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26451.

The outermost electronic configuration of the most electronegative element is

Answer»

`3s^(2)3p^(5)`
`6s^(1)`
`2S^(2)2P^(5)`
`2s^(2)2p^(4)`

ANSWER :C
26452.

The outer electronic configuration of 15 group

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`ns^2 np^1`
`ns^2 np^2`
`ns^2 np^3`
`ns^2 np^4`

ANSWER :C
26453.

The outermost electronic confi-guration of transition metal is

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`ns^2np^3`
`ns^2np^6`
`ns^2np^5`
`(n-1)d^(1-10)ns^2`

ANSWER :D
26454.

The outer shell of an egg was dissolved in hydrochloric acid and than placed in concentrated NaCI solution. Which one of the following will happen ?

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The egg will swell
The egg will shrink
Nothing will happen to the egg
The INSIDE of the egg will BECOME SALTISH .

SOLUTION :Endoosmosis
26455.

The outermost electron is most loosely held in:

Answer»

Li
Na
K
Cs

Answer :D
26456.

The outer shell electronic configuration of palladium (Z=46) is

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`4d^(8)5s^(2)`
`4d^(9)5s^(2)`
`4d^(10) 5s^(0)`
`4d^(2)5s^(2)5P^(6)`

Solution :`15200cm^(-1)(Z^(2))=15200xx(3)^(2) `
`=136800cm^(-1)`
26457.

The outermost elecronic configuration of most electronegative element is :

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`ns^2np^3`
`ns^2np^4`
`ns^2np^5`
`ns^2np^6`

ANSWER :C
26458.

The outer electronic configurations of two transition metals are (i) 3d^(5)4s^(2) and (ii) 3d^(6)4s^(2) respectively. Based on this information predict the relative stability of +2 and +3 oxidation state of these metals. Which of the two exhibits larger number of oxidation states ?

Answer»

Solution :Metal with configuration `3d^(5)4s^(2)` will show oxidation state (+2) more readily because of greater STABILITY of half-filled d-orbitals. Metal with configuration `3d^(6)4s^(2)` will be more stable in +3 oxidation state than +2 due because after losing two ELECTRONS the configuration of the metal ION will be `3d^(5)`, which is a stable configuration.
26459.

The outer electronic configuration of two members of the lanthanoid series are as follows : 4f^(1) 5d^(1) 6s^(2) and 4f^(7) 5d^(-) 6s^(2) What are their atomic numbers ? Predict the oxidation states exhibited by these elements in their compounds.

Answer»

Solution :Complte E.C. of 1ST lanthanoid `= [Xe]^(54) 4f^(1) 5d^(1) 6 s^(1) `. Atomic No. ` = 58 (C e) `
COMPLETE E.C. of 2nd lanthanoid `= [ Xe]^(54) 4f^(7) 5d^(0) 6s^(2)` . Atomic No. `=63 (E u)`
OXIDATIO states of 1st lanthanoid `= + 2 ( 4f^(2)) , + 3( 4f^(1)) , + 4 ( 4f^(0))`
Oxidation states of 2nd lanthanoid ` = +2 (4f^(7)) ` and `+ 3 ( 4f^(6))`
26460.

The outer shell configuration of a halide ion is

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`ns^2`
`ns^2 np^6`
`ns^2 np^5`
`ns^2 np^4`

ANSWER :B
26461.

The outer electronic structure of lawrencium (atomic number 103) is:

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`Rn5f^(13)7S^(2)7p^(2)`
`Rnf^(13)6d^(1)7s^(1)7p^(2)`
`Rn5f^(14)7s^(1)7p^(1)`
`Rn5f^(14)6d^(1)7s^(2)`

Answer :D
26462.

The outer electronic configuration of Gd (Atomic No:64) is :

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`4F^(4) 5D^(4) 6s^(2)`
`4f^(7) 5d^(1) 6s^(2)`
`4f^(3) 5d^(5) 6s^(2)`
`4f^(6)5d^(0) 6s^(2)`

Solution :`Gd : [Xe] 4f^(7) 5d^(1) 6s^(2)`
26463.

The outer electronic configuration of Gd (Atomic no. 64) is…..

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`4f^(3) 5D^(5) 6s^(2)`
`4f^(6) 5d^(0) 6s^(2)`
`4f^(4) 5d^(4) 6s^(2)`
`4f^(7) 5d^(1) 6s^(2)`

ANSWER :D
26464.

The outer electronic configuration of alkaline earth metal is

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`ns^(2)`
`ns^(1)`
`NP^(6)`
`ND^(10)`

ANSWER :A
26465.

The outer elecftronic configuration of plutonium in +6 oxidatino state is

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`7S^(0), 5F^(5), 6d^(0)`
`7s^(0), 5f^(1), 6d^(0)`
`7s^(0), 5f^(2), 6d^(0)`
`7s^(0), 5f^(4), 6d^(0)`

ANSWER :C
26466.

The other name of 1, 2, 3-trihydroxy benzene is …………………….. .

Answer»

SOLUTION :PYROGALLOL
26467.

