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16751.

Which one of the following carbohydrates will show mutarotation?

Answer»

Sucrose
Maltose
Lactose
Both (B) and (C )

ANSWER :D
16752.

Whichof thefollowingcannotbeconsidered as amechansticstepin cahainreactionof methanewith Cl_(2) ?

Answer»

`Cl_(2) toCl^("*")`
`CH_(4)+Cl^("*") to CH_(3)Cl+H^("*")`
`Cl^("*")+CH(4)to CH_(3)^("*")+HCL.`
`Cl^("*")+CH_(3)^("*") to CH+(3)Cl`?

Answer :B
16753.

Which of the following are secondary bromides ?

Answer»

`(CH_(3))_(2)CHBR`
`(CH_(3))_(3)C CH_(2)Br`
`CH_(3)CH(Br)CH_(2)CH_(3)`
`(CH_(3))_(2)CBrCH_(2)CH_(3)`

Solution :
16754.

Write the IUPAC name of CH_(3)-underset(NH_(2))underset(|)(CH)-CH_(2)-CHO

Answer»

SOLUTION :3-Aminobutanal.
16755.

Which indicator can be used in the titration of strong acid and strong base

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Only phenoplphthalein
Only methyl orange
Eitehr of the two
Red litmus

Solution :As the RESULTANT solution will be NEUTRAL so either of them can be USED.
16756.

What is the half-life period of a reaction having rate constant 6.93xx10^(-4) sec^(-1).

Answer»

SOLUTION :Half-life PERIOD
`T_(1/2)=0.693/(LAMBDA)=0.693/(6.93xx10^-4)=10^3sec`
16757.

Which of the following reagents can be used for separating a mixture of ehter and alkyl halide ?

Answer»

Dil. `H_2SO_4`
Conc.`H_2SO_4`
Alk. `KMnO_4`
ACIDIC `K_2Cr_2O_7`

Solution :ETHERS form soluble dialkyl OXONIUM HYDROGEN sulphate with conc. `H_2SO_4` while ALKYL halides are not soluble in conc. `H_2SO_4`
16758.

Which of the following does not refer to the principle forms of carbohydrate present in our food?

Answer»

fructose
sucrose
starch
cellulose

Answer :C
16759.

Transition metals are placed in tlhe long form of periodic tabe between

Answer»

`3^(nd)` and `4^(TH)` group
`1^(ST)` and `3^(RD)` group (C) `2^(nd)` and `13^(th)` group
2^(nd)` and `13^(th)` group
1^(st)` and `2^(nd)` group

Answer :C
16760.

When orthophosphoric acid is strongly heated the product formed is

Answer»

PHOSPHINE `PH_3`
Phosphorous TRIOXIDE , `P_2O_3`
Phosphorous ACID, `H_3PO_3`
METAPHOSPHORIC acid , `HPO_3`

ANSWER :D
16761.

Which of the following is an example of covalent solid ?

Answer»

Silicon carbide
`BaSO_(4)`
Solid `CO_(2)`
IODINE.

Solution :SiC (COVALENT), `BaSO_(4)` ( IONIC), solid `CO_(2)` ( molecular), iodine ( molecular)
16762.

Which of the following compound can be used as antifreeze in automobile radiators?

Answer»

methanol
ethanol
Neopentyl alcohol
ethan -1, 2-diol

ANSWER :D
16763.

What is the "coagulation" process?

Answer»

Solution :The PROCESS by means of which the particles of the dispersed phase in a sol are precipitated is called coagulation. It is generally ACHIEVED by neutralizing the CHARGE on colloidal particles by the addition of a suitable solvent.
16764.

To neutralize completely 20 mL of 0.1M aqueous solution of phosphorus acid (H_(3)PO_(3)) the volume of 0.1M aqueous KOH solution required is

Answer»

40 mL
20 mL
10 mL
60 mL

Solution :Since `H_(3)PO_(3)` is dibasic, 0.1 M solution =- 0.2 N solution.
`underset(("Acid"))(N_(1)V_(1))=underset(("Base"))(N_(2)V_(2))`
`(0.2 N)xx20 mL)=(0.1N)xxV_(2)`
`V_(2)=((0.2N)xx(20ML))/((0.1N))=40 mL.`
16765.

The structure of cyclohexanol is _________

Answer»




ANSWER :B
16766.

