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6101.

69. Differentiate between SN1 and SN2 mechanism.1.

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6102.

68.When SN1 or SN2 reaction mechanism is possible?

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TheSN2reaction is concerted. That is, theSN2occurs in one step, and both the nucleophile and substrate are involved in the ratedeterminingstep.

Therefore the rate is dependent on both the concentration of substrate and that of the nucleophile.

TheSN1reaction proceeds stepwise

6103.

10) a) (1) Explain the Sn2 reaction withsuitable example. (3M)

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Substitution Nucleophilic bimolecular (SN2)

This reaction follows second order kinetics and the rate of reaction depends upon both haloalkane as well as participating nucleophile. Hence this reaction is known as substitution nucleophilic bimolecular reaction. In this reaction, the nucleophile attacks the positively charged carbon and the halogen leaves the group. Both the formation of carbocation and exiting of halogen take place simultaneously. In this process, unlike the SN1 mechanism, the inversion of configuration is observed. Since this reaction requires the approach of the nucleophile to the carbon bearing the leaving group, the presence of bulky substituents on or near the carbon atom has a dramatic inhibiting effect. So opposite to SN1 reaction mechanism, this is favored mostly by primary carbon, then secondary carbon and then tertiary carbon.

6104.

A SN2 reaction on chiral substrate is accompanied by inversion of configuration

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Let's say we have chlorofluoromethyl tosylate.

As we know that tosylate is a really good leaving group. We chuck in a bunch of iodide and we have an SN2 reaction between the chlorofluoromethyl tosylate and iodide leaving us with chlorofluoroiodomethane and tosylate leaves.

We know the stereocentre inverts from the mechanism and I've tried to draw it in a way that shows this. When we assign the stereocentres though, we find they're both R for the reaction as in figure. Note that the oxygen of the tosylate is priority 2 in the starting material, but it's replaced by iodine, which has a priority of 1 when assigning stereochemistry.

Examples like this do highlight that there is a bit of arbitrariness to the rules which we use to assign stereochemistry and they can be a little counter-intuitive.

6105.

7. N2 and H2 are taken in 1 :3 molar ratio in a closedvessel to attained the following equilibriumN2(g)+ 3H2g2NH(g). Find Kp for reaction attotal pressure of 2P if PN2 at equilibrium is P/34(a) 3p2(b) 3p?4 P(d) none

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6106.

State the relation between the joule and the calorie.

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1 calorie = 4.186 joule

6107.

What is bom calorie meter

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Bomb calorimeter is a thick-walled steel container used to determine the energy contained in a substance by measuring the heat generated during its combustion.

6108.

2. Which of the following is isoelectronic? 12002](a) CO2, NO(c) CN, CO(b) NO,, CO(d) SO,, co29

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CN- CO is isoelectronic

6109.

Whichofthefollowing molecule has no dative bond?1)Co(2) CO3(4) All of these

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option 4 all of the above

Carbon monoxide, CO, can be thought of as having two ordinary covalent bonds between the carbon and the oxygen plus a coordinate bond using a lone pair on the oxygen atom.

In theLewis structure of CO32-, the C atom in the middle forms one double bond with an O atom and forms two single bonds with the remaining two O atoms. The two single C-O bonds include O atoms that have lone pairs that can form coordinate covalent bonds with atransitionmetal ion. CO32-can then become monodentate by creating one coordinate bond using one oxygen atom's lone pair, or become bidentate by creating two coordinate bonds using both the oxygen atoms with lone pairs. Carbonato cannot form a coordinate covalent bond using the O atom in the double C-O bond because oxygen is most stable when it has two bonding pairs and two non-bonding pairs. That O atom is already in a favorable state and would not likely want to form a coordinate bond.

6110.

Determine the Point group of the following molecule.

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6111.

Qreestion of the DayIdentify the point group symmetryof the following molecule(all (-( bond lengths areequal)(a) Car (b), (c) Dad (2) Dad

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option C is the correct answer

option C is correct answer

C) is the best answer

it is a octahedral structure and a high symmetric group so it should have S4 type

in this structure high symmetric group...it is S4 type

6112.

