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23251.

Which of the following compounds has the highest boiling point?

Answer»

`CH_(3)CH_(2)CH_(2)Cl`
`CH_(3)CH_(2)CH_(2)CH_(2)Cl`
`CH_(3)CH(CH_(3))CH_(2)Cl`
`(CH_(3))_(3)C Cl`

Answer :B
23252.

Write the product of the following reaction

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ANSWER :`(##RES_CHM_CCAK_E01_002_A01##)`
23253.

What is the effect of increasing pH on K_(2)Cr_(2)O_(7) solution ?

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Solution :It changes from orange to yellow colour due to the FOLLOWING reaction :
`Cr_(2)O_(7)^(2-)+2OH^(-)to2CrO_(4)^(2-)+H_(2)O`
23254.

Which one of the following compounds will not given iodoform by the reaction with iodine and NaOH?

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Ethanol
Methanol
Acetaldehyde
Acetone

Answer :B
23255.

Which is the correct order of increasing energy of the listed orbitlas in the atom of titanium? (Atomic No. Z=22)

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3S 3p 3d 4s
3s 3p 4s 3d
3s 4s 3p 3d
4s 3s 3p 3d

Solution :Ti(22) = `1s^(2) 2s^(2) 2P^(6) 3s^(2) 3p^(6) 4s^(2) 3d^(2)`
order of ENERGY is 3s 3p 4s 3d
23256.

Which of the following is a natural polymer?

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Bakelite
Cellulose
`PVC`
Neoprene

Answer :B
23257.

What is the effect of temperature on the electrical conductance of electrolyte ?

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SOLUTION :TEMPERATURE INCREASES, ELECTRICAL CONDUCTANCE increases.
23258.

Which M-M bond has highest bond energy?

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`Sn-Sn`
`Ge-Ge`
`C-C`
`Si-Si`.

ANSWER :C
23259.

The semipermeable membrane used in Berkely -Hartley method is

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ANIMAL BLADDER membrane
copper phosphate
copper ferricyanide
Copper ferrocyanide

Answer :D
23260.

Which of the following is not a true statement about the detergents?

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Anionic detergents are sodium SALTS of sulphonatedlong CHAIN ALCOHOLS or hydrocarbons.
Cationicdetergents are quarternary ammonium salts of AMINES with acetates, chloridesor bromides as an ions.
Non-ionic detergents do not CONTAIN any ion in their constitution.
Detergents containingbranched hydrocarbons chains are biodegradable .

Solution :Detergents containing branched hydrocarbon chains are non-biodergradable.
23261.

Which chemical compounds to food cause slow activity of oxygen ?

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Preservatives
ANTIOXIDANTS
Food colours
Synthetic SWEETENER 

SOLUTION :Antioxidants
23262.

Zincile and colamine respectively are

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OXIDE and CARBONATE ore AL Zn
Carbonate and oxide ore of Zn
Oxide and sulphate or of Zn
Sulphate and SULPHITE gre of Zn

Answer :D
23263.

Which of the following will be the major product when is treated with dil. H_(2)SO_(4) in the presence of HgSO_(4) ?

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SOLUTION :
23264.

Which of the following compound has strong intermolecular Hydrogen bond ?

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METHYL HYDROXY BENZENE
PHENOL
Benzaldehyde
p-hydroxy benzaldehyde

Solution : Phenol
23265.

Three dimensional molecular structure with cross links are formed in the case of a

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THERMOPLASTIC
thermosetting plastic
Both (a) and (B)
NONE of the above

Solution :Thermosetting plastics have three dimensional cross linked STRUCTURE.
23266.

Which one of the following is an example for tranquilizer?

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CIMETIDINE
DIAZEPAM
histamine
PABA

SOLUTION :diazepam
23267.

Which of the folliwng compounds will show faster ArSN^(2) reactions?

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Solution :`ArSN^(2)` REACTIONS are favoured by STRONG `EWG, -I` EFFECT of `F` is highest (more `EN` of `F`)

23268.

The vapour pressure of liquid _____ with rise of temperature .

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SOLUTION :ATMOSPHERIC PRESSURE.
23269.

Whichformoftheiron isthepurest form of commercialiron ?

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Solution :Wroughiron isthepurestform ofcommercialiron. It containsabout` 0*2 - 0*5% ` carbonbesidestracescarbonbesidestracesofPandSi in FORMOF SLAG. Carbonin wroughironis presentpartlyas graphiteand partlyascementile,` Fe_ 3C`.
23270.

Which of the following is most electronegative?

