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15701.

Which is correct about physical adsorption?

Answer»

HIGH TEMPERATURE and high pressure FAVOUR ADSORPTION.
High temperature and LOW pressure favour adsorption.
Low temperature and high pressure favour adsorption.
Low temperature and low pressure favour adsorption.

Answer :C
15702.

Which of the following has Frenkel defect?

Answer»

sodium chloride
GRAPHITE
silver BROMIDE
DIAMOND

Answer :C
15703.

What are the limitations of valence bond theory?

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Solution :In case of the coordination compounds, the valence bond theory has the following LIMITATIONS :
(1) It cannot explain the spectral properties (colours) of the complex compounds.
(2) Even if the magnetic MOMENTS can be calculated from the number of unpaired electrons, it cannot explain the magnetic moment arising due to orbital motion of electrons.
(3) It cannot explain why the metal ions with the same oxidation state give inner complexes and OUTER complexes with different ligands.
(4) In every complex, it cannot explain magnetic properties based on geometry of the complex.
(5) Quantitative interpretations of THERMODYNAMIC and kinetic stabilities of the coordination compounds cannot be accounted.
15704.

Total number of complexes among the following which are opticaly active? (i) [Cr(O x)_(3)]^(3-) (ii) cis-[Pt(Cl_(2))(en)] (iii) cis[Rh(Cl_(2))(NH_(3))_(4)]^(+) (iv) Ru(dipy)_(3)]^(3+) (v)cis[Co(NO_(2))_(3)(dien)] (vi) Trans-[Co(NO_(2))_(3)(dien)] (vii) cis[Co(NO_(2))_(3)(NH_(3))_(3)]

Answer»


ANSWER :2
15705.

Which one of the following compounds when heated with KOH and a primary amine gives carbylamine test.

Answer»

`CHCl_(3)`
`CH_(3)Cl`
`CH_(3)OH`
`CH_(3)CN`

SOLUTION :`CHCl_(3)` GIVE carbylamine test.
`RHN_(3)+CHCl_(3)+3 KOH("alc.")overset(Delta)rarrunderset("ALKYL isocyanide")(RNvec=C+KCl+3H_(2)O)`
15706.

Which of the following ligand(s) can act as pi-acid ligand.?

Answer»

`sigma`-cyclopentadienyl
`pi`-allyl
`B_(3)N_(3)H_(6)`
`pi`-cyclopentadienyl

Solution :Given ligands accept `M overset(pi)TOL` BACK bonding to disperse increased electron DENSITY at metal.
15707.

Which of the following is the anhydride of perchloric acid:

Answer»

`Cl_2O`
`ClO_2`
`Cl_2O_6`
`Cl_2O_7`

ANSWER :D
15708.

What are unit cells ? State its types.

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SOLUTION :The smallest part of space LATTICE of a crystal that SPECIFY the crystal completely is called unit cell.

The unit cell chosen in most general case has its sides PERPENDICULAR to each other and has shortest length and the ENTIRE crystal is generated by translational displacement of unit cell in 3D. The above figure shows movement of unit cell in 2D.
In 2D, a parallelogram with side of length ..a.. and ..b.. and an angle r between these sides is chosen as unit cell.
15709.

Two element X (At.mass=75)and Y (At. Mass=16) combine to give a compound having 75.8% of X. the formula of the compound is:

Answer»

XY
`X_(2)Y`
`X_(2)Y_(2)`
`X_(2)Y_(3)`

ANSWER :D
15710.

When phosphorus trichloride PCI_3(l) reacts with water, the products are

Answer»

`PCl_(5) and H_(3)PO_(4)`
`H_(3)PO+_(4) and Cl_(2)`
`H_(3)PO_(4) and HCl`
`H_(3)PO_(3) and HCl`

Answer :D
15711.

Which of the following polymers is biodegradable ?

Answer»

`(--CH_(2)-underset("CL")underset("|")"C"=CH-CH_(2)--)_(N)`


SOLUTION :PHBV is a biodegradablepolymer .
15712.

Which of thefollowingcan beusedto distanguish propene frompropyne ?

Answer»

ALK.`KMnO_(4)`<BR>`Br_(2)`water
dil . `H_(2) SO_(4)`
ammonical `AgNO_(3)`

ANSWER :D
15713.

