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23151.

Which hydride is the strongest base ?

Answer»

`SbH_(3)`
`NH_(3)`
`PH_(3)`
`AsH_(3)`

ANSWER :B
23152.

Which one has highest boiling point :

Answer»

ETHANE
Butane
Butan-1-ol
Pentane

Answer :C
23153.

What is meant by an elementary reaction ?

Answer»

SOLUTION :A REACTION which takes PLACE in one step is called an elementary reaction. For example, reaction between `H_(2)` and `I_(2)` to from 2 HI is an elementary reaction. DIFFERENT steps of a complex reaction are also elementary reactions.
23154.

When one mole of F atoms are ionised to F^(-) , the energy released is X Joules. Then :-

Answer»

X Joules is sufficient to ionise 1 MOLE of gaseous Cl into `Cl^(+)`
X Joules is sufficient to ionise 1 mole of gaseous F into `F^(+)`
X Joules is sufficient to ionise 1 mole of gaseous F into `F^(+)` as well as 1 mole of gaseous Cl into `Cl^(+)`
Less than 1 mole of gaseous F or Cl atom will be ionised to `F^(+) or Cl^(+)`

ANSWER :D
23155.

Which of the following substances on heating will give a white sublimate ?

Answer»

`NH_(4)Cl`
`HgCl_(2)`
`AgCl`
`Hg_(2)Cl_(2)`

Answer :A,B,D
23156.

What is the ratio of Al, Cu and Na when 3F current is pass through different electrolytic solution of molten Al_(2)O_(3),, aqueous CuSO_(4) and molten NaCl ?

Answer»

`3:4:6`
`2:1:6`
`3:2:1`
`2:3:6`

SOLUTION :`2:3:6`
23157.

Why are Grignard soluble in ether but not in benzene?

Answer»

SOLUTION :Grignard reagents form COORDINATION COMPLEXES with ether but not with benzene since the former has lone PAIR of electrons but the latter does not.
23158.

Urea is not used :

Answer»

As fertilizer
In MANUFACTURE of plastic
In preparation of medicines
In purification of WATER

ANSWER :D
23159.

The standard reduction potentials of the elements A,B and C are +2.73 V, -1.85 V ande -1.36 V respectively. The order of their reducing power is

Answer»

`B GT C gt A`
`A gt B gt C`
`C gt B gt A`
`B gt A gt C`

ANSWER :A
23160.

The reagent required to convert ethene to 2- chloroethanol is :

Answer»

HCl
HOCl
NaOCl
`PCl_5`

ANSWER :B
23161.

What isthe orderfor thefollowingreactions? (a)2NO_(2(g))+ F_(2(g))to 2NO_(2) F_((g)) rate= k[NO_(2)][F_(2)] (b)CHC1_(3(g))+ C1_(2(g))to CC1_(4(g)) + HC1_((g)) rate = k [ CHC1_(3)][C1_(2)]^((1)/(2))

Answer»

SOLUTION :(a)ORDEROF THEREACTION=2
(B) Theorderof thereaction`=(3)/(2)`
23162.

underset(2./_\) overset(1. HNO_(2))toP The P is

Answer»




Solution :It is a semi pinacol-pinacolone TYPE REACTION and product is formed after formation of carbocation and its REARRANGEMENTS by ring EXPANSION.
23163.

Thermodynamically the most stable form of carbon is

Answer»

DIAMOND
graphite
Fullerene
none of these

Answer :A::B
23164.

Which of the following will give brick red ppt. with Fehling's solution?

Answer»

HCHO
HCOOH
glucose
FRUCTOSE

SOLUTION :`{:(HCHO),(|),(HCOOH),(|),("Glucose GIVES positive test with Fehling.s solution"),(|),("Fructose"):}`gives positive test with Fehling.s solution.
23165.

Which type of molecules form micelles?

Answer»

Non polar molecules
Polar molecules
Surfactant molecules
SALT of WEAK ACID and weak base

Answer :C
23166.

Which of the following ketone reduces Tollen's reagent in basic medium?

Answer»

`CH_3 COCH_3`

`{:(CH_2 OH),(""|),(C=O),(""|),("(CHOH)"_3),(""|),(CH_2 OH):}`
`{:(CHO),(""|),("(CHOH)"_4),(""|),(CH_2 OH):}`

Answer :C
23167.

Which of the following choices match(es) with the real gas with very large molar volume?

Answer»

`Zne1`
Attractive FORCES are DOMINANT
PV = nRT
P(V - nb) = nRT

Answer :C
23168.

Which of the following statements is/are incorrect?(a) Cassiterite is not the ore of tin (b) Metallurgy is a process of mixing of ore (c) concentration of chromite (FeO.Cr_2O_3) is done by magnetic separation (d) ZnS with depressant NaCN forms Na_2[Zn(CN)_4]

Answer»

(a) & (B)
only (a)
(b),(C) & (d)
(c) & (d)

ANSWER :A
23169.