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O
S
TE
Se

Solution :`{:(,"ELEMENT",O,S,SC,Te,PO),(,"ELECTRONEGATIVITY",3.5,2.5,2.4,2.1,2.0):}`
23271.

Which of the following is not a chlorinated insecticide ?

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DDT
Methoxychlor
Parathion
BHC

Answer :C
23272.

Which of the following has less bond enthalpy ?

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`CH_(3)-I`
`CH_(3)-F`
`CH_(3)-CL`
`CH_(3)-Br`

ANSWER :A
23273.

Which has highest boiling point under point under 1 atm pressue ?

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0.1 M NACI
0.1 M Scurose
0.1 M `BaCI_(2)`
0.1 M Glucose.

SOLUTION :0.1 M `BaCI_(2)` because it will form maximum ions (3) in solution
`Deltat_(b)=iKbm`
23274.

Write the structure of trans isomer of [Co(NH_3)_4CI_2]^-.

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SOLUTION :
23275.

Which of the following rate laws has an overall order of 0.5 for reactioninvolving substances x , y and z

Answer»

Rate = `K (C_(x)) (C_(y)) (C_(z))`
Rate = `K (C_(x))^(0.5) (C_(y))^(0.5) (C_(z))^(0.5)`
Rate = `K(C_(x))^(1.5) (C_(y))^(-1) (C_(z))^(0)`
Rate = `K(C_(x)) (C_(z))^(n) // (C_(y))^(2)`

SOLUTION :Order of REACTION is SUM of the power raised on concentration terms to EXPRESS rate expression.
23276.

Which of the following is chemical twins ?

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Zr and TA
Nb and W
Ta and Nb
Tc and Os

ANSWER :C
23277.

Which kind of isomerism is exhibited by octahedral [Co(NH_(3))_(2)Br_(2)]Cl ?

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GEOMETRICAL and ionization
Geometrical and optical
Optical and ionization
Geometrical only

Answer :A
23278.

Which compound not reacts with phenol ?

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`Na_(2)CO_(3)`
`NaHCO_(3)`
(A) and (B) both
NaOH

Answer :C
23279.

Which of the following reaction of xenon compounds is not feasible ?

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`XeO_(3)+6HF RARR XeF_(6)+3H_(2)O`
`3XeF_(4)+6H_(2)Orarr 2Xe+XeO_(3)+12HF+1.5O_(2)`
`2XeF_(2)+2H_(2)Orarr 2Xe+4HF+O_(2)`
`XeF_(6)+RbF rarr Rb[XeF_(7)].`

Solution :The REACTION is not feasible because `XeF_(6)` formed is readily hydrolysed to give `XeO_(3)`.
`XeF_(6)+3H_(2)Orarr XeO_(3)+6HF`
23280.

There are four alcohols P,Q,R and S which have 3,2,1 and zero alpha hydrogen atom (s) respectively. Which on of the following will give an alkene when heated with copper

Answer»

<P>P
Q
R
S

ANSWER :D
23281.

When an ideal diatomic has is heated at constant pressure the fraction of the heat energy supplied which oncreases the internal energy of the gas is :

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2/5
3/5
3/7
5/7

Answer :D
23282.

The resistance of 0.5 N solution of an electrolyte in a conductivity cell was found to be 45 ohms. If the electrodes in the cell are 2.2 cm apart and have an area of 3.8 cm^2then the equivalent conductance (in Scm^2 eq^(-1) ) of a solution is

Answer»

25.73
15.75
30.75
35.75

Answer :A
23283.

Which among the following is an intensive property?

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Enthalpy
Entropy
Gibbs FREE energy
Pressure

Answer :B
23284.

When alkyl halide is heated with dry Ag_(2)O,it produces

Answer»

ester
ether
ketone
alcohol

Answer :B
23285.

Which of the following compounds will give haloform test?

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`CH_(3)COCH_(2)l`
`CH_(3)-CHCl-CH_(3)`
`C_(6)H_(5)COCH_(3)`
`CH_(3)CH_(2)Br`

Solution :`CH_(3)COCH_(2)lunderset(NaOH)overset(l_(2))toCH_(3)`
`C_(6)H_(6)COCH_(3)underset(NaOH)overset(l_(2))toCHl_(3)`
Under the basic conditions of the REACTION, both `CH_(3)CHClCH_(3)andCH_(3)CH_(2)Br` will further undergo hydrolysis to GIVE `CH_(3)CHOHCH_(3)andCH_(3)CH_(2)OH` respectively which will give iodoform test.
23286.

