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13251.

Which of the following choices match(es) with hydrogen gas at P = 200 and T = 273K ?

Answer»

`Zne1`
Attractive forces are DOMINANT
PV = nRT
P(V - nb) = nRT

Answer :C
13252.

What is true out of the following ?

Answer»

FLUORINE REDUCES WATER to oxygen
Fluorine neutralises wate
Fluorine oxides water to FORM `O_3` and `O_2`
Fluorine does not react with water

Solution :`2F_2+H_2O to 4HF + O_2 , 3F_2 + H_2O to 6HF + O_3`
13253.

Which of the following reactiongives H_(2) gas ?

Answer»

`NaNH_(2)+H_(2)O rarr`
`ZN+"CONC."H_(2)SO_(4)rarr`
`Zn+" aq" NaOH rarr`
`CaH_(2)+H_(2)O rarr`

Solution :`NaNH_(2)+H_(2)O rarrNaOH+NH_(3)UARR`
`underset(("conc."))(Zn+H_(2)SO_(4))rarrZnSO_(4)+SO_(2)uarr +H_(2)O`
`Zn+aq. NaOH rarr Na_(2)ZnO_(2)+H_(2)uarr`
`CaH_(2)=H_(2)O rarrCa(OH)_(2)+H_(2)uarr`
13254.

Transition elements should be more reactive than hydrogen on the basis of electrode potential. But most of them do not give hydrogen on reaction with dilute acids because

Answer»

an OXIDE layer is formed on their surface. 
METALLIC BONDS are strong in them
their hydration ENERGY is low.
 their ELECTRONEGATIVITY is low.

Answer :A
13255.

Total number of compound which can shows tautomerism are :-

Answer»

1
2
3
4

Answer :D
13256.

Whatis essentially the differencebetweenalpha- fromof glucose? Explain.

Answer»

SOLUTION :Thetwo froms ofglucosediffer in theconfigurationof thehydroxyl group at `C_(1)`, calledtheanomeric CARBON. The TWO forms of GLUCOSEARE given below .
13257.

What is the role of benzoyl peroxide in addition polymerisation of alkenes ? Explain its mode of action with the help of an example.

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SOLUTION :Benzoyl peroxide acts as a RADICAL INITIATOR in the polymerization of ethene
13258.

What volume of O_(2)at NTP liberated by 5 A current flowing for 193 and through acidulated water ?

Answer»

56 mL
112 m L
158 mL
965 m L

Solution :`W = ( I xx t xx E)/(F) = (5 xx 193 xx 8)/(96500)= 0.08 G `
At NTP , volume of 32 g of `O_(2)` = 22400 mL
`therefore 0.08` g = x
` x = (22400 xx 0.08)/(32) = 56 ` mL
13259.

The sodium extract of an organic compound on acidification with acetic acid andaddition of lead acetate solution gives a black precipitate. Theorganic compound contains

Answer»

Nitrogen
Halogen
Sulphur
Phosphorus

Solution :N//A
13260.

Which is not electromagnetic radiation ?

Answer»

INFRARED RAYS
X-rays
Cathode rays
`gamma-rays`

ANSWER :C
13261.

The units of rate constant and rate of reaction are identical for :

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ZERO order REACTION
first order reaction
second order reaction
pseudo -first order reaction

SOLUTION :(A) Rate =` k [A]^(0)`for zero order reaction .
`:.` Units of rate and k are same .
13262.

Which of the following is the weakest nucleophile in aprotic solhent.

Answer»

`F^-`<BR>`CL^-`
`Br^-`
`I^-`

SOLUTION :WEAKEST NUCLEOPHILE is [F]
13263.

Which of the following has longest [CO(CN)_(6)]^(3-) bond length?

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`[Co(CN)_(6)]^(3-)` has FOUR unpaired electrons and will be in a high-spin CONFIGURATION
`[Co(CN)_(6)]^(3-)` has four no unpaired electrons and will be in a high-spin configuration
`[Co(CN)_(6)]^(3-)` has four unpaired electrons and will be in a low-spin configuration
`[Co(CN)_(6)]^(3-)` has four unpaired electrons and will be in a low-spin configuration

Solution :`[Co(CN)_(6)]^(3-)` Oxidation number of Co
13264.

When benzenediazonium chloride is warmed with methanol, the product formed is

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benzene
benzenol
benzyl alcohol
anisole

Solution :SEE A-Level INFORMATION.
13265.

Which of the following organic compounds unable to give precipitation after reaction with silver nitrate (AgNO_3) ?

