1.

At `100^(@)C` the vapour pressure of a solution of `6.5g` of an solute in `100g` water is `732mm`.If `K_(b)=0.52`, the boiling point of this solution will be :A. `103^(@)C`B. `101^(@)C`C. `100^(@)C`D. `102^(@)C`

Answer» Correct Answer - B
At.`B.P.P_(0)=760 "torrr"` for elevation of B.P.
`(P_(0)-P_(s))/(P_(s))=(W_(B)//M_(B))/(W_(A)//M_(A))`
`(760-732)/(732)=(6.5//M)/(100//18)`
On solving `M=32`
`=1xx0.52xx((6.5)/(32))/((100))xx1000=1`
`DeltaT_(B)=T_(B)^(S)-T_(B)^(0)soT_(B)^(S)=DeltaT_(B)+T_(B)^(0)`
`T_(B)^(S)=1+100=101^(@)C`


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