Which readily liberates I_(2) from KI in acidic medium

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`PO_(4)^(3-)`
`NO_(2)^(-)`
`PO_(4)^(3-)`
`NO_(3)^(-)`

ANSWER :B
16767.

Which of the following does not undergo Aldol condensation ?

Answer»

`Cl-CH_(2)-CHO`
`C Cl_(3)-CHO`
`C_(6)H_(5)-CH_(2)-CHO`
`CH_(3)-CHO`

Answer :B
16768.

Which of the following statements is (are) incorrect? (i) Percentage ionic character in CsCl bond is ~55%. (Electronegativity values of Cs and Cl are 0.7 and 3.0 respectively) (ii) From H_(2)O to H_(3)O^(+), the geometry around O atom changes drastically . (iii) The most stable oxidation state for element with atomic number 113 is expected to be +2. (iv) The 2^("nd") ionization energy of Ca is greater than 1^("st") ionization energy of it but lower then 2^("nd") ionization energyof K.

Answer»

Only i
i,II, iii
ii, iii
iii, iv

Answer :C
16769.

The reagent used in the Wolff-Kishner reduction is

Answer»

Zn-hg and conc HCl
Anhydrous `ZnCl_(2)` and conc HCl
Hydrazine, GLYCEROL and alkali
Zn and `CH_(3)COOH`

Answer :C
16770.

Using IUPAC norms, write the formulae of the following : (i) Tetrahydroxozincate (II) (vi) Hexaamminecobalt (III) sulphate (ii) Potassium tetrachloridopalladate (II) (vii) Potassium trioxalatochromate (III) (iii) Diamminedichloridoplatinum (II)(viii) Hexaammineplatinum (IV) (iv) Potassium tetracyanonickelate (II) (ix) Tetrabromidocuprate (II) (v) Pentaamminenitrito-O-cobalt (III) (x) Pentaamminenitrito-N-cobalt (III)

Answer»

Solution :(i) `[Zn(OH)_(4)]^(2-)` (II) `K_(2)[PdCl_(4)]` (III) `[Pt(NH_(3))_(2)Cl_(2)]`(iv) `K_(2)[Ni(CN)_(4)]`
(v) `[Co(NH_(3))_(5)(ONO)]^(2+)` (vi) `[Co(NH_(3))_(6)]_(2)(SO_(4))_(3)` (vii) `K_(3)[Cr(C_(2)O_(4))_(3)]`
(viii) `[Pt(NH_(3))_(6)]^(4+)`(ix) `[CuBr_(4)]^(2-)` (x) `[Co(NH_(3))_(5)(NO_(2))]^(2+)`
16771.

Very pure hydrogen (99.9%) can be made by which of the followingprocesses ?

Answer»

REACTIONOF SALT like hydrides with water
reactionof methane with steam
MIXING natural HYDROCARBONS of highmolecular weight
electrolysis of water

Answer :A
16772.

The solvent which neither accepts proton nor donates proton is called

Answer»

Amphoteric
Neutral
Aprotic
Amphiprotic

Solution :The SOLVENT which NEITHER accept PROTON nor donates.
16773.

Which polymer is used in preparation of carpet ?

Answer»

PVC
Nylon-6
Nylon-6,6
Terylene

Solution :Nylon-6
16774.

What is starch? What are the ultimate hydrolysis products?

Answer»

Solution :(i) Starch is a polysaccharide in which a LARGE NUMBER of monosaccharide UNITS are linked to each other by oxide bridges and these linkages are called glyosidic linkages. General FORMULA of starch is `(C_(6)H_(10)O_(5)_(n)`.
(ii) It is a white amorphous substance with no taste or smell. (iii) Starch get hydrolysed to monosaccharides.
`underset("Starch")((C_(6)H_(10)O_(5))_(n))+nH_(2)Ooverset(H^(+))rarrunderset("GLUCOSE")(nC_(6)H_(12)O_(6))`
16775.

What is carbylamines test for 1^(@) amine?

Answer»

Solution :Carbylamine TEST: When `1^(@)` AMINE is heated with `CHCl_(3)` and alcoholic KOH solution, an isocyanide or carbylamine is produced. This reaction is called carbylamine test for `1^(@)` or primary amines.
e.g `underset("ETHYLAMINE")(C_(2)H_(5))-NH_(2)CHCl_(3)to+3KOH (alc) overset(Delta)to underset("Ethyl carbylamine")(C_(2)H_(5)-NC)+3KCI+3H_(2)O`
16776.

