis produces 2 moles of propanone, the alkene is

Answer»

3-methyl-1-butene
2, 3-dimethyl-2-butene
2, 3-dimethyl-2-pentene
2, 3-dimethyl-2-pentene

ANSWER :D
995.

Which of the following would undergo aldol condensation?

Answer»

`"CCL"_3CHO`
`CH_3 - undersetoverset(|)(CH_3)oversetunderset(|)(CH_3)(C ) - CHO`
`HCHO `
`CH_3CHO`

SOLUTION :`CH_3CHO`
996.

Which of the following units is useful in relating concentration of solution with its vapour pressure ?

Answer»

Mole fraction
Parts per million
Mass percentage
Molality

SOLUTION :Explanation : It is mole fraction (x) which is useful in RELATING concentration of solution with its vapour presure. For EXAMPLE according to Rault.s law in a binary solution of two volatile liquids, `p_(1)=x_(1)p_(1)^(0)` where `p_(1)` is vapour pressure of component I, and `x_(1)` is its mole fraction in solution, `p_(1)^(0)` DENOTES the vapour pressure of pure solvent.
997.

Which among the following is not an antibiotic

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Ofloxacin
Oxytocin
Penicillin
Tetracycline

Solution :Oxytocin is a HORMONE, which is released from posterior pituitary gland. It controls the contraction of uterus after child BIRTH and releases MILK from themammary glands.
998.

Which of following oxide is not acidic ?

Answer»

<P>`N_(2)O_(3)`
`P_(4)O_(10)`
`N_(2)O_(5)`
`Bi_(2)O_(5)`

Answer :D
999.

Write the structures of the isomers of alcohols with molecular formula C_(4)H_(10)O. Which of these will exhibit optical activity ?

Answer»

Solution :`to` The structures of the ISOMERS of alcohols with molecular formula `C_(4)H_(10)O` are :
(a) `underset("Butan-1-ol"(1^(@)))(CH_(3)CH_(2)CH_(2)CH_(2)OH)`
(B) `underset("2-Methylpropan-1-ol" (1^(@)))( CH_(3)- underset(CH_(3))underset(|)CH- CH_(2)OH)`
(c) `underset("2-methylpropan-2-ol"(3^(@)))(CH_(3)- underset(OH)underset(|)overset(CH_(3))overset(|)C- CH_(3))`
Butan-2-ol is optically active.
1000.

Write name and structure of monomers of following polymer : Dacron

Answer»

SOLUTION :ETHYLENE GLYCOL + Terephthalic ACID