Answer»


`(CH_3)_(3)C CL`
`CH_3CH = CH- Cl`
`CH_2=CH-CH_2-Cl`

ANSWER :C
13266.

Which of the following can possibly be used as analgesic , without caousing addiction and unconsiousness?

Answer»

MORPHINE
Codeine
ASPIRIN
All of these

Solution :Aspirin is a NON - NARCOTIC ANALGESIC.
13267.

What do you understand by mild tranquilizer? Give examples.

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SOLUTION :MEPROBAMATE and chlorodiazepoxide are MILD tranquilizers. They are suitable for RELIEVING TENSION.
13268.

Which of the following processe (s) during the extraction of copper from chalcopyrites ? (1) Froth floatation (2) Roasting (3) Bassemerisation (4) Leaching

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1, 2
1, 3
`1, 2, 3`
3, 4

Answer :C
13269.

What is the size of colloidal particle ?

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SOLUTION :`10^-9`m or `10^-7`m.
13270.

The relative acidic strengths of benzoic acid, o- toluic acid and p- toluic acid is of the decreasing order :

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p- toluic ACID `gt` o- toluic acid `gt` BENZOIC acid
o- toluic `gt` p- toluic acid `gt` benzoic acid
p- toluic acid `gt` benzoic acid `gt` o- toluic acid
o- toluic acid `gt` benzoic acid `gt` p- toluic acid.

Answer :B
13271.

Which of the following carboxylic acid is more reactive towards Esterification with alcohols?

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`CH_3 COOH`
`(CH_3)_3C- COOH`
`CH_3 CH_2 CH_2 COOH`
`CH_3 - UNDERSET(CH_3) underset(|)(CH) -COOH`

ANSWER :A
13272.

Which one of the reactions gives an explosive RDX?

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NITRATION of PHENOL
Nitration of GLYCOL
Nitration of UROTROPINE
Nitration of glycerol

Solution :Nitration of urotropine
13273.

Using uncertainity principle,calculate the uncertainty in velocity ofan electron if the uncertainty in position is 10^(-4) m .

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SOLUTION :`0.577 m SEC^(-1)`
13274.

underset((a))CH_(3)-C-=C-underset((b))(CH_(2)-CH)=CH-CH_(2)-underset((c))(overset(O)overset(||)(C))-Cl Reactivity toward catalytic hydrogenation

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`a GT B gt C`
`b gt a gt c`
`a gt CGT b`
`c gt a gt b`

ANSWER :D
13275.

Which of the following halic acid and maximum oxidising strength?

Answer»

`HClO_3`
`HC LO`
`HClO_4`
`HClO_2`

SOLUTION :Cl in `HClO_4` has highest oxidation STATE
13276.

What is an aqua regia ? Give its one use.

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Solution :Aqua regia is a MIXTURE of 1 : 3 by volume of CONE . `HNO_(3) ` and Cone . HCl.
Aque regia is used to dissolve to dissolve NOBLE metals like Au and pt.
`Au+4H^(+)+NO_(8)^(-)+4Cl^(-)rarrauCl_(4)^(-)+2H_(2)O+NO`
13277.

When CO is heated with NaOH under pressure we get

Answer»

SODIUM oxalate
Sodium acetate
Sodium format
Sodium benzoate

Answer :C
13278.

The time taken for 10% completion of a first order reaction is 20 mins. Then, for 19% completion, the reaction will take

Answer»

40 mins
60 mins
30 mins
50 mins

SOLUTION : `k = (2.303)/(20) log (100)/(90)`…(i)
`k=(2.303)/(x) log (100)/((100-19))`…(II)
On equating (i) and (ii), `x=(20(2-log81))/((2-log90))`=40 mins
13279.

Which is not considered as a constituent of portland cement?

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`Ca_2SiO_4`
`Ca_3SiO_5`
`Ca_3Al_2O_6`
`CaSiO_3`

ANSWER :D
13280.

Which of the following carbonium ions has the least stability ?

Answer»

METHYL
ethyl
isopropyl
tert-butyl.

ANSWER :A
13281.

The reagent can be used to distinguish between cane sugar and lactose is

Answer»

BAYER's reagent
lodine solution
Million's reagent
Tollen's reagent

Answer :D
13282.

Which of the following pair hasmoreor less same atomicradius due to lanthanide contraction?

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TI and V
Fm and Md
No andLr
ZR and HF

Solution : Zr and Hf
13283.