Which of the following Lewis structures are valid resonating structuresfor the azide ion?

Answer»

`:OVERSET(..)(N)overset(o+)(-)UNDERSET(..)overset(..(N)-overset(..)(N):`
`:N-=N=overset(..o+)(N):`
`:overset(o+..)(N)=overset(+)(N)=overset(..o+)(N):`

ANSWER :A::C
16777.

Which of the following statement is correct:

Answer»

KI is added into `I_(2)`to increase its SOLUBILITY in water
Boron is used as CONTROLLER in nuclear reactor
`Tl` and Pb are poisonous in nature
All of these

Solution :When KI added into `I_(2), KI_(3)`formed and solubility of KI increase.
16778.

Which one is weak antiseptic ?

Answer»

DILUTE solution of BORIC acid
Tincture iodine
`KMnO_(4)`
Soframycine 

Solution :Dilute solution of boric acid
16779.

What is the coordination number of octahedral voids?

Answer»

SOLUTION :The C.N. of an OCTAHEDRAL VOID is 6.
16780.

Which of the following can be used as an antacid ?

Answer»

Ranitidine
Histamine
Equanil
Aspirin

Answer :A
16781.

Write the optical properties of colloids with diagram.

Answer»

Solution :(i) Colloids have OPTICAL property. When a homogeneous solution is seen in the DIRECTION of light, it appears clear but it appears DARK, in a perpendicular direction. (ii) But when light passes through colloidal solution, it is scattered in all directions. (iii) This effect was first observed by Faraday, but investigations are made by Tyndall in detail, HENCE CALLED as Tyndall effect.
16782.

Which of the following complex is used for treatment of cancer ?

Answer»

`K_4[Fe(CN)_6]`
Cis-`[PT(NH_3)_2Cl_2]`
`[C^0(NH_3)_6]Cl_3`
`NA[Ag(CN)_2]`

Answer :C
16783.

Which is an example of thermo setting polymer

Answer»

Polythene
PVC
NEOPRENE
Bakelite

Answer :D
16784.

Which one of the following statements is not true regarding ( +) Lactose ?

Answer»

On hydrolysis , (+)lactose gives equal amount of D(+) GLUCOSE and D(+) GALACTOSE .
(+) Lactose is a `beta`-glucoside formed by the union of a molecule of D(+) glucose and a molecule of D(+) galactose.
(+) Lactose is a reducing sugar and does not EXHIBIT mutarotation .
(+) Lactose ,`C_(12)H_(22)O_(11)` contains 8-OH groups.

Solution :`(+)` Lactose is a reducing sugar and all reducing sugar shows mutarotation.
16785.

The unit of K for pseudo first order reaction is

Answer»

`"MINUTE"^(-1)`
`"MOL"^(-1) L "LIT""minute"^(-1)`
`"mol"^(-1) " lit ""minute"^(-1)`
`"mol"^(-2) " lit "^(2)"minute^(-1)"`

Answer :B
16786.

Which one of the following is used as selective reducing agent in the conversion of cyanide to aldehyde?

Answer»

RANEY NI
`LiAlH_4`
`SnCl_2 //HCL`
DIBAL-H

Solution : DIBAL-H
16787.

What is chromatography?

Answer»

Solution :• The chromatographic technique is a PROCESS of separation of components in a mixture which is mainly BASED on adsorption of components on the surface of adsorbents.
• This method is very effective and used for identification, detection and estimation of many SUBSTANCES even if they are CONTAINED in micro QUANTITIES.
16788.

What is a primary cell? Give an example.

Answer»

Solution :A primary cell is the cell in which the REDOX reactio OCCURS only once and the cell becomes DEAD after some time. It cannot used again.
16789.

Which reactants are involved in Mendius reaction ?

Answer»

RCN and `Na//C_(2)H_(5)OH`
RCN and `H_(2)O//HCl`
RCN and `Zn//NH_(4)CL`
RCN and `SnCl_(2)//HCl`.

SOLUTION :Medius reaction INVOLVES the reduction of a cyanide with `Na//C_(2)H_(5)OH` to give `1^(@)` amine.
16790.

