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2801.

Which of the following is not a fatty acid

Answer»

Propionic ACID
OXALIC acid
Valeric acid
STEARIC acid

ANSWER :B
2802.

When 1.0 xx 10^(-5) mg of a protective colloid is added to 20 ml of standard gold sol, the precipitation of gold sol was prevented by adding 5 ml of 10% solution of NaCl. If the gold number of protective colloid is 2.0 x 10^(-x) mg then x is = __?

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SOLUTION :`20 rarr 1 xx 10^(-5) MG , 10 ml rarr ? `
`(10^(-5) xx 10)/(20) = 0.5 xx 10^(-5) , 5 ml to 0.5 xx 10^(-5) , 1 rarr ? , 0.1 xx 10^(-5) = 1 xx 10^(-6)`.
2803.

Write the overall reaction in nickel-cadmium cell during discharge.

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Solution :`CD(s) + 2Ni(OH)_(3)(g) to CdO (s) + H_(2)O(l)`
2804.

Whichof the following is the energy of a possible excited state of hydrogen?

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`+13.6eV`
`-6.8eV`
`-3.4eV`
`+638eV`

Solution :ENERGY of excited state is negative and corresponds to n more THAN1 for hydrogen.
`E=-(13.6Z^(2))/(n^(2))eV`
Z=1, FIRST excited state n=2
`:.E=-3.6/(2^(2))=-3.4eV`
2805.

Which reagent mixture is used in Lucas test?

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Anhydrous `AICI_(3)`
Anhydrous `ZnCl_(2)` + CONC. HCL
Anhydrous `ZnCl_(2)` + Conc. `HNO_(3)`
Anhydrous `ZnCl_(2) + H_(2)SO_(4)`

Solution : Anhydrous `ZnCl_(2)` + Conc. HCl
2806.

Which of the following diagrams us correctly related to different steps involved in the extraction of Zn from zinc blende ore?

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Both`(a)`and`(b)`
None of these

Solution :• Concentration `RARR` The ore is concentated forst by gravity method and then by froth floatation process.
• Rasting `rarr` Concentated ore is then roasted at `900^(@)-1000^(@)C` to convert `ZnS` and `ZnSO_(4)`to `ZNO`.
• Readuction of ckoe `rarr` The oxide `ZnO` is reduced with coke at about `1500^(@)C` to obtain metallic zinc.
• Electrolytic refining `rarr` Pure zinc is obtained by electrolysis zinc in presence of ACIDIFIED `ZnSO_(4)` as ELECTROLYTE.
2807.

Which one is bronstad acid but not a bronstad base?

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`H_2O`
`NH_3`
`H_2S`
`HCO_3^-`

ANSWER :C
2808.

Which of the following is an antacid

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A only
B only
C only
All

ANSWER :D
2809.

Write partial structure of the following polymer.Teflon

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SOLUTION :`[--CF_2 - CF_2--]_n`
2810.

Which of the following is placed above the pure mercury in calomel electrode ?

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Hg+KCl
Hg+NaCl
`Hg+Hg_(2)Cl_(2)`
`Hg+MgCl_(2)`

SOLUTION :`Hg_2Cl_2` SALT is known as CALOMEL.
2811.

Which reaction producese SO_(2)

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`2Na_(2)S_(5)+3O_(2)overset(DELTA)underset(air)rarr`
`2Na_(2)SO_(3)+underset("excess")Soverset(Delta)rarr`
`Na_(2)S_(2)O_(3)+2HCl"(DIL)"`
`Na_(2)S_(2)O_(3)+Cl_(2)+H_(2)Orarr`

Answer :C
2812.

Which of the following has the small size ?

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`CL^-`
Cl
`O^(2-)`

ANSWER :C
2813.

Which of the following undergoes hydrolysis when dissolved in water

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`CH_(3)COONa`
`CH_(3)CONH_(2)`
Both (a) and (B)
`C_(6)H_(5)CH_(3)`

ANSWER :C
2814.

Which one of the following is found in alkenes ?

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CHAIN isomerism
Geometrical isomerism
Metamerism
Position isomerism

Answer :C
2815.

When nitrobezene is treated with Br_2 in the presence ofFeBr_2 the major product formed is m-bromonitro-benzene . Statements which are related to obtatining the m-isomer are :

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The electron densitty on meta-carbon is more than that on ortho-and para -positons
The intemediate CARBONIUM ion formed after intial attakc of ` Br^(o+)` at the meta-position is LEAST destabnilise
Loss of aromaticity when ` Br^(o+)` attacks at the orth- and para -POSITIONS and not at meta-position.
Easier loss of ` H^(o+)` to regain aromaticity from the meta-position than FROMM the ortho- and para-positions

Solution :` (##KSV_CHM_ORG_P2_C15_E01_158_S01.png" width="80%">
2816.

The standard reduction potential values of three metallic cations, X,Y, and Z are 0.52,-3.03, and -0.18V, respectively. The order of reducing power of the corresponding metal is

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`YgtZgtX`
`XgtYgtZ`
`ZGTYGTX`
`ZgtXgtY`

ANSWER :A
2817.