The Ostwald process is the main method for the manufacture of nitric acid. In the first step in this process

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nitrogen and HYDROGEN REACT to FORM `NH3`
ammonia is BURNED in `O_2` to generate `N_2 and H_2O`
nitrogen and OXYGEN react to form `NO_2`
ammonia is burned with `O_2` to generate `NO and H_(2)O`

Answer :D
26468.

The othernameof glucose is ………. .

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DEXTROSE
BLOOD sugar
aldohexoe
all the above

ANSWER :D
26469.

The other name of fructoseis ………… .

Answer»

KETOHEXOSE
FRUIT SUGAR
LEVULOSE
all the above

ANSWER :D
26470.

The number of signiicant figures in piare

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1
2
3
infinite

Answer :D
26471.

The other name of 3,5-dihydroxy toluene is known as …………………. .

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ORCINOL
QUINOL
PYROGALLOL
RESORCINOL

SOLUTION :Orcinol
26472.

The other name of 1,2,3-trihydroxy benzene is called ……………………. .

Answer»

Pholoroglucinol
QUINOL
PYROGALLOL
HYDROXY quinol

SOLUTION :Pyrogallol
26473.

The number of silver atoms present in a 90% pure silver wire weighing 10 g is :

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`5.57 xx 10^22`
`0.62 xx 10^23`
`5.0 xx 10^22`
`6.2 xx 10^29`

Solution :Amount of PURE SILVER in 10g wire
` = 10 xx 90/100 = 9g `
108 g of Ag contain ATOMS =`6 xx 10^23`
9g of Ag contain atoms
` = (6 xx 10^23)/(108) xx 9= 5 xx 10^22`
26474.

The osmotic presure of a urea solution is 500 mm of Hg at 10^(@)C. The solution is diluted and its temperature is reised to 25^(@)C. It is now found that the osmotic pressure of the solution is reduced to 105.3 mm. Detyermine the extrant of dilution of the solution.

Answer»


Solution :According to Van't Hoff equation for dilute solution.
`piV=n_(B)RT or pi=(n_(B)RT)/V`
`At 10^(@)C:""pi=((500MM))/((750mm))xx(1"atm")=500/760"atm",T=10+273=233=283 K`
`(500/760"atm")=(n_(B)xxRxx283K)/V`
`At20^(@)C:""pi=(10.5.3mm)/(760mm)xx1(atm)=105.3/760("atm"),T=20+273=293K`
`((105.3)/760"atm")=(n_(B)xxRxx293K)/V'`
`"Dividing eqn. (i) by eqn.(II),"(500/760"atm")xx(760/105.3"atm"^(-1))=((283K))/Vxx(V')/((293K)`
`(V')/V=500/105.3xx((293K))/((283K))=4.92~~5.`
V'=5V
This means that the solution has been diluted five times.
26475.

The number of significant zeros in 0.001010 is :

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two
three
four
one

ANSWER :A
26476.

The osmotic pressure (pi) of a solution is given by reation

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<P>`pi = (RT)/C`
`pi = (CT)/R`
`pi = (RC)/T`
`pi/C =RT`

Solution :PV = N RT `:. P = n/v RT = CRT.`
26477.

The number of significant figures present in 0.0200 is ………………whereas number of significant figures in a dozen (12) is………………… .

Answer»

SOLUTION :3, INFINITE
26478.

The osmotic pressure (P) of a solution is given by relation:

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<P>`P= (RT)/( C ) `
`P= (CT)/( R ) `
`P= (RC)/( T ) `
`(P) / ( C )= RT`

Answer :D
26479.

The osmotic pressure of which solution is maximum (consider that deci-molar solution of each 90% dissociated)

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Aluminium sulphate
Barium chloride
Sodium sulphate
A MIXTURE of equal VOLUMES of (b) and (c )

Solution :`Al_(2)(SO_(4))_(3)` gives maximum osmotic PRESSURE because it gives 5 IONS.
26480.

The number of significant figures in piare:

Answer»

three
Infinite number
zero
one

Answer :B
26481.

The osmotic pressure of which solution is maximum ( consider that deci-molar solution of each 90% dissociated )

Answer»

Aluminium sulphate
Barium chloride
Sodium Sulphate
A MIXTURE of equal volumes of ( B ) and ( c )

Solution :`Al_(2)(SO_(4))_(3) rarr2Al^(+++) +3SO_(4)^(--) ` ( 5 particles )
`BaCl_(2) rarr BA^(++) +2Cl^(-) ` ( 3 particles )
`Na_(2) SO(4) rarr 2Na^(+) +SO_(4)^(--) ` ( 3 particles )
A mixture of equal volumes.
26482.

The number of significant figures in the final answer of : (( 16.8 -14.2) ( 6.023 xx 10^(23)))/(2.76)is :

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2
3
1
4

Answer :A
26483.

The osmotic pressure of the solution obtained by mixing 200 "cm"^3 of 2% (mass-volume) solution of urea with 200 "cm"^3 of 3.42% solution of sucrose at 20^@C is

Answer»

4 BAR
1.2 bar
5.2 bar
2.60 bar

ANSWER :C
26484.

The number of significant figures in 6.02xx10^(23) is

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23
3
4
26

Answer :B
26485.