]) Which of the following molecule involveselectrovalent bond(a) H(c) CaCl,(b) CH(d) HCI

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The answer of this question is CaCl2

A transfer of one electron from one atom to another resulting in opposite charges on the two atoms that holds them together by electrostatic (opposite charges attract) attraction is called an electrovalent or ionic bond. good examples of this is the bond formed between a Na (sodium) and a Cl (chlorine) atom, MgCl2, cacl2 KCl, etc

6113.

1.Which of the following molecule has no dative bond?(1) CO(2) CO(3) SO3(4) All of these

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option d is the correct answer

B-Carbonate ion have no any dative bond..

the answer could be option 2

option D is the correct answer

Dative bond or coordinate bond is a type of bond where only one atom shares the electrons of another atom without affecting it. ... But in CO3^2-, the two O atoms , each are singly negatively charged ,i.e, they need one more electron to complete their octet

options b is the correct answer.

6114.

Define electrovalent bond.

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Chemical bond formed by the electrostatic attraction between two oppositely charged ions is called anelectrovalent bond.

Definitionofelectrovalent bond. : a chemicalbondformed between ions of opposite charge. — called also ionicbond. —distinguished from covalentbond.

a chemical bond formed between ions of opposite charge.____ called also ionic bond

a type of chemicalbondin which oneatomlosesanelectronto form apositiveionand the other atomgainsthe electron to form anegativeion. The resulting ions are held together byelectrostaticattraction .

6115.

5.Compound So, has x bond pairs and y lone pairs of electrons. Calculate value of x t y

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in so3 there are 6 bond pairs with 2 attached to each so bond and 0 lone pair so x+y is equal to 6+0=6

yes you are right but answer given is 12

6116.

70. Thecorrect order of increasing C-O bond length of Co, Co3 , co,is(a) CO 2-<CO,-CO(c) CO <CO3<CO2Which of the following statements about LiCi and NaCl is wrong?(a) LiCi has lower melting point that NaCI(b) LiCl dissolves more in organic solvents whereas NaCl does not(c) LiCl would ionise in water more than NaCi(d) Fused Li act(b) COCoCO(d) CO Co CO71.Cl would be less conducting than fused N

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bond length is inversly proportional to bond order.

and bond order = no. of bonds shared between two atoms on average..

so, CO has bond order = 3 CO2 has bond order = 2 and (CO3)²- has bond order = 1.333

so, bond length will be CO3²- > CO2> CO.

2. option 3 is wrong.

6117.

84. Explain the nature of C-X bond in haloarenes.

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Haloarenes are the chemical compounds containing arenes, where one or more hydrogen atoms bonded to an aromatic ring are replaced with halogens. The nature of C-X bond depends on both the nature of carbon in the aromatic ring and the halogen attached. Halogens are generally denoted by “X”.

Salient points on the nature of C-X bond in haloarenes are:

1.The C-X bond in haloarenes is polarized, as halogens are more electronegative than carbon. Due to high electronegativity of halogen, it attracts the electron cloud more towards itself and thus gains slight negative charge, on the other hand, carbon obtains a slight positive charge.

2.As halogens need only one electron to achieve their nearest noble gas configuration, only one sigma bond is formed between one carbon and one halogen atom.

3 .Due to the increase in atomic size from fluorine to astatine, the C-X bond length in haloarenes increases from fluorine to astatine and bond dissociation strength decreases.

6118.

) Define bond length.

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6119.

The energies of activation for forward and reversereactions for A2 +-B2 2AB are 180 kJ mol 1and 200 kJ mol-1 respectively. The presence of acatalyst lowers the activation energy of both(forward and reverse) reactions by 100 kJ mol-1.The enthalpy change of the reaction (A2+ B22AB) in the presence of catalyst will be (in kJ mol )-AIEEE 20071(A) 300(C) 280(B) 120(D) 20

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6120.

The X-X bond length is 1.5 A and Y-Y bond lengthis 1.48 A. If electronegativity values of X and Y are3 and 3.5 respectively, then Y-X bond length wouldbe(1) 1.44 A(3) 1.75 A(2) 0.98 A(4) 0.73 A

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Thanks bhai

6121.