Which will reduce acidified potassium dichromate solution?

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POTASH alum
Mohr's salt
Chile saltpetre
White vitriol

Answer :B
2818.

Which of the following reagents is used to convert - COOH group to CH_(3) group ?

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<P>Red P and HI
`LiAlH_(4)`
`Na,C_(2)H_(5)OH`
`Zn+HCl`.

Answer :A
2819.

What products are obtained in the electrolysis of fused KCl and aqueous solution of KCl between platinu electrodes ?

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ANSWER :
2820.

Which of the following is/are a surfactant?

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DETERGENTS
SOAPS
Syndect
SODIUM PROPIONATE

Solution :sodium propionate is not SOAP
2821.

Which of the following is incorrect about NaCl structure ?

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NEAREST neighbours of `Na^(+)` ion is SIX `Cl^(–)` ion
`Na^(+)` ion make FCC lattice
`Cl^(–)` ion PACK in cubic close packed ARRANGEMENT
There are eight next nearest neighbours of`Na^(+)` ion

Answer :D
2822.

Write the chemical equations for one example of each of the following : (a) Coupling reaction""(b) Hoffmann's bromamide reaction (c) Acetylation.

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Solution :(a) Coupling reaction :

(B) Hoffmann.s bromamide reaction :
`underset("ETHANAMIDE")(CH_(3)-overset(overset(O)(||))(C)-NH_(2))+Br_(2)+4KOH rarr underset("Methanamine")(CH_(3)NH_(2))+K_(2)CO_(3)+2KBr+2H_(2)O`
(c) Acetylation :
When ANILINE reacts with acetyl chloride in the presence of NaOH, we get acetanilide. This process is called acetylation.
2823.

When a primary amine reacts with chloroform and ethanolic KOH, then the product formed is

Answer»

isocyanide
aldehyde
cyanide
alcohol

Solution :CARBYLAMINE REACTION YIELDS ISOCYANIDES.
2824.

Which of the following is not an ore of aluminium ?

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Anglesite
Mica
Beryl
Orthoclass.

Solution :Anglesite (PBS) is an ORE of LEAD while all OTHERS are the ores of aluminium.
2825.

Which statement (s) is (are) correct?

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Electrons in motion behave as if they are waves
s-orbital is non-directional
An orbital can ACCOMMODATE a MAXIMUM of two electrons with PARALLEL spins
The energies of the various sub LEVELS in the same shelll are in ORDER `sgtpgtdgtf`

Answer :A::C
2826.

Which halogen shows only one oxidation state ?

Answer»

F
Cl
Br
I

Answer :A
2827.

When H_(2)S gas is passed into a certain solution, it reacts to form a white precipitate. The solution referred to contains ions of

Answer»

Lead
Zinc
Copper
Nickel

Solution :ZNS is WHITE.
2828.

Which of the following is not present in DNA ?

Answer»

Adenine
Guanine
Uracil
Thymine.

ANSWER :C
2829.

What is the effect on AH and AS during the process of adsorption?

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SOLUTION :Both `DELTAH and DELTAS ` DECREASES (DeltaH `= -ve and `DeltaS = -ve`)
2830.

Which of the following are correct methods for the preparation of propanoic acid ?

Answer»

`H_(3)C-CH=CH_(2)OVERSET(HBr)rarroverset(Mg)underset(Ether)rarroverset(CO_(2))underset(H_(3)^(OPLUS)O)rarr`
`H_(3)C-C-=CHoverset(BH_(3).THF)underset(H_(2)O_(2),.^(Θ)OH)rarroverset(KMnO_(4))rarr`
`H_(2)C=CH_(2)overset(HBr)rarroverset(Mg)underset(Ether)rarroverset(CO_(2))underset(H_(3)^(oplus)O)rarr`
`H_(3)C-CH=underset(CH_(3))underset(|)C-CH_(3)overset(O_(3))underset(Ag_(2)O)rarr`

Answer :B::C
2831.

What are the colours of the following sulphides ? (i) CoS (ii) CuS (iii) MnS (iv) CdS.

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Solution :(i) Black (ii) Black (III) FLESH coloured (IV) Yellow
2832.

XeF_6 + 2H_2Oto .......... + HF

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`XeO_(2)F_(2)`
`XeOF_(2)`
`XeO_(3)`
`XeOF_(4)`

ANSWER :A
2833.

Which one of the following is an example for water in oil emulsion?

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Milk
Vanishing cream
BUTTER
Soap

Solution :Butter
2834.

When electrons are trapped into the crystal in anion vacancy, the defect is known as

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Schottky defect
Frenkel defect
Stoichiometric defect
F-centre

Solution :When ELECTRONS are TRAPPED in anion VACANCIES, these are CALLED F-centre
2835.

To prepare tert -butyl ethyl ether by Williamson synthesis, the reactants needed are

Answer»

Sodium ethoxide and sodium TERT butoxide
Sodium ethoxide and tert -BUTYL bromide
Sodium tert-butoxide and ETHY1 bromide
ETHYL ALCOHOL and tert -butyl alcohol

Answer :C
2836.