Which of the following reactions is not exothermic

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`C(s)+O_(2)(g)rarrCO_(2)(g)`
`C(s)+2S(s)rarrCS_(2)(g)`
`CH_(4)(g)+2O_(2)(g)rarrCO_(2)(g)+2H_(2)O(l)`
`CO(g)+(1)/(2)O_(2)(g)rarrCO_(2)(g)`

Solution :This reaction absorbed HEAT, so it is ENDOTHERMIC reaction.
13284.

Which one of the following is NOT ture for bleaching powder ?

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It is used as a reducing AGENT in chemical INDUSTRIES
It is used for bleaching wood pulp in paper factories
It is used for disinfecting drinking water
it is used for bleaching linen in TEXTILE INDUSTRY

Solution :Bleaching POWDER is not used as a reduction agent in chemical industries. Reducing agent a substance that tends to bring about reduction by being oxidized and losing electrons.
13285.

Which of the following binary mixtures will have same composition in liquid and vapour phase?

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BENZENE - Toluene
Water - NITRIC acid
Water - Ethanol
n-Hexane - n - Heptane

Solution :(b) and (c) FORM non-ideal solutions and hence azeotropic mixture which have same composition in liquid and vapour phase.
13286.

The reagent of choice for the selective reduction of a keto group in the presence of an ester functional group is :

Answer»

LITHIUM ALUMINIUM hydride
Sodium borohydride
Hydrogen and PALLADIUM on carbon
Sodium in ethanol

Answer :B
13287.

Which compound in each of the following pairs will react faster in S_(N)2reaction with - OH ? (i) CH_(3)Br " or " CH_(3) I "" (ii) (CH_(3))_(3)C Cl " or " CH_(3)Cl

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Solution :(i) Since `I^(-)`ION is a better leaving group than Brion, THEREFORE, `CH_(3) I`REACTS faster than `CH_(3)Br` .
(ii) On STERIC consideration, `1^(@) ` halides are more reactive than tert-alkyl halides in `S_(N)2`REACTIONS. Therefore, `CH_(3)Cl`will react at a faster rate than`(CH_(3))_(3) C Cl `.
13288.

Theory of 'active mass' indicates that the rate of a chemical reaction is directly proportional to the

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EQULIBRIUM constant
PROPERTIES of reactants
VOLUME of APPARATUS
CONCENTRATION of reactants

Answer :D
13289.

Which of the following is a double salt?

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Carnalite
Mohr's salt
Alum
All of the aovbe

Answer :D
13290.

Which amongst the following metal carbonyls are inner orbital complex with diamagnetic property (i) Ni(CO)_(4) (ii) Fe(CO)_(5) (iii) V(CO)_(6) (iv) Cr(CO)_(6) Select the correct code :-

Answer»

I & II
II, III & IV
II & IV
I, II, & IV

Answer :C
13291.

Which is correct representation for the following chemical reaction?

Answer»




ANSWER :B
13292.

The section contains one question. Each question contains statements given in two columns which have to be matched . The statements in Column I are labelled A, B, C and D , while the statements in Column II are labelled p,q, r, s and t. Any given statement in Column I can have correct matching with ONE OR MORE statements (s) in Column II . The appropriate bubbles corresponding to the answers to these questions have to be darkened as illustrated in the following example: If the correct matches are A-p, s and t, B-q and r, C-p and q, and D-s and t, then the correct darkening of bubbles will look like the following . Match the following :

Answer»