Which one of the following chlorides will not fume in air?

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`BiCl_(3)`
`C Cl_(4)`
`PCl_(5)`
NONE of these.

Answer :B
23287.

When a gas is bubbled through water at 298 K, a very dilute solution of the gas is obtained. Henry's law constant for the gas at 298 K is 100 kbar. If the gas exerts a partial pressure of 1 bar, the number of millimoles of the gas dissolved in one litre of water is

Answer»

`0.555`
`5.55`
`0.0555`
`55.5`

SOLUTION :`k_(H)` = 100 kbar, p = 1 bar
`p=k_(H)xx` mole fraction
Mole fraction `=(p)/(k_(H))=(1)/(100xx10^(3))=10^(-5)`
Mole fraction `=("Mole of gas")/("Total moles")`
Moles of water `=("Weight of water")/("MOLECULAR weight of water")`
Weight of water= 1000g `(because 1000 mL = 1000g)`
Moles `=(1000)/(18)=55.5`
Mole fraction `= 10^(-5)=(x)/(55.5+x)`
As `55.5 gt gt gt x`, thus neglecting x from denominator
`10^(-5)=(x)/(55.5)rArr x = 55.5xx10^(-5)` moles
or `55.5xx10^(-2)` millimoles = 0.555 millimoles.
23288.

Which element among the lanthanides has the smallest atomic radius

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Cerium
Lutetium
Europium
Gadolinium

Answer :B
23289.

Which one of the following compounds is different from the rest in terms of undergoing hydrolysis to form simpler compounds?

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Sucrose
Maltose
Lactose
Glucose

Answer :D
23290.

When a substabce is dissolved in a solvent, the vapour pressure of solvent decresases. This brings:

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An INCREASE in b.pt. of the solution
A DECREASE in b.pt. of a solution
An increase in f.pt. of the solvent
None

Answer :A
23291.

What is the correct order of rectivity of alchohols in the following reaction ?

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`1^@ GT 2^@ gt 3^@`
`1^@ LT 2^@ gt 3^@ `
`3^@ gt 2^@ gt 1^@`
`3^@ lt 2^@ lt 1^@`

ANSWER :C
23292.

Which of the element of oxygen family is most poisonous to human race

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O
S
SE
NONE

ANSWER :C
23293.

Which of the following processes involves the roasting process ?

Answer»

`ZncO_3 RARR ZNO + CO_2`
`Fe_2O_3 + 3C rarr 2FE _ 3CO`
`2PbS + 3O_2 rarr 2PbO + 2SO_2`
`Al_2O_3 cdot2H_2O rarr Al_2O_3 + 2H_2O`

Answer :C
23294.

What happens when electric field is applied to colloidal solution ?

Answer»

SOLUTION :The charged COLLOIDAL particles MOVE towards oppositely charged ELECTRODES.
23295.

Which one of the following is a positively charged colloid?

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AG
AU
BASIC DYES
Clay

Solution : Basic dyes
23296.

Which of the statement is not true -

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`K_(2)Cr_(2)O_(7)` solution in acidic medium is ORANGE
`K_(2)Cr_(2)O_(7)` solution becomes yellow on increasing the PH beyond 7
on PASSING `H_(2)S` through acidified `K_(2)Cr_(2)O_(7)` solution, a milky colour PREFERRED over `K_(2)Cr_(2)O_(7)` in volmetric analysis

Solution :`Na_(2)Cr_(2)O_(7)` is hydrophilic in nature and hence `K_(2)Cr_(2)O_(7)` is more appropriate in volumetric analysis.
23297.

Which of the following is an optically active compound ?

Answer»

GLYCINE
Lysine
Isoleucine
ASPARTIC acid

Answer :A
23298.

Which of the following shall form an octahedral complex ?

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`d^(4)` (LOW spin)
`d^(8)` (high spin)
`d^(6)` (low spin)
All of these

Solution :In `d^(6)` (low spin), electrons PAIR up thereby making two empty d-orbitals available for `d^(2)sp^(3)` hybridisation as in the CASE of `[FE(CN)_(6)]^(4-)`
23299.

What are sulpha drugs? Give two examples.

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SOLUTION : A group of drugs which are derivatives of sulphanilamide and are used in PLACE of antibiotics are called sulpha drugs.
EG.: Sulphadizine, Sulphanilamide.
23300.

Why are carbohydrates generally optically active ?

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SOLUTION :Carbohydrates have chiral carbon ATOM and they do not have PLANE of SYMMETRY.