Which one of the following reacts with concentrated sulphuric acid

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Au
Ag
Pt
Pb

Solution :`2Ag+2H_(2)SO_(4)rarrAg_(2)SO_(4)+SO_(2)+2H_(2)O`
`Pb+2H_(2)SO_(3)rarrPbSO_(4)+SO_(2)+2H_(2)O`
2837.

The structure of BF_3 is :

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Tetrahedral
Pyramidal
Trigonal
None of the above

Answer :C
2838.

Why adenine always pairs with thymine and guanine with cytosine ?

Answer»

Solution :Adenine can FORM two hydrogen BOND with THYMINE and Guanine FORMS three hydrogen bonds with cytosine.
2839.

What is vulcanization of rubber ?

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Solution :During vulcanization, natural ID heated with `3-5%` sulphur . The FUNCTION of sulphur is to introduce sulphur (or disulphide) bridges or cross-links between polymer chainsthereby IMPARTING more tensile strength, elasticity and resistance to abrasion.
2840.

Two reactions proceed at 25^(@)C at the same rate . The temperature coefficient of the rate of first reaction is 2 and the that of second reaction is 2.5 . The ratio of rates of these reactions at 95^(@) C is :

Answer»

5.6
9.85
4.768
70

Solution :( C)
`:. (R_(2))/(R_(1))= ((2.5)^(7))/(2^(7))= 4.768`
2841.

Which of the following possesses highest melting point?

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Chlorobenzene
o-Dichlorobenzene
m-Dichlorobenzene
p-Dichlorobezene

Answer :D
2842.

Which of the following is true about the complex [PtCl_(2)(NH_(3))OH_(2)] ? [Atomic number of Pt=78] (P) It will have two geometrical isomeric forms, cis and trans (Q) The hybridisation state of Pt(II) is sp^(2) (R ) It is a square planar complex (S) It is a diamagnetic complex (T) It can show hydrate isomerism (U) It is tetrahedral complex

Answer»

<P>P, R, S
Q, S, T
Q, T, U
P,T,U

Solution : Diamagnetic , `dsp^(2)`
2843.

Whichof the followingis correct?

Answer»




SOLUTION :
2844.

Which of the following is not a target molecule for drug function in body ?Carbohydrates,Lipids,Vitamins,Proteins.

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Carbohydrates
Lipids
Vitamins
Proteins.

Answer :C
2845.

Thermal decomposition of a compound is of first order. If 50% of a sample of the compound is decomposed in 120 minutes how long will it take for 90% of the compound to decompose?

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`399` min
`410` min
`250` min
`120` min

Solution :First calculate the values of `K`
`K = (0.693)/(T_(1//2)) = (0.693)/(120) = 5.77 XX 10^(3) min-1`
Now we know that for a first order reaction
`K = (2.303)/(t) "log"((a)/(a-x))`
Here the initial CONCENTRATIION `a = 100` and `N = 90`
`:. 5.77 xx 10^(-3) = (2.303)/(t) "log"(100)/(100-90)`
`t = (2.303)/(5.77 xx 10^(-3))"log"((a)/(a-x))`
Solving,`t = 399` minute
2846.

The two compounds used as refrigerants are 1. NH_(3) 2. C Cl_(4) 3. CF_(2) 4. CF_(2) Cl_2

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1,2
2,3
1,3
1,4

Solution :1 and 4 Both can be LIQUEFIED EASILY.
2847.

What are the applications of the Ellingham diagram ?

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Solution :(i) Ellingham diagram helps us to select a suitable reducing agent and appropriate TEMPERATURE range for reduction.
(II) From the Ellingham diagram, we can infer the relative stability of different metal oxides at a GIVEN temperature.
(iii) Ellingham diagram is USED to predict thermodynamic feasibility of reduction of oxides of one metal by another metal.
2848.

Write the product of following reactions : (i) CH_(3)-C-=C-CH=CH_(2) overset(O_(3)//H_(2)O_(2))rarr, (ii) ,overset(O_(3)//H_(2)O_(2))rarr

Answer»


SOLUTION :`(i) CH_(3)-COOH+HOOC-COOH+HCOOH`""
2849.

Which of the following statements are correct ? (i) When an animal hide, which has negatively charged particles , is soaked in tannin, which contains positively charged colloidal particles, mutual coagulation does not take place. (ii) Photographic films are prepared by coating an emulsion of the light sensitive silver bromide in gelatin over glass plates or celluloid films. (iii) Latex is a colloidal solution of rubber particles which are negatively charged. (iv) In Cottrell precipitator , the smoke , before it comes out from the chimney, is led through a chamber containing plates having a charge opposite to that carried by smoke particles. The particles on coming in contact with these plates acquire some charge and do not get precipitated .

Answer»

(i) and (IV) only
(II) and (III) only
(ii), (iii) and (iv) only
All of these.

Answer :B
2850.

Which one of the following statements is not true regarding cellulose ?

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It is a colourless amorphous SOLID 
It is a branched chain polysaccharide 
It does not REDUCE the Tollen's reagent 
It contains `beta-1,4-` glycosidic linkages between glucose units. 

ANSWER :B