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6051.

45. How is ammonia gas liquefied ?How does applying pressure (or compression) help in the liquefaction of

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6052.

An electric spark is struck between 2 electrodes placed near each other in a closed tank full of petrol. Will the petrol catch fire? explain

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6053.

ung each of the digitsWe Hindu-Arabi(i) CCXLIIindu-Arabic numeral for each of the following:(iv) DCCXLI(ii) CDLXVWrite the Roman(v) XCIV(iii) LXXVI(vi) CXCIX

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1.252, 2.464 3.76 4.741 5.94 6.219

1) 252 2) 464 3) 76 4)741 5) 94 6) 219

6054.

A gas at a pressure of 5 atm is heated from 0° to546°C and simultaneously compressed to d ofit original volume. Hence final pressure is3

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okei i got it bt..hw ??T2=810 i thnk t2=799 and answer is 43.95

6055.

Derive the unit of pressure and work.0)

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Since the formula of work(W)= Force.Displacement=F.s

So, the unit of Work is kg m ^2 s^-2

or you can also call it Joule which consist of Newton metre.

6056.

Problem 5.1 2A balloon is filled with hydrogen at roomtemperature. It will burst if pressureexceeds 0.2 bar. If at 1 bar pressure thegas occupies 2.27 L volume, upto whatvolume can the balloon be expanded

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Using Boyle;s LawP1V1=P2V2If p1 is 1bar , V1 will be 2.27 LIf p2 = 0.2 barV2 = p1v1/p2 = 11.35 L

6057.

13Prove that (203+75) is an irrational number. Also check whether(23+15)(2+3 – V5) is rational or irrational

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7 is the correct answer

6058.

(liquified petroleum gas) cylinder weighs 14.8 kgwhen empty. When full it weighs 29.0 kg and shows apressure of2.5 atm. In the course of use at 27°C, the weightof the full cylinder reduces to 23.2 kg. Find out the volumeof the gas in cubic metres used up at the normal usageconditions, and the final pressure inside the cylinder.Assume LPG to the n-butane with normal boiling point of(1994)AnLPG0°C

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6059.

. Which of the following has the largest size?B. IA BrC. I

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option C is correct I- This is because an extra electron is added to the last orbit,hence makes it bigger..

6060.

Gt -PR~ e TR नि

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2-Chloro Butane............

6061.

Density of a gas is found to be 5.46 g/dm3 at 27°C at 2 bar pressure. What will be its density atSTP?(A) 6 gm/(B) 8 gm/l(C) 3 gm/l(D) 1.5 gm/l

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is there a joke going on

6062.

Which of the following species will havethe largest and the smallest size?Mg, Mg*, Al, Al3+

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Largest size will be of Mg and smallest will be Al3+

Thank you sir

6063.

19. The atom of largest size among the following is(a) Li(b) At(d) Be(J & K CE

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option B

option B

6064.

The atom of largest size among the following is(a) Li(c) I19.(b) At(d) Be(J& KCET)

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Periodic Trends of Atomic Radius

An atom gets larger as the number of electronic shells increase; therefore the radius of atoms increases as you go down a certain group in the periodic table of elements.

In general, the size of an atom will decrease as you move from left to the right of a certain period.

option btaiye

At(astatine) will have the largest size among the following in accordance to the concept mentioned earlier.

6065.

7. Considering air as a 4 1 mixture of nitrogen andoxygen, the mass ofar in a hall with dimensions 5m ×5m × 5m at STP is approximately(A) 160 g(C) 160 kg(B) 16g(D) 1.60 kg

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PV = nRT n = m/M (mass/molarmass) PV = mRT/M PM/RT = m/V = D The effective molar mass of air is 0.8x28 + 0.2x32 = 22.4 + 6.4 = 28.8g/mole. so D = 1atm x 28.8g/mole / (0.0821Latm/moleK x 301K) = 1.17g/L

Another way to think about it is: At STP the density of air is 28.8g/22.4L = 1.29g/L Gases expand when heated so the density will decrease if T increases from 273 to 301 so applying a temperature correction factor: 1.29g/L x 273/301 = 1.17g/L

6066.

