1.

An oxygen cylinder of volume 30 litres has an initial gauge pressure of 15 atm. And a temperature of 27^(@)C. After some oxygen is withdrawn from the cylinder, the gauge pressure drops to 11 atm. And its temperature drops to 17^(@)C. Estimate the mass of oxygen taken out of the cylinder. (R = 8.1 J "mole"^(-1) K^(-1), molecular mass of O_(2) = 32 u).

Answer»

Solution :`V_(1)=30"litre"=30xx10^(3)CM^(3)=3xx10^(-2)m^(3)`
`P_(1)=15xx1.013xx10^(5)N/m^(2)`
`T_(1)=300K`
`mu_(1)=(P_(1)V_(1))/(RT_(1))=18.3`
`P_(2)=11xx1.013xx10^(5)N//m^(2)`
`V_(2)=3xx10^(-2)m^(3)`
`T_(2)=290K`
`mu_(2)=(P_(2)V_(2))/(RT_(2))=13.9`
`mu_(2)-mu_(1)=18.3-13.9=4.4`
Mass of GAS taken out of CYLINDER
`=4.4xx32g`
`=140.8g`
`=0.140kg`


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