1.

At `80^(@)C`, the vapour p[ressure of pure liquid A is 520 mm of Hg and that of pure liquid B is 1000 mm of Hg. If a mixture solution of A and B boils at `80^(@)C` and 1 atomoshere pressure, the amount of A in the mixture is (1 atm = 760 mm of Hg)A. 60 mol precentB. 52 mol precentC. 34 mol presentD. 48 mol precent.

Answer» Correct Answer - a
According to available information,
`P_(A)^(@)=520 mm Hg, P_(B)^(@)=1000mm Hg`
`P_(A)^(@)X_(A)+P_(B)^(@)X_(B)=760 mm Hg`.
`P_(A)^(@)X_(A)+P_(B)^(@)(1-X_(A))760`
`520 X_(A)+1000(1-X_(A))=760`
`520X_(A)+1000-1000X_(A)=760`
`-480X_(A)=-240`
or `X_(A)=240/480=1/2 "or 50 mol precent".


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