37. (a) What is the molecular formula and structure of the alcohol which can be thought to be derived frompentane ?(b) Write the names of the following functional groups(iii)-COOH(iv) /(-0(v)--X(c) What makes the candle flame yellow and luminous ?

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thank you

6067.

(a) Write the names of the functional groups in:0) c-o

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ketone & aldehyde.

thankyou very much

6068.

In the lithium atom, screening effect oelectron is caused by-(1) Electrons of K and L shell(2) Electrons of K shell(3) Two electrons of 1st and one of 2(4)

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First two shells are responsible for the screening effect hence option A is correct..

6069.

functional groups formula

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Chemical Group Forumla

Alcohol Hydroxyl OH

Aldehyde Aldehyde RCHO

Alkane Alkyl RHn

Alkene Alkenyl R2C=CR2

Hit like if you find my answer useful

6070.

The amount of energy required to remove an electronfrom ground state of Het ion is(1) 54.4 eV(3) 20.4 eV(2) 13.6 eV(4) 34 ev

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6071.

(4) maximum energy in arbit. The lonisation energy for the H-atom is 136 eV. Then the required energy in eV to excite the electronfrom the ground state to next higher state wil be: in eV)(G) 10.2(3) 12.1m of electron in the

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6072.

PbO2 acts as oxidising agent. Why?

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Pb has an oxidation state of +4 in PbO2, but Pb+2 is more stable, due to which pb+4 has an innate ability to get converted into Pb+2, thus being able to oxidise others in the reactions.

6073.

dwing elementsCa vAO3, 23 amu (i) 19, 19 amu) ,1.000 amu. (v) 40, 40 amu, () 108, 108 amu.A sample of (CHethane has the same mass an 10' molemolecules doos the sampla contain ?mass as 10' molecules of methana. How many Gh

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Molar mass of methane = 16 g/mol1 mole of methane contains = 6.023 x 10^23 molecules Mass of 6.023 x 10^23 molecules of methane = 16 g​Mass of 1 molecule of methane = 16/ (6.023 x 10^23 ) g

Mass of 10 million molecules o molecules = [​16/ (6.023 x 10^23 ) ] x 10^7 = 2.65 x 10^-16 g

Thus mass of ethane sample = ​ 2.65 x 10^-16 g

​Molar mass of ethane or mass of 1 mole of ethane = 30 g/mol

If 30 g of ethane contain = 6.023 x 10^23 moleculesThen

​ 2.65 x 10^-16 g of ethane contains = [6.023 x 10^23 /30] x 2.65 x 10^-16 = 5.3203 x 10^6 molecules of ethane

6074.

what inspiration should we gain from the Life Of Swami Vivekananda

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determination and self confidence

6075.

IK&LL&MExCalculate the radius of 2nid excited state of La

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r (n ) = n ^ 2*0.529* 10^ -10 / zmz = atomic number = 3n = 2 (as given 2ndorbit )just put the value in the formula and calculate it .r (n ) = 4 * 0.529* 10 ^ -10

6076.

Q11 Name the first element of Newland'soctaves.

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lithium is the first element.

6077.

rates faster in china dish as compared to test tube?(b) Why water evaporates faster in china

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Water evaporates faster in a China dish as compared to a test tube 'cause the surface area of China dish is greater than that of the test tube. And, greater the surface area of water, faster the evaporation will be.

water evaporate more faster as compared to test tube because evaporation become more faster with the increase in surface area. Therefore, the surface area of China dish is more as compared to test tube. So, the evaporation become more faster.

6078.

Q27 Sand and naphthalene balls were heated together in a china dish. Which substance willbe2left in china dish after heating? Why?

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When mixture of sand and naphthalene is heated, naphthalene undergoes sublimation and hence is converted to gas and collected by a cotton ball.

