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Among the following, the solution which shows the highest osmotic pressure isA. `0.04 M FeSO_(4).(NH_(4))_(2)SO_(4).H_(2)O`B. `0.05 M K_(4)[Fe(CN)_(6)]`C. `0.05 M k_[Cu(CN)_(4)]`D. `0.05 M Al(NO_(3))_(3)` |
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Answer» Correct Answer - 2 `pi=I CRT` At a given temperature, solution having the highest value of iC has the gighest osmotic pressure. `K_(4)[Fe(CN)_(6)] rarr 4K^(+)+[Fe(CN)_(6)]^(4-)` `iC=(5)(0.05)=0.25` `FeSO_(4). (NH_(4))_(2)SO_(4).6H_(2)Ooverset(H_(2)O)(rarr) Fe^(2+)+2NH_(4)^(+)+2SO_(4)^(2-)` `iC=(5)(0.04)` `=0.2` `K_(3)[Cu(CN)_(4)]overset(H_(2)O)(rarr) 3K^(+)+[Cu(CN)_(4)]^(3-)` `iC=(4)(0.05)` `=0.2` `Al(NO_(3))_(3)overset(H_(2)O)(rarr)Al^(3+)+3NO_(3)^(-)` `iC=(4)(0.05)` `=0.2` |
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