Which of the following is not a salt

Answer»

Slaked lime
Lead SULPHATE
ZINC nitrate
NaCl

Answer :A
23170.

What is ammonolysis?

Answer»

Solution :The reaction of alkyl halides with ammonia (or amines) to FORM MIXTURE of `1^(@),2^(@),3^(@)` amines and quaternary SALTS is called AMMONLYSIS.
23171.

Wash is :

Answer»

`95.5%` alcohol
`10%` alcohol
`50%` acetate+ water
`50%`acetate+`50%` molasses

Answer :B
23172.

The vapour pressure of benzene at 90^@C is 1020 torr. A solution of 5 g of a solute in 58.5 g benzene has vapour pressure 990 torr. The molecular weight of the solute is:

Answer»

78.2
178.2
206.2
220

Answer :D
23173.

Which sugar is present in DNA ?

Answer»

RIBOSE
2-Deoxyribose
GLUCOSE
FRUCTOSE

ANSWER :B
23174.

Which of the following is the correct sequence of relative acidic strength ?

Answer»

`FCH_(2)COOHgtClCH_(2)COOHgtBrCH_(2)COOH`
`ClCH_(2)COOHgtBrCH_(2)COOHgtFCH_(2)COOH`
`BrCH_(2)COOHgtClCH_(2)COOHgtFCH_(2)COOH`
`ClCH_(2)COOHgtFCH_(2)COOHgtBrCH_(2)COOH`.

ANSWER :A
23175.

Which of the following are not thermosetting polymers?

Answer»

Bakelite
Polystyrene
PVC
Melmac

Answer :B::C
23176.

Which of the following are isomers ?

Answer»

METHYL alcohol and DIMETHYL ether
ETHYL alcohol and dimethyl ether
Acetone and ACETALDEHYDE
Propionic acid and propanone

Answer :B
23177.

Which of the following is/are soluble in ethanol

Answer»

`HgF_(2)`
`HgCl_(2)`
`HgBr_(2)`
`HgI_(2)`

Solution :Due to less capacity of HYDROGEN bonding of `I_(2)` with water `HgI_(2)` is less SOLUBLE in water .
23178.

The substance constituting more than 80% of cell contents is :

Answer»

Protein
Mineral
Fat
Water

Answer :D
23179.

When 2 gm A gas is introduced into an evacuated flask kept at 25^(@)C, the pressure is found to be 1 atm. If 3 g of another gas B is then added to same flask, the total pressure becomes 0.5 atm. The ratio of molecular weights is

Answer»

`1:1`
`1:2`
`2:3`
`1:4`

ANSWER :C
23180.

Which is the correct order of decreasing boiling point of azeotropic mixtures X-H_(2)O?

Answer»

`HI GT HBr gt HF gt HCL`
`HI gt HCl gt HBr gt HF`
`HF gt HCl gt HBr gt HI`
`HCl gt HF gt HBr gt HI`

Answer :B
23181.

When a radioactive element emits an alpha particle, the daughter element is placed in the periodic table

Answer»

TWO positions to the left of the parent element
Two positions to the RIGHT of the parent element
One POSITION to the right of the parent element
In the same position as the parent element

Solution :According to group DISPLACEMENT law
23182.

The vapour pressure 2.1%of an aqueous solution of a non volatile solute at 373 K is 755 mm Hg. Calculate the molar mass of the solute.

Answer»


Solution :`(P_(A)^(@)-P_(S))/P_(S)=x_(A)`
`P_(A)^(@)=760" MM hg, "P_(S)=755" mm Hg "`
`x_(B)=(P_(A)^(@)-P_(S))/P_(S)=(760" mm Hg "-755" mm Hg ")/(755mmhg)=0.0066`
A 2.1% awueous solution means 2.1 g of SOLUTE in 100 g of solution
`therefore "Mass of SOLVENT "=100 g-2.1g=97.9g `
`therefore "Mass of solvent" =100G 2.1 g-2.1 g =97.9 g`
`"Moles of solvent "n_(A)=(97.9g)/(18" g mol"^(-1))=5.439 g`
`x_(B)=n_(B)/(n_(A)+n_(B))" or "1/x_(B)=(n_(A)+n_(B))/n_(B)=n_(A)/n_(B)+1`
`n_(A)/n_(B)+1/x_(B)-1=1/(0.0066)-1=151.5-1=150.5`
`n_(B)=n_(A)/(150.5)=((5.349mol))/(150.5)=0.036 mol.`
`"MOLAR mass of folute"=("Mass of solute")/("Moles of solute")=((2.1g))/(("0.036mol"))=58.3" g mol"^(-1)`
23183.

Which of the following electrolytic solutions has the least specific conductance ?

Answer»

`0.02 N `
`0.2 N`
`2 N`
`0.002 N`

ANSWER :D
23184.

Which is not truonic, case of transition metals :

Answer»

They are mallcable and ductile
They have high melting and boiling points
They crystallise with body centred cubic and HEXAGONAL close PACKED structure only
They shows VARIABLE oxidation STATE althought not always

Answer :C
23185.

