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1.

What is the quantity of electricity in coulombs needed to reduce 1 mol of  Cr2O72-? Consider the reaction: Cr2O72- +14H ++6e --> 2Cr3+ +8H2O

Answer»

The given reaction is as follows:

CrO72- + 14H+ 6e- → Cr3+ + 8H2

Therefore, to reduce 1 mole of CrO72-, the required quantity of electricity will be:

=6 F

= 6 × 96487 C

= 578922 C

2.

Why does the conductivity of a solution decrease with dilution? 

Answer»

The conductivity of a solution is the conductance of ions present in a unit volume of the solution. The number of ions (responsible for carrying current) decreases when the solution is diluted. As a result, the conductivity of a solution decreases with dilution.

3.

Can you store copper sulphate solutions in a zinc pot? 

Answer»

Zinc is more reactive than copper. Therefore, zinc can displace copper from its salt solution. If copper sulphate solution is stored in a zinc pot, then zinc will displace copper from the copper sulphate solution. 

Zn+CuSO4 ---> ZnSO4 +Cu

Hence, copper sulphate solution cannot be stored in a zinc pot. 

4.

Given the standard electrode potentials, K +/K = −2.93V, Ag+/Ag = 0.80V, Hg2+/Hg = 0.79V Mg2+/Mg = −2.37 V, Cr 3+/Cr = − 0.74V Arrange these metals in their increasing order of reducing power. 

Answer»

The lower the reduction potential, the higher is the reducing power. The given standard electrode potentials increase in the order of K+/K < Mg2+/Mg < Cr3+/Cr < Hg2+/Hg < Ag+/Ag.

 Hence, the reducing power of the given metals increases in the following order: Ag < Hg < Cr < Mg < K