The Osmotic pressure of solution containing 4.0g of solute (molar mass 246) per litre at 27^@C is (R = 0.082L atm "k"^(-1) "mol"^(-1))

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`0.1 ATM`
`0.2 atm`
`0.4 atm`
`0.8 atm`

ANSWER :C
26486.

The osmotic pressure of equimolar solutions of glucose, KCI, MgC12 follows the order

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`MgCl_2 GT KCI gt GLUCOSE`
`Glucose gt KCI gt MgCl_2`
`KCI gt MgCl_2 gt Glucose`
`MgCl_2 gt Glucose gtKCl`

ANSWER :A
26487.

The number of significant figures for the three numbers 161 cm, 0.161 cm, 0.0161 cm are

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3, 4 and 5 respectively
3, 4 and 4 respectively
3, 3 and 4 respectively
3, 3 and 3 respectively

Solution :We know that all non-zero digits are significant and the ZEROS at the beginning of a number are not significant. THEREFORE number 161 cm, 0.161 cm and 0.0161 cm have 3, 3 and 3 significant FIGURES respectively.
26488.

The osmotic pressure of equimolar solutions of glucose, sodium chloride and barium chloride will be in the order :

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`BaCl_(2) GT NaCl gt ` glucose
`BaCl_(2) gt` glucose `gt` NaCl
Glucose `gt BaCl_(2) gt NaCl`
`NaCl gt BaCl_(2) gt` glucose

Solution :Osmotic PRESSURE DEPENDS upon the number of particles given by solute. Glucose remains undissociated, SODIUM chloride gives `(NA^(+)+Cl^(-))^(2)` mole particlesper mole and barium chloride gives `(Ba^(2+), 2Cl^(-))`3 mole particles pre mole. Therefore, correct order is A.
26489.

The osmotic pressure of equimolar solutions of following solutes have been measured. Which of these show minimum osmotic pressure ?

Answer»

`MgCl_(2)`
KCL
`(NH_(4))_(3)PO_(4)`
Sucrose

SOLUTION :Sucrose does not ionize in solution.
26490.

The number of significant figures in 1.00 xx 10^6 is:

Answer»

one
three
eight
eleven

ANSWER :B
26491.

The osmotic pressure of equimolar solutions of BaCl_2, NaCl and glucose follow the order:

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`BaCl_2` > NACL > GLUCOSE
Glucose > NaCl > `BaCl_2`
NaCl > `BaCl_2` > glucose
NaCl > glucose > `BaCl_2`

ANSWER :A
26492.

The number of significant figures in (0.04)^2 + (0.25)^2is :

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one
two
three
four

Solution :`(0.04)^2+ (0.25)^2 = 0.0016 + 0.0625 = 2 XX 10^(-3) + 62 + 10^(-3)`
(up to correct significant figures)
` = 64 xx 10^(-3)`
Number of significant figures = 2
26493.

The osmotic pressure of decimolar solution of glucose at 30^(@)C is :

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24.88 atm
2.488 atm
248.8 atm
2488 atm

Solution :`C.RT = 0.1 XX 0.082 xx 303 = 2.488`
26494.

The osmotic pressure of decimolar solution of glucose at 30^@C is:

Answer»

24.88 atm
2.488 atm
248.8 atm
None

Answer :B
26495.

The number of significant figures in 0.0230 is :

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2
3
4
5

Answer :B
26496.

The osmotic pressure of an aqueous solution containing 45g of sucrose (343) per litre of solution is 2.97 atm at 0^(@)C. Find the value of the gas constant and compare the result with the accepted value.

Answer»


ANSWER :`0.086`lit.atm/K/mole
26497.

The number of significant figure in 60.001 are

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5
6
3
2

Solution :All the ZEROES between two non ZERO digit are SIGNIFICANT. Hence in 60.0001 significant figures is 6.
26498.

The osmotic pressure of blood is 8.21 atm at 37^(@)C. How much glucose would be used for an injection that is at the same osmotic pressure as blood?

Answer»


Solution :`"MOLAR conc. of GLYCERINE "=10.2//M" (M = mol. mass)"`
`"Molar conc. of GLUCOSE "=(2)/(180)xx(1)/(100)xx1000="0.111 mol L"^(-1)""THEREFORE""(10.2)/(M_(2))=0.111"or"M_(2)=91.9"g mol"^(-1)`.
26499.

The number of sigma bonds in Zeise's salt is :

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4
6
7
none of these

Solution :In `C_(2)H_(4)` itself 5 `delta`-bonds are PRESENT. Apart from this, metal has `delta`-co-ordination from 3`CL^(-)` ligands and `delta`-co-ordination from `pi-C_(2)H_(4)`.
`K[PtCl_(3)(C_(2)H_(4))]`
26500.

The osmotic pressure of an aqueous solution of sucrose is 2.47 atm at 303 K and the molar volume of the water present in solution is 18.10cm^(3). Calculate the elevation of boiling point of this solution. Given Delta H_("vap") = 540 cal//g. Assume volume solvent equal to volume of solution.

Answer»


ANSWER :`5.145 XX 10^(-2)` ;