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29551.

The IUPA name of the following compounds is: CH_(3)-overset(O)overset(||)(C)-CH_(2)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-CN

Answer»

4-cyano-4-methyl-2-oxopentane
2-cyano-2-methyl-4-oxopentane
2,2-dimethyl-4-oxopentanenitrie
4-cyano-4-methyl-2-pentanone

ANSWER :C
29552.

The isotopic mass of ""_(92)^(238)U is 238.125 a.m.u. Its packing fraction is :

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5.25
0.125
12.5
1.25

Answer :A
29553.

The isotopic abundance of C-12 and C-14 is 98% and 2% respectively : What would be the number of C-14 isotope in 12 g carbon sample :

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`1.032 XX 10^22`
`3.01 xx 10^23`
`5.88 xx 10^23`
`6.02 xx 10^23`

ANSWER :A
29554.

The isotopes .^(238)U and .^(235)U occur in nature in the mass ratio 140 : 1. it is assumed that intially they were found in equal mass. If half life (t_(1//2)) of .^(238)U=4.5xx10^(9) and t_(1//2) of .^(235)Uxx10^(8)years respectively then the age of earth is (log 7=0.846,log2=0.3)

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`4.02xx10^(9)` YEAR
`2.01xx10^(9)` year
`8.72xx10^(9)` year
none of these

ANSWER :A
29555.

The industrial preperation of chloroform employs acetone and :

Answer»

SODIUM chloride
chlorine gas
Calcium hypochlorite
Phosgene

Answer :C
29556.

The isotopes of elements were discovered by :

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Soddy
Curie
Chadwick
Thomson.

Answer :D
29557.

The isotope .^(14)C undergoes radioactive decay slowly. Which mode of decay is most likey?

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ALPHA emission
Beta emission
Positron emission
Electron CAPTURE

ANSWER :B
29558.

The isotope ""_(92)^(235) U decays in a number of steps to an isotope of ""_(87)^(207)Pb. The no of particles emitted in this process will be :

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`4 ALPHA`
`6 beta`
`7 alpha`
`4 beta`

Solution :`""_(92)U^(235) to ""_(82) U^(2-7) + a (""_(2) alpha^(4)) + b(""_(-1) beta^(0))`
`a = (235- 207)/(4) = 7 alpha , 92- 82 = 2 (7) - b , 10 = 14- b IMPLIES b = 4 beta`
29559.

The indicator which is obtained by coupling the diazonium salt of sulphanilic acid with N, N-dimethylaniline is:

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indigo
methyl orange
methyl red
phenolphthalein.

Answer :B
29560.

The isopropyl alcohol and n-propyl alcohol can be distinguished chemically by …..

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ALKALINE SOLUTION of iodine
Reduction
Ozonolysis
Phosphorus pentachloride

Solution :Isopropyl ALCOHOL forms a yellow precipitate of IODOFORM with alkaline solution of iodine
29561.

The isomersim exhibited by C_(2)H_(5)-O-C_(2)H_(5) and CH_(3)-O-underset(CH_(3))underset(|)(CH)-CH_(3) is __________

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FUNCTIONAL
METAMERISM
POSITION
Chain

ANSWER :B
29562.

The isomers which can be converted into one another by free rotation about carbon-carbon bond are called :

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CONFORMATIONS
OPTICAL isomers
Stereoisomers
DIASTEREOMERS

ANSWER :A
29563.

The isomers whose structures differ markedly in arrangment of atoms, but which exist in equilibrium are called :

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METAMERS
ENANTIOMERS
Tautomers
Mesomers

Answer :C
29564.

The individual members of the lanthanide series is called as

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LANTHANIDES
LANTHANONS q
4f ELEMENTS
all of these

ANSWER :D
29565.

The isomers which can be converted into another forms by rotations of the molecules around single bond are

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GEOMETRICAL isomers
Conformers
Enantiomers
Diastereomers

Solution :Conformers - CONFORMATION ARISES because of free rotation AROUND C-C bond axis.
29566.

The indicator used in the titration of iodine against sodium thiosulphateis

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STARCH
`K_(3)Fe(CN)_(6)`
`K_(2)CrO_(4)`
Potassium

Answer :A
29567.