Thus the residue left is sand only.

6079.

0. When1 mole of pure ethyl alcohol (CJ,0H) is mixed with i mole of acetic acid at 25°brium mixture contains 2/3 mole each of ester and waterequiliC2H,OHD+CH COOH)CH,COOC2H()+H2oDThe A Go for the reaction at 298 K is:(a) 3435 J(b) 4 J(c)-3435 J(d) Zero

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6080.

" Heat a china dish containing aboutcopper powder (Fig. I.10)." What do you observe?

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When the china dish containing copper is heated oxygen is added to this.As a result the surface of the copper powder becomes coated with black copper oxide . Here copper gains oxygen. so this is an example for oxydation reaction

thanks

6081.

Why copper turn green when kept open in air for long time?

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Copper turns greenbecause of chemical reactions with the elements. Just as iron that is left unprotected in open air will corrode and form a flaky orange-red outer layer,copperthat is exposed to the elements undergoes a series of chemical reactions that give the shiny metal a palegreenouter layer called a patina.

6082.

Identify the correct choice in the following questions.1. Law of conservation of masses was firstly established by

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The Law of Conservation of Mass (or Matter) in a chemical reaction can be stated thus: In a chemical reaction, matter is neither created nor destroyed. It was discovered byAntoine Laurent Lavoisier

6083.

Using van der Waals' equation, calculate the constant 'awhen two moles of a gas confined in a four litre flask exerta pressure of 11.0 atm at a temperature of 300 K. Thevalue of 'b' is 0.05 L mol-1(1998)

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6084.

Which country produces electricity from solid waste?

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Japan and China produce electricity from solid waste

6085.

why does a gas exert pressure

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The molecules are continually colliding with each other and with the walls of the container. When a molecule collides with the wall, they exertsmall force on the wall Thepressure exertedby thegasis due to the sum of all these collision forces.The more particles that hit the walls, the higher thepressure.

6086.

Give reasonsa Gases exert pressure on the walls of the container.

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Themoleculesare continually colliding with each other and with the walls of the container. When a molecule collides with the wall, theyexertsmall force on the wall Thepressureexerted by thegasis due to the sum of all these collision forces.The more particlesthat hit the walls, the higher the pressure.

6087.

Activity5.6How do you calculate the valency of an element from its eleetronicconfiguration?

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The no. of electrons in the outermost shell decides the valency of the element(atom).If the no. of electrons in the last shell is5 or more than 5simply subtract it frm 8(maximum number of electrons in the outermost shell) the difference is the valency.Eg: S (16)=2,8,66 is greater than 5.So the valency is 8-6=2.If it isless than 5the number itself is the valency.Eg:Na (11)=2,8,11 is less than 5.So the valency is 1.

6088.

How do you calculate the valency of an element from its electronicconfiguration?

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The no. of electrons in the outermost shell decides the valency of the element(atom).If the no. of electrons in the last shell is5 or more than 5simply subtract it frm 8(maximum number of electrons in the outermost shell) the difference is the valency.Eg: S (16)=2,8,66 is greater than 5.So the valency is 8-6=2.If it isless than 5the number itself is the valency.Eg:Na (11)=2,8,11 is less than 5.So the valency is 1.

6089.

Sand, salt or sugar when filled in different container they took the shape of the container. How can you say that they are solid?

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because,They Have Fixed VolumeFix Shape etc..

They take the shape of the container as their particle size is small but the particle have fixed shape.

6090.

14. The valency of a metal is +2 and +3. What is the formulae of its two sulphates ?15. What is the valency of metal M in MPO,?

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6091.

How do you calculate tbe valency of an element from its electronicconfiguration?

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The no. of electrons in the outermost shell decides the valency of the element(atom).If the no. of electrons in the last shell is5 or more than 5simply subtract it from 8(maximum number of electrons in the outermost shell) the difference is the valency.Eg: S (16)=2,8,66 is greater than 5. So the valency is 8-6=2.If it isless than 5the number itself is the valency.Eg:Na (11)=2,8,11 is less than 5.So the valency is 1.

