1.

(a) Mr. Raju has determined the molecular masses of different solutes in different solvents by osmotic pressure measurements and presented them in the following table. Please help him to complete the table.SoluteSolventTheoretical Molecular MassExperimental Molecular MassNaClWaterAA/2BenzoicBenzeneB—AcidWaterC—UreaBenzeneD—Acetic acidWaterE—CaCl2WaterF—GlucoseWaterG—Ai2(So4)3—(b) The extent of deviation from ideal behaviour of a solution is explained by van’t Hoff factor, i. What is meant by van’t Hoff factor?

Answer»

(a) 2B, C, 2D, E/3, F, G/5.

(b) 2B and 2 D are due to association

i = \(\frac{Normal \,molar \,mass}{Abnormal \,molar \,mass}\)

OR

i = \(\frac{Observed\,Colligative\, Property}{Calculated\,Colligative\, property}\)



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