The isomer(s) of [Co(NH_(3))_(4)Cl_(2)] that has/have a Cl-Co-Cl angle of 90^(@), is /are :

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MERIDIONAL and trans
cis and trans
trans only
cis only

Solution :`[CO(NH_(3))_(4)Cl_(2)]` has 2 geometrical isomers

cis isomer has `Cl–Co–Cl` ANGLE of `90^(@)`
29568.

The isomerism which exists between CH_(2)ClCH_(2)ClandCH_(3)CHCl_(2) is :

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POSITION isomerism
Functional isomerism
metamerism
CHAIN isomerism

Answer :A
29569.

The isomerism possible in [Pt(en)_(2) Br_(2)]Cl_(2) is…… .

Answer»


ANSWER :IONISATION ISOMERISM
29570.

The indicator used in the titration of sodium carbonate with sulphuric acid is

Answer»

Phenolphthalein
Methyl organe
Potassium ferrocynide
Potassium ferricynide

Answer :B
29571.

The isomerism that arises due to restricted bond rotation is:

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OPTICAL isomerism
metamerism
position isomerism
functional isomerism

Answer :A
29572.

The indicator used in the titration of sodium carbonate with sulphuric acid is :

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POTTASIUM ferrocyanide
Pottasium ferricyanide
Methyl orange
Phenolphthalein

Answer :C
29573.

The isomerism possible in [CO(NH_(3))_(5)(NO_(2))]^(2+) is……… .

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ANSWER :LINKAGE ISOMERISM
29574.

The isomerism not shown by alkyl halides is ……..

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CHAIN ISOMERISM
FUNCTIONAL isomersim
POSITION isomerism
Optical isomerism

ANSWER :B
29575.

The isomerism exhibited by the co-ordination complex [Cr(NH_3)_2(H_(2)O)_(2)Cl_2]^(+) are :

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ionisation, OPTICAL
hydrate , optical
co-ordinate , geometrical
geometrical , optical

SOLUTION :The COMPLEX exhibits both geometrical and optical isomerism.
29576.

The indicator that is obtained by coupling the diazonium salt of sulphanilic acid with N, N-dimethylaniline is

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phenanthroline
methyl orange
methyl red
phenolphthalein

Answer :B
29577.

The isomerismexhibitedby primaryand secodanry nitroalkane to showaci -formis

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positionisomerism
GEOMETRICALISOMERISM
chainisomerism
TAUTOMERISM

SOLUTION :DEFINITION of tautomerism.
29578.

The isomerism exhibited by n-butyl alcohol and isobutyl alcohol is:

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Metamerism
Positional
Functional
Chain

Answer :D
29579.

The isomerism exhibited by n-butyl alcohol and isobutyl alcohol is

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CHAIN
POSITIONAL
FUNCTIONAL
METAMERISM

ANSWER :A
29580.

The isomerism exhibited by CH_(3)CH_(2)COOHandCH_(3)COOH_(3) is ________

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metamerism
position
chain
functional

Answer :D
29581.

The isomerism exhibited by 1-nitro butane and 1-nitro-2-methyl propane is…………..

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chain
tautomerism
position
functional

Answer :B
29582.

The isomerisation of 1-butyne to 2 -butyne can be achieved by treatment with

Answer»

HYDROCHLORIC acid
ammoniacal silver nitrate
ammoniacal cuprous chloride
ethanolic potassium hydroxide

Solution :On heating with alcoholic KOH or `NaNH_2` in inert solvent , the triple bond of 1-alkyne is shifted TOWARDS the centre to form an ISOMERIC 2-alkyne.
`CH_(3) underset("1-Butyne")(CH_2C) -= CH overset("ALC." KOH)underset(DELTA)(to) CH_(3) -underset(2-"Butyne")(C-=C)- CH_(3)`
29583.

The isomeric compounds 'A' and 'B' with molecular formula C_7 H_9 N give the following reactions. When B is acetylated and then brominated, it gave one monobromo derivative. 'A' when treated with NaNO_2 and HCl gave the compound 'C'. 'C' was heated with acetic acid in the presence of conc. H_2 SO_4, a pleasant smelling liquid (D) was obtained. 'B' was treated with NaNO_2 and HCl in cold condition and treated with beta-Naphthol in NaOH to give an orange red dye. 'A' is

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o-toluidine
N-Methylaniline
p-toluidine
BENZYLAMINE

Solution :ISOMERIC COMPOUNDS A and B are benzylamine & p-toluidine
29584.

