1.

A gas with molecular formula C_(n)H_(2n + 2) diffuses through a porous plug at a rate 1//6th of the rate of diffusion of hydrogen gas under similar condtition. The formula of the gas is:

Answer»

SOLUTION :Let the molecular weight of the hydrocarbon be `M_(X)` and its rate of diffusion be `r_(x)`
`r_(H_(2))/r_(x) =SQRT(M_(x)/M_(H_(2))), r_(x) = 1//6r_(H_(2))`
`:. r_(H_(2))/r_(x)=6=sqrt(M_(x)/2)`
` RARR 36 XX 2 = M_(x)`
` rArr M_(x) = 72`
Molecular weight of thehydrocarbon is 72.
Let thenumber of carbon atoms present in one molecule of the hydrocarbon be be m.
`:' ` the hydrocarbon is saturated, the number of hydrogen atoms present in that hydrocarbon molecule is 2 m + 2
`:. (12 xxm) +2 m + 2 = 72`
` rArr 14 m +2 = 72 rArr m = 5`
`:.` Molecular formula of the hydrocarbon is `C_(5)H_(12)`.


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