Write the structues of organic compound A to F in the following sequence of reactions : .

Answer»

SOLUTION :.
15714.

Which of the following ppt is insoluble in NH_(3) solution ?

Answer»

`AGI`
`Ag_(2)S`
`AGCL`
`AgBr`

ANSWER :a,B
15715.

Write the IUPAC name the draw the structure of each of the following complex entities :3 (i) [Co({:(COO),(|""),(COO))_(3)]^(3-) (ii) [Cr(CO)_(6)] (iii) [PtCl_(3)(C_(2)H_(4))] (At.nos. Cr=25,Co,27, Pt=78)

Answer»

Solution :(i) Trioxalato Cobaltate (III)

(ii) Hexacarbonyl chromium (o)

(iii) Trichloridoethene platinum (IV)
15716.

Which one is most metallic ?

Answer»

P
As
Sb
Bi

Answer :D
15717.

Which statement is wrong

Answer»

Beryl is an EXAMPLE of CYCLIC SILICATE
`Mg_(2)SiO_(4)` is orthosilicate
Basic structural unit in silicates is the `SiO_(2)` tetrahedron
Feldspars are not aluminosilicates

Answer :D
15718.

When the following aldohexose exists in its D-configuration, the total number of stereoisomers in its pyranose form, is {:(CHO),(|),(CH_(2)),(|),(CHOH),(|),(CHOH),(|),(CHOH),(|),(CH_(2)OH):}

Answer»


ANSWER :`4.00`
15719.

The reagent with which both acetaldehyde and acetone react easily is :

Answer»

FEHLING SOLUTION
Grignard REAGENT
Schiff.s reagent
Tollen.s reagent

Answer :B
15720.

Which of the following compound can not show geometrical isomerism?1

Answer»




ANSWER :A
15721.

What freezes out first when a solution of common salt is cooled?

Answer»

SOLUTION :WATER as ICE.
15722.

What is Sol ?

Answer»

Solution :The colloidal SYSTEM of SOLID dispersed in liquid calleded .SOL..
15723.

Which is the characteristic of oxygen molecule?

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diamagnetic with no-unpaired electron
diamagnetic with two unpaired electrons
paramagnetic with two unpaired electrons
paramagnetic with no unpaired electrons

Solution :OXYGEN `O_2` is paramagentic DUE to PRESENCE of two unpaired electrons in antibonding MOLECULAR ORBITALS
15724.

Which of the following term means pain killing?

Answer»

Antibiotic
Analgesic
Antipyretic
Antioxidant

Solution :Medicines which RELIEVE or DECREASE PAIN are termed as analgesics.
15725.

Write the structures of the following compounds: (i) 2-Chloro-3-methylpentane (ii) 1-Chloro-4-ethylcyclohexane. (ii). 4-tert-butyl-3-iodoheptane (iv) 1-4-Dibromobut-2-ene. (v) 1-Bromo-4-sec-butyl-2-methylbenzene.

Answer»

SOLUTION :
15726.

Which of the following gives carbylamine reaction?

Answer»

`CH_3 CONH_2`
`CH_3NH_2`
`(CH_3)_2 NH`
`C_2 H_5 NO_2`

SOLUTION :`CH_3NH_2`
15727.

Which electronic configuration corresponds to minimum energy and maximum stability?

Answer»

`(n-1) d^10 ns^1`
`(n-1) d^5 ns^1`
`ns^2 np^6`
`ns^2 np^3`

SOLUTION :`ns^2 np^6` (CONFIGURATION of octet) has maximum stability and MINIMUM ENERGY
15728.

The SRP for the different halogens is in the order of

Answer»

`F GT Cl gt Br gt I`
`F lt Cl lt Br lt I`
`F lt Cl gt Br gt I`
`F=Cl = Br = I`

ANSWER :A
15729.

What type of change takes place when suger is dissolved in a cup of tea ?

Answer»

Solution :When suger is dissolved in a cap of TEA , PHYSICAL change takes PLACE .
15730.

The type of hybridisation take place in [HgI_(3)^(-)] is ………………..

Answer»

`SP`
`sp^(3)`
`sp^(2)`
`DSP^(2)`

ANSWER :B::C
15731.