The isomeric compounds 'A' and 'B' with molecular formula C_7 H_9 N give the following reactions. When B is acetylated and then brominated, it gave one monobromo derivative. 'A' when treated with NaNO_2 and HCl gave the compound 'C'. 'C' was heated with acetic acid in the presence of conc. H_2 SO_4, a pleasant smelling liquid (D) was obtained. 'B' was treated with NaNO_2 and HCl in cold condition and treated with beta-Naphthol in NaOH to give an orange red dye. 'D' is

Answer»




SOLUTION :SWEET SMELLING COMPOUND is benzylacetate
29585.

The indicator phenol red is half in the ioic form when pH is 7.2. If the ratio of the undissociated form to the ionic form is 1 : 5, find the pH of the solution. With the same pH for solution, if indicator is altered such that the ratio of undissociated form to dissociated form becomes 1 : 4, find the pH when 50% of the new indicator is in ionic form.

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ANSWER :PH 7.3
29586.

The isomeric compounds 'A' and 'B' with molecular formula C_7 H_9 N give the following reactions. When B is acetylated and then brominated, it gave one monobromo derivative. 'A' when treated with NaNO_2 and HCl gave the compound 'C'. 'C' was heated with acetic acid in the presence of conc. H_2 SO_4, a pleasant smelling liquid (D) was obtained. 'B' was treated with NaNO_2 and HCl in cold condition and treated with beta-Naphthol in NaOH to give an orange red dye. 'B' is

Answer»

BENZYLAMINE
p-toluidine
o-toluidine
m-toluidine

Solution :Isometic COMPOUNDS A and B are benzylamine & p-toluidine
29587.

Theisomerisation of 1-butyne to 2-butyne can be achieved by treatment with-

Answer»

hydrochloric acid
ammoniacal silver nitrate
ammoniacal cuprous chloride
ethanolic POTASSIUM hydroxide

Solution :`UNDERSET("1-butyne")(CH_(3)CH_(2)C -=CH) underset(Delta)OVERSET("ethanolic KOH")RARR underset("2-butyne")(CH_(3)-C-=C -CH_(3))`
29588.

The isomeric compounds ‘A’ and 'B' with molecular fomula C_(7)H_(9)N gave the following reactions. When B is acetylated and then brominated, it gave one monobromo derivative. 'A' when treated with NaNO_(2) and HCI gave the compound 'C'. 'C' was heated with acetic acid in the presence of conc. H_(2)SO_(4), a pleasant smelling liquid (D) was obtained. 'B' was treated with Na ‘A’ is

Answer»

o-toluidine
N-methylaniline
p-toluidine
benzylamine

Solution :
29589.

The indicator methyl orange is prepared by coupling diazonium salt of sulphanilic acid with:

Answer»

Aniline
N, N - Dimethylaniline
p - Methylaniline
Naphthol.

Answer :B
29590.

The isomeric compounds ‘A’ and 'B' with molecular fomula C_(7)H_(9)N gave the following reactions. When B is acetylated and then brominated, it gave one monobromo derivative. 'A' when treated with NaNO_(2) and HCI gave the compound 'C'. 'C' was heated with acetic acid in the presence of conc. H_(2)SO_(4), a pleasant smelling liquid (D) was obtained. 'B' was treated with Na 'D' is

Answer»




SOLUTION :
29591.

The isomeric cis-2-butene and trans-2-butene can be distinguished on the basis of:

Answer»

Their OPTICAL properties
Their REDUCTION PRODUCTS
The products they give on ozonlysis
The products they give on ADDITION to bromine

Answer :D
29592.

The indicator use in the titrating oxalic acid with caustic soda solution is :

Answer»

METHYL orange
Methyl red
Fluorescein
Phenolphthalein

Answer :D
29593.

The isomeric compounds ‘A’ and 'B' with molecular fomula C_(7)H_(9)N gave the following reactions. When B is acetylated and then brominated, it gave one monobromo derivative. 'A' when treated with NaNO_(2) and HCI gave the compound 'C'. 'C' was heated with acetic acid in the presence of conc. H_(2)SO_(4), a pleasant smelling liquid (D) was obtained. 'B' was treated with Na ‘B’ is

Answer»

benzylamine
p-toluidine
o-toluidine
m-toluidine

Solution :
29594.

