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Calculate the mole fraction of solute in a dilute aqueous solution from which ice begins to separate out at `-46^(@)C`. (`K_(f)` of `H_(2)O` =`1.86 K m^(-1)`) |
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Answer» `DeltaT_(f)=K_(f) xx m rArr m=(DeltaT_(f))/K_(f)=(0-(0-0.46))/1.86 = 0.46/1.86=0.247 m` Use the relation, `m=(n_(2)xx1000)/(n_(1)xxMw_(1))` `:.n_(2)/n_(1)=chi_(2)=(m xx Mw_(1))/1000` =`(0.247 xx 18)/1000` `=0.004` |
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