Which shows sp^3-hybridisation:

Answer»

`ClO_2^-`
`ClO_3^-`
`ClO_4^-`
All

Answer :B
16791.

When I_(2) is dissolved in C C l_(4) the colour that result is

Answer»

BROWN
Violet
Colourless
Bluish green

Solution :The COLOUR of Iodine solution in aliphatic hydrocarbons ( or ) `C C l_(4)` is bright violet
16792.

Whichof the followingstatementsare trueabout HCOOH ?

Answer»

Itis STRONGER acid than `CH_(3)COOH`
Itfromsformyl chloride with `PCl_(5)`.
It givesCO and`H_(2)O`on heatingwith conc `H_(2)SO_(+)`
It reduces Tollen'sreagent.

Solution :Thestatementthat HCOOH reactswith `PCl_(5)`to fromformylchloride is wrong . Allother statemenet i.e., (A) (C) and(D) are correct .
16793.

Which statement is true

Answer»

`C_(6)H_(5)OH` is more acidic than `C_(2)H_(5)OH`
`C_(6)H_(5)OH` is less acidic than `C_(2)H_(5)OH`
`C_(6)H_(5)OH` react with `NaHCO_(3)`
`C_(6)H_(5)OH` GIVES oxime with `NH_(2)OH and HCl`

Solution :
16794.

The value of disintegration constant of radioactive isotope

Answer»

Decreases with increasing TEMPERATURE
Decreases with increasing pressure
Increases with increasing pressure
Is INDEPENDENT of temperature and pressure

Answer :D
16795.

What is Activation Energy (E_(a))?Explain graph of reaction of activation energy and write about its probability.

Answer»

Solution :The energy required to form the intermediate,called activated complex (C ).Is known as activation energy `(E_(a))` or
The MINIMUM energy required to convert reactant to the product is called KINETIC energy of reaction.
Explanation of activation energy with the help of graph 2 mole.HI is formed by the reaction of 1 MOL `H_(2)` with 1 mole `I_(2)`
`H_(2(g))+I_(2(g))to2HI_((g))`
According to Arrhenius ,this reaction can take place only when amolecule of hydrogen and a molecule of iodine collide to form an ustable intermediate.
It EXISTS for a very short time and then breaks up to form two molecules of Hydrogen iodide.

The energy required to form this intermediate called activated complex (C ) ,is known as activaition energy `(E_(a))`

Activated Energy `(E_(a))`= (Potential energy of intermediate complex (C))-(Potential energy of reactants)
The probability of reaction and `E_(a)`
(i)The COLLISION of molecules with more kinetic energy than `E_(a)` result into product
(ii)The collision of molecules with less kinetic energy than `E_(a)` do not form product.
(iii)`E_(a)ge` energy of collide -molecule than product will form .
(iv)According to Arrhenius energy of activation and rate of reaction is related as
`k=Ae^((-E_(a))//(RT))` and In k=In A-`(E_(a))/(RT)`
16796.

Which of the following has lowest boiling point ?

Answer»

HF
HCl
HBr
HI

Answer :B
16797.

Which polymer is generally used in carry bag?

Answer»

Polyester
Bakelite
Polyethylen
Alkyd resin

Answer :C
16798.

Which of the following polymers soften on heating and harden on coolong ? What are the polymers with this property collectively called ? What are the structural similarities between such polymers ? Bakalite , urea - formaldehyde resin , polythene, polyvinyls , polystyrene.

Answer»

Solution :Polythene , POLYVINYLS (PVC , teflon , acrilan , ETC.) polystyrene soften on heating and harden on coolong. Such polymers are called thermoplastic polymers. These polymers are linear or slightly branched long chain molecules. Their intermolecular forces of attraction lie in between those of elastomers and fibres. BAKELITE and urea -FORMALDEHYDE , on the other hand , are thermosetting polymers , These cannot be remelted and reworked.
16799.

Which phenomenon will occur when water is added to anhydrous Calcium Chloride ?

Answer»

ABSORPTION 
ADSORPTION 
DESORPTION 
SORPTION 

SOLUTION :Absorption
16800.

The typical animal glycolipids is

Answer»

lecithin
cephalin
prostaglandins
cerebrosides

Answer :D