Calculate the lattice energy (in Units kJ mol 1) for ZnO crystal using Eq. 3.4 based on electrostatic model and using a Born-Haber cycle. Compare the two answers and comment on any difference.

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Provide the figure attached to the question for a complete answer.

6122.

D Niobium is found to crystallise with bee structureand found to have density of 8.55g cmDetermine the atomic radius of niobium if itsatomic mass is 93 (14.29 nm)

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6123.

Atomic number and mass number of an elementare 18 and 40 respectively. Identify the elementand write the number of electrons and neutronspresent in its atom. Show the schematic atomicstructure of the atom.

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18 is argon no of protons 18 no of electrons 1840 is Zirconium no of protons 40 no of electrons 40

6124.

6. Anatom of an element has 7 electrons in it's I she'la. What is its atomic number?b.State it's valency.cildentify the element.

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atomic number is 9valency is 1element is flourine

Atomic number= 9as valency = 1Element will be Fluorine

6125.

(b) How does bleeding from a wound stop by applying alum?

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Bleedingcan bestoppedby coagulation of the blood (formation of a clot). ... Potashalumhas highly charged Al3+ and (SO4)2- ions which act as neutralizing ions for the protein colloid in blood. This causes aggregation or clotting and this in turnstopsthebleeding.

6126.

HF is liquid while other hydrides of halogens are gases at normal temperature

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Hydrogen flouride is liquid at room temperature due to association.Hence option (iii) is the correct answer.Though HF is a diatomic molecule, it forms very strong intermolecular hydrogen bonds and thus at room tempertaure it forms a zig-zag chain of molecule by association as shown below:

6127.

COvalent ulan thhalides ?7.2 Why is Bitl, the strongest reducing agent amongst all the hydrides ofGroup 15 elements?

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Thanks

6128.

Intext Questionsare pentahalides more covalent than trihalides ?7.1 Why7.2 Why is BiHs the strongest reducing agent amongst all the hydrides ofGroup 15 elements ?

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1

2

7.2

6129.

How does the air flow betweenregions having different temperatures?

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When warmairrises, coolerair willoften move in to replace it, so wind often moves fromareaswhere it's colder toareaswhere it's warmer. The greater the differencebetweenthehighand low pressure or the shorter the distancebetweenthehighand low pressureareas, the faster the windwillblow.

6130.

e^x*log(sin(2*x), 10)

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2ex tan 2x + ex log con2x is the correct answer

y=e^x log(sin2x)lny=xlog(sin2x)log(sin2x) =z10^z=sin(2x)or z ln10=lnsin(2x)i.e z =lnsin(2x)/ln10Hence lny =xln(sin2x)/ln10Differentiating both sides wrt 'x'we get(1/y)(dy/dx)=[lnsin(2x)+x{2cos(2x)/sin2x}]/ln10or dy/dx= y[lnsin(2x)+x{2cos(2x)/sin2x}]/ln10={xlog(sin2x)}×[lnsin(2x)+x{2cos(2x)/sin2x}]/ln10

6131.

Why does the reactivity of nitrogen differ from phosphorus?

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6132.

block diagram of computer system

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6133.

2. What atoms are connected by a peptide bond?

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two amino acids are connected by a peptide bond

Amino acids is the basic building block of proteins; they are composed of a carbon atom attached to a hydrogen, a carbonyl group, an amine group, and an R group. Large proteins are formed by linking amino acids with peptide bonds.

bond between carbon and nitrogen

6134.

From given groups of animals an open circulatory system is present in which of the following?a) Molluscab) Arthropodad) Annelidac) Coelenterata() a and b(iii) b and c(i) a and c(iv) b and d

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Two of the largest phyla in the world, Arthropoda and Mollusca, have an open circulatory system.

The answer is option i)

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6135.

27.From given groups of animals an open circulatory system is present in which of the following?a) Molluscab) Arthropodac) Coelenteratad) Annelida(i) a and Ib(iii) b and c(ii) a and c(iv) b and d

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Corrct option: (i)The open circulatory system exists in Mollusca and Anthropoda.