Write the isomers of the compound having formula C_(4)H_(9)Br.

Answer»

Solution :The possible isomers of `C_(4)H_(9)BR` are :
(i) `CH_(3)-CH_(2)-CH_(2)-CH_(2)-Br`
(II)`CH_(3)-underset("Br ")underset("| ")("C ")H-CH_(2)-CH_(3)`
(iii)`CH_(3)-underset(CH_(3))underset("|")("C ")H-CH_(2)-Br`
(IV)`CH_(3)-overset(CH_(3))overset("|")underset(CH_(3))underset("|")("C ")-Br`
23186.

The shape of ethylene molecule is

Answer»

Tetrahedral
Trigonal planar
Pyramidal
Linear

Answer :B
23187.

Which isomerism is shown by hte complex [Cr(H_(2)O)_(5)NCS]^(2+) ?

Answer»

Solution :It shows linkage ISOMERISM. The isome has the STRUCTURE: `[Cr(H_(2)O)_(5)SCN]^(2+)`
23188.

Which forms multimolecular layers during adsorption ?

Answer»

Chemisorption
van DER WAAL's adsorption
Freundlich adsorption
All

Answer :D
23189.

Which one is most reactive towards nucleophilic addition reaction?

Answer»




ANSWER :D
23190.

Which of the following minerals contains Fe

Answer»

MAGNETITE
magnesite
siderite
lemonite

Solution :Magnete `(Fe_(2)O_(4))` Siderite `(FeCO_(3))` and limonite `(Fe_(2)O_(3)3H_(2)O)` CONTAINS iron where as magnesite `(MgCO_(3))` magnesium containing MINERAL.
23191.

The specific conductance of 0.1N KCl solution at 23^@C is 0.012 Ohm^(-1) cm^(-1) . The resistance of the cell containing the solution at the same temperature was found to be 55 Ohm. The cell constant will be ………. .

Answer»

`0.142 cm^(-1)`
`0.66 cm^(-1)`
`0.918 cm^(-1)`
`1.12 cm^(-1)`

Solution :`K = 1/R xx "CELL constant"`
`:.` Cell constant = `k xx R`
`= 0.012 xx 55`
`= 0.66 cm^(-1)`.
23192.

Which one of the following is used as a sweetening agent in confectionery and beverages?

Answer»

GLYCEROL
PHENOL
BENZYL alcohol
Ethylene glycol

Solution :Glycerol
23193.

Which one of the following will not give white precipitate with ammonical silver nitrate solution

Answer»

`CH_(3)=C^(@)C-CH_(3)`
`CH_(3)-underset(CH_(3))underset(|)(CH)-C-=-CH_(3)`
`CH_(3)-CH_(2)-CH=CH_(2)`
all of these

Solution :TERMINAL alkyne GIVES +ve test with ammonical silver NITRATE solution.
23194.

Which of the following equimolar solution is expected to have lowest freezing point ?

Answer»

`0.5 M H_(3)PO_(3)`
`0.5 M Na_(3)PO_(4)`
0.5 M NaCl
0.5 M Aniline

Solution :`Na_(3)PO_(4) HARR 3Na^(+)+PO_(4)^(3-)` (PRODUCES 4 IONS)
23195.

Writethe chemical name ,source and deficientof the following(i) VitaminB_(6)(ii) Vitamin B_(6)(iii)VitaminB_(9) (iv) Vitamin B_(12)(v) Vitamin C.

Answer»

SOLUTION :
23196.

What happens when ethanol is heated with conc. H_2SO_4 at 140^@C ?

Answer»

SOLUTION :DIETHYLETHER is FORMED.
23197.

Which of the following statements is not correct about order of a reaction?

Answer»

The order of a reaction can be a fractional number
Order of a reaction is experimentally determined quantity
The order of a reaction is ALWAYS eqaul to the SUM of the stoichiometric COEFFICIENTS of reactants in the balanced chemical eqaution for a reaction.
The order of a reaction is the sum of the powers of molar concentration of the reactants in the REATE law expression

Solution :Here (C ) is not correct.
General reaction `xA+yBto`Products
Reaction rae =`k[A]^(x)[B]^(y)`
So x and y are order of reaction of A and B and (x+y) is the order of reaction .
23198.

Which of the following isa vinyl halide ?

Answer»

Chloroethene
1-chloro-3-phenylpropene
1-bromocyclohexene
All the above

SOLUTION :
23199.

Which represents correct difference for an ideal solution containing non-volatile solute ?

Answer»

<P>P ,Q , R
P , R
Q , R
P , Q

ANSWER :A
23200.

The smogis essentiallycaused by the presenceof :

Answer»

Oxidesis sulphurand NITROGEN
`O_(2)` and `N_(2)`
`O_(2)` and `O_(3)`
`O_(3)` and `N_(2)`

ANSWER :A