<P>

Solution :(A) `Na_(2)CO_(3) + NaHCO_(3)`
USING phenolphthalein INDICATOR .
eq of `Na_(2)CO_(3)` will react.
` :. 1^(st)` titre value
`Na_(2) CO_(3) + HCl to NaHCO_(3)+ NaCl`
` :. 1^(st) ` titre value = eq of`Na_(2)CO_(3)`
Using methyl orange indicator :
eq of `NaHCO_(3) ` produced from `Na_(2)CO_(3)` & eq of `NaHCO_(3)` present will react :
`NaHCO_(3) + HCl to NaCl + H_(2)O + CO_(2)`
` :. 2^(nd) ` titre value = eq of `Na_(2)CO_(3) + " eq of " NaHCO_(3)` .
` A to r, s`
(B) `Na_(2)CO_(3) + NaOH`
Using phenolphthalein indicator :
`Na_(2)CO_(3)+HCl to NaHCO_(3) + NaCl`
` NaOH + HCl to NaCl + H_(2)O`
` :. 1^(st) ` titre value = eq of `Na_(2)CO_(3) + ` eq of NaOH .
Using methyl orange indicator :
`NaHCO_(3) + HCl to NaCl + H_(2)O + CO_(2)`
(produced from `Na_(2)CO_(3)`)
`2^(nd) ` titre value = eq of `Na_(2)CO_(3)`
` B to q,t `
(C ) `Na_(2)C_(2)O_(4) + H_(2)C_(2)O_(4)`
Using `NaOH ` & phenolphthalein indicator :
` H_(2)C_(2)O_(4) + NaOH to Na_(2)C_(2)O_(4) + H_(2)O`
` :. 1^(st)` titre value of NaOH =eq. of `H_(2)C_(2)O_(4)`
Using `KMnO_(4)` in acidic MEDIUM :
Using `KMnO_(4)` in acidic medium :
`KMnO_(4) + Na_(2)C_(2)O_(4) + H^(+) to CO_(2) + Mn^(2+) + H_(2)O + Na^(+)`
`2^(nd)` titre value will give the eq of total `Na_(2)C_(2)O_(4) & H_(2)C_(2)O_(4)` but in different n-factor value .
The estimation of `Na_(2)C_(2)O_(4)` can be done by the difference in moles of total `Na_(2)C_(2)O_(4) + H_(2)C_(2)O_(4) " in " 2^(nd) ` titration & moles of `H_(2)C_(2)O_(4) " in " 1^(st)` titration .
But difference in `1^(st) & 2^(nd)` titre value will not give the estimation of `1^(st)` constituent.
` C to P `
(D) `H_(2)CO_(3) + NaHCO_(3)`
Using NaOH & methyl orange indicator :
`H_(2)CO_(3) + NaOH to NaHCO_(3) + H_(2)O`
`1^(st)` titre value will give the estimation of `1^(st)` constituent.
Using `NaOH` & phenolphthalein indicator :
`NaHCO_(3) + NaOH to Na_(2)CO_(3) + H_(2)O`
`uparrow`
`(NaHCO_(3) " present + " NaHCO_(3) " preduced from " H_(2)CO_(3))`
Difference in `2^(nd) & 1^(st)` titre value will give the estimation of `2^(nd)` constituent .
`D to s, t`
13293.

Which one of the following bonds has the highest average bond energy(kcal/mol):

Answer»

S=O
C=C
C-=C
N-=N

Answer :D
13294.

Which of the following is cinnabar?

Answer»

`BaSO_(4)`
`HgS`
PbS
`CaSO_(4)2H_(2)O`

ANSWER :B
13295.

Which of the following compounds is expected to be most basic ?

Answer»




Solution :The basicity depends on the avaliablity of lone pair on N. Due to the PRESENCE of electron DONATING `CH_(3)` group the electron density on N increases. In COMPOUNDS (C) and (D) due to the presence of electronegative element (O and Cl respectively), availability of the lone pair on N is involved into RESONANCE with benzene.

13296.

Which of the following order is correct?

Answer»

`N_(2) gt F_(2) gtO_(2)`: Ionisation ENERGY
`H_(2)Te gt H_(2)SE gt H_(2)S gt H_(2)O`: REDUCING naturue
`H_(2)O gt H_(2)TegtH_(2)Se gt H_(2)S`: Boiling point
`HClO_(4) gt HClO_(3) gt HClO_(2) gt HClO`: oxidising nature

Answer :B::C
13297.

The section contains one question. Each question contains statements given in two columns which have to be matched . The statements in Column I are labelled A, B, C and D , while the statements in Column II are labelled p,q, r, s and t. Any given statement in Column I can have correct matching with ONE OR MORE statements (s) in Column II . The appropriate bubbles corresponding to the answers to these questions have to be darkened as illustrated in the following example: If the correct matches are A-p, s and t, B-q and r, C-p and q, and D-s and t, then the correct darkening of bubbles will look like the following . Match the reactions in Column I with nature of the reactions/type of the products in Column II. Indicate your answer by darkening the appropriate bubbles of the 4 xx 4 matrix given in the ORS.

Answer»


SOLUTION :N/A
13298.

What type of isomerism is shown by the following complexes? (i) [Cr(en)_(3)]^(3+) (ii) [Pt(NH_(3))_(4)][PtCl_(4)]

Answer»

SOLUTION :(i) Optical ISOMERISM (ii) Coordination isomerism (because sone CL and `NH_(3)` ligands may interchange, e.g., `[Pt(NH_(3))_(3)Cl] [Pt(NH_(3))Cl_(3)]`
13299.

What is PVC ? Give one use of it.

Answer»

Solution :PVC is polyvinyl chloride .
It is used for making RAIN COATS and TOYS.
13300.

Which one of the compounds does not decolourised an acidified solution of KMnO_4 ?

Answer»

`SO_2`
`FeCl_3`
`H_2O_2`
`FeSO_4`

ANSWER :B