The isomer of diethyl ether is

Answer»

`(CH_(3))_(2)CHOH`
`(CH_(3))_(3)C-OH`
`C_(3)H_(7)OH`
`(C_(2)H_(5))_(2)CHOH`

ANSWER :B
29595.

The isomer of C_(7)H_(7)Cl having weakest C-Cl bond is :

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o-Chlorotoluene
m-Chlorotoluene
p-Chlorotoluene
BENZYL chloride

Answer :D
29596.

Theisomerof C_(5) H_(13) N'A on reaction withnitrousacid gives-2- Methyl-2- butanolthe isomer 'B'on reactionwithacetyl chloridegives N- ethyl-N-isopropylacetamide Whereas isomer'C'have noreactionwith aceticanhydridewhich of thefollowingare A, B and C ?

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2-methyl -2- butanamineN-ethyl-2- PROPANAMINE N-ethyl - N- methylehtanamine
2-Methyl -1- butanamine N- ethyl -2-propanamine andN,N- dimethyl ethanamine
2-methyl - 1-butanamineN- ethyl-2-propanamineand N,N- dimethyl ethanamine
20 Methyl- 2- butanamineN- methyl-2-butanamineand N- ethyl -N- methylethanamine

Solution :`CH_(3)- overset(CH_(3)) overset(|)underset(NH_(2)) underset(|) (C ) -CH_(2) CH_(3)+ HNO_(2) to CH_(3)- overset( CH_(3))overset(|)underset( OH) underset (|) ( C ) - CH_(2)- CH_(3)`
Isomer A(Primaryamine )
`CH_(3)- underset( CH_(3) ) underset(|) (CH) -NH -C _(2) H_(5) +CH_(3) COCI to `
`CH_(3) - underset( CH_(3))underset(|)(C H)- overset(COCH_(3)) overset(|) (N)- C_(2) H_(5)`
Isomer B(Secondaryamine)
`C_(2) H_(5)-underset( CH_(3) ) underset(|)( N) - C_(2)H_(5) +(CH_(3) CO )_(2)O to` Noreaction
29597.

The indicator methyl orange is prepared by coupling dia- zonium salt of sulphanilic acid with

Answer»

Aniline
N, N-dimethylaniline
p-methylaniline
NAPHTHOL.

SOLUTION :
29598.

The isomer of an oxime is:

Answer»

`R-NO_(2)`
`R-O-C-=N`
`R-O-N-=O`
`R-CONH_(2)`

Solution :Oxime is represented by the FORMULA `R-OVERSET(H)overset(|)(C )=N-OH`
`therefore R-CONH_(2)` will will be the the isomer of oxime.
29599.

The isoelectronic species K^(+),Cl^(-),S^(2-) and Ca^(2+) can be arranged in the following decreasing order of size:

Answer»

`CA^(2+)gtK^(+)GTCL^(-)gtS^(2-)`
`Cl^(-)gtS^(2-)gtK^(+)gtCa^(2+)`
`S^(2-)gtCl^(-)gtCa^(2+)gtK^(+)`
`S^(2-)gtCl^(-)>K^(+)gtCa^(2+)`

Solution :Size decreases with increase in nuclear CHARGE in an iso -electronic series. The nuclear charge INCREASES as:
`(S^(2-)""Cl^(-)""K^(+)""Ca^(2+)),(+16""+17""+19""+20)`
29600.

The indicator constant of phenolphthalein is approximately 10^(-8).A solution is prepared by adding 100.01 c.c. of 0..01 N sodium hydroxide to 100.00 c.c. of 0.01 N hydrochloric acid.If a few drops of phenolphthalein are now added.what traction of the indicator is converted to its coloured form ?

Answer»

`1/3`
`3/4`
`1/2`
`9/11`

SOLUTION :millimole, `UNDERSET(100.01xx0.01)(NaOH)underset(" "100xx0.01)(+HCl)toNaCl+H_2O`
So, NaOH left =0.0001
Hence, CONCENTRATION of `OH^(-) =0.0001/200.01=0.0001/200`
`HPhhArr H^+ + Ph^(-)`
`K_a=([H^+][Ph^(-)])/([HPH])`
`implies 10^(-8)=(k_w[Ph])/([OH^(-)][HPh])=((10xx^(-14)xx[Ph])/0.0001)/(200)[HPh], " " ([Ph^(-)])/([HPh])=1/2`
so `([Ph^(-)])/([Ph^(-)]+[HPh])=1/3`