6092.

Growth is increase in size. It is physical change or chemical

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6093.

B oy o T vrrl oqorp rnftor Jo o) ¼oYY 0T W o &༈

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When an iron nail dipped in the copper sulphate solution than iron displaces copper from the copper sulphate because iron is more reactive than copper. Therefore the colour of the copper sulphate solution changes.

6094.

1.What are the uses of CO, in everyday life?

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Carbon dioxide is also used widely as a coolant, a refrigerant, and an ingredient in the manufacture of frozen foods. Carbon dioxide fire extinguishers are often used to control electrical andoilfires, which cannot be put out withwater.

6095.

C) EDA complexes.

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Electron‐donor‐acceptor complexes (EDA) can be established through halogen‐bonding interactions between the N lone electron pair from organic bases (or N‐/O‐centered anions) and perfluoroalkyl iodides RF–I. These EDA complexes can be activated thermally or photochemically, and will be shown to be responsible for new C–RFbond formation reactions, bypassing the use of visible‐light photocatalysts (either organic or organometallic) or harsh reaction conditions, thus simplifying reaction protocols, work‐up and analysis. Through this strategy, diverse reaction types can be realized, such as atom transfer radical additions, homolytic aromatic substitutions, and multicomponent reactions.

6096.

\left. \begin{array} { l } { ( 1 ) 4.06 \text { atm } } \\ { ( 3 ) 40.6 \text { atm } } \end{array} \right.

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2 molal solution means 1000g solvent contains 2 moles sucrose.It means 1000g solvent contains 2x342 = 648g sucroseMass of solution = 1648 g.Volume of solution = 1648/1.4 = 1.17LMolarity of solution = 2/1.17= 1.709M

Osmotic pressure = CRTOsmotic pressure = 1.709x0.0821x298 = 40.6 atm

very correct

6097.

I Three moles of an ideal gas are expandedisothermally from a volume of 300 cm3 to 2.5 Lat 300 K against a pressure of 1.9 atm. Calculatethe work done in L atm and joules.(-4.18 L atm,-423.4 J)

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6098.

. In hypothetical reaciton A, + B,2AB follows the mechanism as given belowA,A + B,--→ AB + B (slow reaction)A BAB (fast reaction)A +A (fast reaction)Find the ว¡der of reaction.

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order of the reaction is 1/2+1 = 3/2.

6099.

what is SN1 and SN2??

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6100.

69.Differentiate between SN1 and SN2 mechanism.

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In substitution reactions, there are two mechanisms that will be observed. An Sn2 and Sn1 reaction mechanism.

Sn2 reactions are bimolecular in rate of reaction and have a concerted mechanism. The process involves simultaneous bond formation by the nucleophile and bond cleavage by the leaving group. The transition state looks like this. Because the reaction is concerted, Sn2 mechanisms will always lead to an inversion of stereochemistry! For reactivity using an Sn2 mechanism, primary >> secondary >> tertiary carbon centers.

On the other hand, Sn1 reactions are unimolecular in rate of reaction and have a step-wise mechanism. This process first involves bond cleavage by the LG to generate a carbocation intermediate. The stability of carbocation formation will determine if Sn1 or Sn2 reactions occur. In the second step, the electronegative nucleophile attacks the carbocation to form the product. The steps look like this. Because the nucleophile can attach either side of the carbocation, which adopts an sp2-hybridized orbital with a trigonal planar geometry, an equal amount of inversion and retention is seen, referred to as a racemic mixture. For reactivity using an Sn1 mechanism, tertiary >> secondary >>> primary carbon centers.

The strength of nucleophiles used help to determine the reaction mechanism. Strong bases will almost always proceed to Sn2 mechanism. Weak nucleophiles will generally proceed to Sn1 mechanism when a stable carbocation is present.