Please hit the like button if this helped you.

6136.

; 0Oo5 0 e o +CH;—(CHy),,—CH, हक O Naहट न % 4 ४ 0 “

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It is Sodium Lauryl Sulphate.

6137.

Rinc rod dipped in aim of zinc Sulphate (In Sou)solution. The salt is asd dessociated of thesedilution at 298. Calculate electrodepotential. tien 24/2n) = -0.761

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6138.

23. A solution has pH - 2. It is diluted 10 times, what will be the pH of the solution after dilution(2) 102(3) 210(4) Remains constantMetalurythe nrocess of

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Initial pH=2

As pH=-log [H+]

[H+]= 10 raise to -2

ON DILUTION

[H+]=10 raise to -3

Hence pH=-log (10 raise to -3)

=-(-3)

pH=3

6139.

in electrolysis what does dilution meansadding of more water or minimizing the conc. of substance.

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Dilution means minimisation of the electrolyte.

In electrolysis dilution means decreasing the concentration of salts per litre of water. So it means decreasing the conc. of substance

6140.

Ostwald dilution lan

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Ostwald's Dilution Law tells us that the equilibrium constant, and the initial concentration of an electrolyte (prior to dissociation or association), can be used to calculate the extent of this dissociation or association for the electrolyte

6141.

6 Arrangethe following compounds in order of increasing dipole moment:Toluene () m-dichlorobenzene (I) o-dichlorobenzene (IIl) p -dichlorobenzene (Iv)

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Dipole moment of p – dichlorobenzene is zero because of symmetrical structure. o- and m-dichlorobenzene have higher dipole moments than toluene due to high electronegativity of chlorine than –CH3group. Further, to the o-dichlorobenzene has higher dipole moment due to lower bond angle than the m-isomer.so the answer is (b)

6142.

cii).AD t câ‘-7A9+cB

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1) decomposition reaction 1→ 2

2) double decomposition reaction.

6143.

हद ;fo 2ANP NS 24+ R]J‘?’Wq SIS

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Crystal structure. The caesium chloride structure adopts a primitivecubiclattice with a two-atom basis, where both atoms have eightfold coordination. The chloride atoms lie upon the lattice points at the edges of the cube, while the caesium atoms lie in the holes in the center of the cubes.

6144.

kasam

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6145.

What to Pu valle of aid sam and Ram water

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the pH value of acid rain is 4.2 to 4.4 and rainwater is 5.6

6146.

: Subtract 5 L 245 mL from 8L 475 mL.

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530 ml is right answer of your question

6147.

Q UE SII. How would you distinguish experimentally between an alcohol aneda carboxylic acid?

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6148.

| 33. बिस्मथ की सबसे स्थायी ऑक्सीकरण अवस्था हैंA) +3 (B) +5| (20 +3 और + 5 दोनों (0) कोई नहीं oL i .

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आर्सेनिक, एंटीमोनी और बिस्मथ के मामले पर विचार करने पर, +3 सबसे ज्यादा इस्थाई अवस्था है।

बिस्मथ एक रासायनिक तत्व है जिसका प्रतीक बीआई और परमाणु संख्या 83 है। यह एक ..... ऑक्सीकरण अवस्था +3 में है, बिस्मथ सभी हैलोजेन के साथ ट्राइहलाइड बनाता है: BiF 3, BiCl 3, BiBr 3, और BiI 3

6149.

Classification of universe

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Galaxies are classified into four classes: spirals, barred spirals, ellipticals and irregulars. It is based on the shapes of the galaxies.Explanation:Galaxies are very important fundamental building blocks of the Universe. Some are simple, while others are very complex in structure. As one of the first steps towards a coherent theory of galaxy evolution, the American astronomer Edwin Hubble, developed a classification scheme of galaxies in 1926.The Hubble classification of galaxies, also referred to as the ‘tuning fork’ diagram because of its shape, classes galaxies along three main lines into:Elliptical galaxiesSpiral galaxiesBarred Spiral Galaxies

6150.

velocity - Time graph is givenbelon50-olosec 20 sec- Timedraw displacement timeThenash

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