When formaldehyde is treated with methanol in presence of dry HCI gas or fused CaCI_(2) it, yields:

Answer»

ACETALDEHYDE
mercaptal
methylal
dimethyl ETHER

ANSWER :C
15732.

Which of the following metals will not react dilute hydrochloric acid?

Answer»

Cu
Zn
Fe
Ca

Answer :A
15733.

Which of the following is a colloid ?

Answer»

SUGAR solution
Urea solution
Silicic acid
NaCl solution

Answer :C
15734.

When 0.01 moles of the following acids are dissolved in 1 L "of" H_(2)O, the [H^(+)] will be greatest in:-

Answer»

`HNO_(2) , pka = 3.0`
`HCOOH , pka = 3.75`
`HCN , pka = 9.4`
`CH_(3)COOH , pka = 4.75`

ANSWER :A
15735.

Vitamin C is chemically

Answer»

ASCORBIC ACID
CITRIC acid
aspirin
aspartic acid

Solution : Ascorbic acid.
15736.

The standard heat of formation of NO_2(g) amd N_2O_4(g) are 8.0 2.0 kcal mol^-1 respectively. The heat of dimerization of NO_2 in kcal is:

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10
`-6.0`
`-12.0`
`-14.0`

ANSWER :D
15737.

Which one is a natural linear polymer ?

Answer»

COTTON
LINEN
SILK
All of these

SOLUTION :All of these
15738.

Which is used in paint?

Answer»

PBO
`Pb_(3)O_(4)`
PbCr`O_(4)`
`PbCl_(2)`

Answer :A::B::C
15739.

Which of the following features of protein is not observed at the iso-electric point ?

Answer»

MAXIMUM SOLUBILITY
Maximum electrophoretic MIGRATION
Maximum PRECIPITATION
Maximum viscosity

Solution :Maximum solubility
15740.

Which of the following can not evolve more than one gas (vapour) if heated in dry test tube.

Answer»

`naNO_(3)(s)`
`MgCO_(3)(s)`
`FeSO_(4)(s)`
`(NH_(4))_(2)Cr_(2)O_(7)(s)`

ANSWER :B
15741.

Which of the following hydrogen halide is liquid at 273K?

Answer»

HI
HBr
HCI
HF

Answer :D
15742.

Two particle A and B are in motion. If the wavelength associated with 'A' is 33.33 nm, the wavelength associated with 'B' whose momentum is 1//3^(rd) of 'A' is

Answer»

`1.0 xx 10^(-8)` m
`2.5 xx 10^(-8)` m
`1.25 xx 10^(-7)` m
`1.0 xx 10^(-7)` m

Solution :(d): `lamda_(A) =33.3` nm = `33.33 xx 10^(-9)` m
`lamda_(A) = H//p_(A)`...(i)
`lamda_(B) = (h)/(p_(A)//3) = (3h)/(p_(A))`...(II)
From eq (i) and (ii), we get
`(lamda_(A))/(lamda_(B)) = 1/3 RARR lamda_(B) = 33.33 xx 10^(-9) xx 3 =99.99 xx 10^(-9)` m
`~~ 1.0xx10^(-7)` m
15743.

t_((t)/(2)) of Th^(232) is 1.39xx10^(10) .Calculate alpha-particles omitted by 1 gm Th per sec.

Answer»

SOLUTION :`4.104xx10^(3)`
15744.

Which of the following compounds is an amine ?

Answer»




SOLUTION :
AMINE
15745.

Which of the following has the maximum acidic strength

Answer»

p-nitrophenol
m-nitrobenzoic ACID
p-nitrobenzoic acid
o-nitrobenozoic acid

Answer :D
15746.

Which metal is used for filament of electric bulb?

Answer»

Pt
Fe
W
Cu

Answer :C
15747.

Units of ebullioscopic constant are K kg mol^-1 .

Answer»
15748.

Which one of the following product is formed when propan-2-ol is treated with Cu at 573 K?

Answer»

PROPANAL
PROPANONE
Propan-1-ol
Propane

SOLUTION :Propanone
15749.

Which name is incorrect?

Answer»




SOLUTION :
15750.

What happens when NH_4Cl is heated withCa(OH)_2(equation only) ?

Answer»

SOLUTION :`2NH_4Cl + CAO overset (Heat) RARR CaCl_2 + H_2O + 2NH_3 UARR`