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A `10%"(w/w)"` solution of cane sugar has undergone partial inversion according to the reaction: `"sucrose+water"rightarrow"glucose+ fructose"`. If the boiling point of solution is `100.27^(@)"C".` (a) What is the average mass of the dissolved materials? (b) What fraction of the sugar has inverted? `"K"_("b")("H"_(2)"O")=0.512" K mol"^(-1)" kg"` |
Answer» Correct Answer - (a)210.65, (b)62.35% `Delta"T"_("b")=[1+("n"-1)alpha]"K"_("b")("W"_("solute")xx1000)/("m"_("solute")xx"W"_("solvent"))` `0.27=[1+(2-1)alpha]xx(0.512xx10xx1000)/(342xx90)` `alpha=0.623` `"m"_("avg")=("m"_("sucrose"))/(1+alpha)=342/(1.623)` Average mass of dissolved material `=209.55"gm mol"^(-1)` |
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